Electrode design for low temperature direct-hydrocarbon solid oxide fuel cells
In certain embodiments of the present disclosure, a solid oxide fuel cell is described. The solid oxide fuel cell includes a hierarchically porous cathode support having an impregnated cobaltite cathode deposited thereon, an electrolyte, and an anode support. The anode support includes hydrocarbon oxidation catalyst deposited thereon, wherein the cathode support, electrolyte, and anode support are joined together and wherein the solid oxide fuel cell operates a temperature of 600° C. or less.
1. A solid oxide fuel cell comprising:
A cathode comprising a porous cathode support, the porous cathode support comprising samaria doped ceria (SDC) with an impregnated cobaltite active material deposited thereon, the cobaltite active material comprising La 0.6 Sr 0.4 CoO 3 , the porous cathode support comprising macropores and mesopores, each macropore having a pore size of greater than 50 nm and 10 micrometers or less, and each mesopore having a pore size from 2 to 50 nm;
an electrolyte comprising samaria doped ceria (SDC); and
an anode comprising an anode support, the anode support comprising nickel-samaria doped ceria (Ni-SDC) with samaria doped ceria (SDC) nanoparticles deposited thereon, the SDC nanoparticles catalyzing oxidation of a hydrocarbon fuel, wherein the cathode support, electrolyte, and anode support are joined together and form an integral component and wherein the solid oxide fuel cell operates a temperature of between 400° C. and 600° C.
2. The solid oxide fuel cell of claim 1 , wherein the solid oxide fuel cell operates at a temperature of 550° C. or less.
3. The solid oxide fuel cell of claim 1 , wherein the solid oxide fuel cell operates at a temperature of 500° C. or less.
4. The solid oxide fuel cell of claim 1 , wherein the solid oxide fuel cell operates at a temperature of 450° C. or less.
5. A method for forming a solid oxide fuel cell comprising:
forming a cathode, the cathode comprising a porous cathode support, the porous cathode support comprising samaria doped ceria (SDC);
depositing a cobaltite active material on the cathode support such that the cobaltite active material is impregnated on the cathode support, the cobaltite active material comprising La 0.6 Sr 0.4 CoO 3 , the porous cathode support comprising macropores and mesopores, each macropore have a pore size of greater than 50 nm and 10 micrometers or less, and each mesopore having a pore size from 2 to 50 nm;
forming an anode, the anode comprising an anode support, the anode support comprising nickel-samaria doped ceria (Ni-SDC);
depositing samaria doped ceria (SDC) nanoparticles on the anode support, the SDC nanoparticles catalyzing oxidation of a hydrocarbon fuel;
co-sintering the cathode support and the anode support with an electrolyte therebetween to form an integral component, wherein the electrolyte comprises samaria doped ceria (SDC), wherein the solid oxide fuel cell is capable of operating at a temperature of between 400° C. and 600° C.