IP Library Granted Patent US 9,263,614
Granted Patent B2
US 9,263,614 · App. 12/912,893 · Granted Feb 16, 2016

In-fiber filament production

Inventors: Daosheng Deng (Cambridge, MA); Nicholas D. Orf (Somerville, MA); Ayman F. Abouraddy (Olievdo, FL); Yoel Fink (Brookline, MA)
Assignee: Massachusetts Institute of Technology
H01L31/035281H01L31/08H01L31/09H01L31/095G02B6/02366G02B6/03694Y02E10/50Y10T29/49801Y10T428/2931
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Quick Facts
Patent No.
US 9,263,614
App. No.
12/912,893
Granted
Feb 16, 2016
Kind
B2
Abstract

In a fiber there is provided a fiber matrix material having a fiber length; and an array of isolated in-fiber filaments that extend the fiber length. The in-fiber filaments are disposed at a radius in a cross section of the fiber that is a location of a continuous filament material layer in a drawing preform of the fiber. As a result, there is provided a fiber matrix material having a fiber length; and a plurality of isolated fiber elements that are disposed in the fiber matrix, extending the fiber length, where the plurality is of a number greater than a number of isolated domains in a drawing preform of the fiber.

Claims (32)

1. A structure comprising:

a fiber preform, having a preform diameter, the fiber preform including a fiber matrix material and a continuous layer of filament material having first and second faces and arranged with the fiber matrix material adjacent to each of the first and second faces, the continuous filament material layer having a thickness and a viscosity that enforce breakup of the continuous filament material layer into an array of in-fiber filaments upon drawing of the preform into a fiber;

a draw-down region connecting the fiber preform and a fiber; and

the fiber, having a fiber length and a fiber diameter that is less than the preform diameter, the fiber including an array of in-fiber filaments extending the fiber length, each filament in the array consisting of the filament material and circumferentially separated from other filaments by the fiber matrix material of the fiber preform.

2. The structure of claim 1 wherein the fiber matrix material comprises a polymeric insulating material.

3. The structure of claim 2 wherein the polymeric insulating material has a glass transition temperature.

4. The structure of claim 2 wherein the polymeric insulating material is selected from the group consisting of poly-sulfone, poly-ether sulfone, and poly-methyl methacrylate.

5. The structure of claim 1 wherein the in-fiber filaments and the continuous filament material layer comprise a metal.

6. The structure of claim 5 wherein the metal is selected from the group consisting of Sn and Bi.

7. The structure of claim 1 wherein the in-fiber filaments and the continuous filament material layer comprise a semiconducting material.

8. The structure of claim 7 wherein the semiconducting material comprises a chalcogenide glass material.

9. The structure of claim 7 wherein the semiconducting material is selected from the group consisting of Se, As 2 Se 3 , and (As 40 Se 60 ) 1-x Sn x .

10. The structure of claim 7 wherein the semiconductor material comprises a glassy inorganic semiconducting material.

11. The structure of claim 7 wherein the semiconducting material has a glass transition temperature.

12. The structure of claim 1 wherein each filament in the array of in-fiber filaments has a thickness and a width that are less than average grain size of the filament material in a polycrystalline state, whereby each in-fiber filament is single-crystal.

13. The structure of claim 1 wherein the in-fiber filaments are semiconducting; and further comprising at least one non-filament metallic in-fiber element extending the fiber length.

14. The structure of claim 1 wherein the in-fiber filaments are semiconducting; and further comprising at least one non-filament semiconducting fiber element extending the fiber length.

15. The structure of claim 1 wherein the in-fiber filaments are metallic; and further comprising at least one non-filament semiconducting fiber element extending the fiber length.

16. A method for producing a fiber comprising:

assembling a fiber preform including a continuous filament material layer having a filament material viscosity and having a continuous filament material layer thickness, with a fiber matrix material being adjacent to each face of the continuous filament material layer; and

drawing the preform into a fiber such that for the filament material viscosity and continuous filament, material layer thickness the continuous filament material layer breaks up into an array of isolated in-fiber filaments extending a fiber length.

17. The method of claim 16 further comprising consolidating the fiber preform prior to drawing the preform into a fiber.

18. The method of claim 16 further comprising crystallizing the in-fiber filaments after drawing the preform into a fiber.

19. The method of claim 18 wherein filament crystallizing comprises annealing the in-fiber filaments.

20. The method of claim 16 wherein the fiber matrix material comprises a polymeric insulating material.

21. The method of claim 20 wherein the polymeric insulating material has a glass transition temperature.

22. The method of claim 20 wherein the polymeric insulating material is selected from the group consisting of poly-sulfone, poly-ether sulfone, and poly-methyl methacrylate.

23. The method of claim 16 wherein the in-fiber filaments and the continuous filament material layer comprise a metal.

24. The method of claim 23 wherein the metal is selected from the group consisting of Sn and Bi.

25. The method of claim 16 wherein the in-fiber filaments and the continuous filament material layer comprise a semiconducting material.

26. The method of claim 25 wherein the semiconducting material comprises a chalcogenide glass material.

27. The method of claim 25 wherein the semiconducting material is selected from the group consisting of Se, As 2 Se 3 , and (As 40 Se 60 ) 1-x Sn x .

Assignments (2)
CONFIRMATORY LICENSE Recorded May 24, 2012
From: MASSACHUSETTS INSTITUTE OF TECHNOLOGY
To: NATIONAL SCIENCE FOUNDATION
Reel/Frame 028274/0691 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Jan 28, 2011
From: DENG, DAOSHENG, MR.; ORF, NICHOLAS D., MR.; ABORADDY, AYMAN, MR.; FINK, YOEL, MR.
To: MASSACHUSETTS INSTITUTE OF TECHNOLOGY
Reel/Frame 025711/0910 →
Continuity (2)
Provisional Application 61279857 · Oct 27, 2009
Related Publication 20110097581A1 · Apr 28, 2011