Nonwoven fabric having cross-linking material
A layer includes a main body having a plurality of first pores and at least one crosslinked binder.
1. A single-ply layer comprising:
a non-woven fabric as a main body having a plurality of first pores, the main body being at least partly filled with inorganic particles, the inorganic particles filling at least some of the plurality of first pores and forming particle-filled regions, wherein the inorganic particles in the particle-filled regions form a plurality of second pores in a labyrinthine structure in which dendritic interpenetration from one side to another of the single-ply layer cannot take place, an average diameter of the inorganic particles being greater than an average pore size of the plurality of second pores; and
a crosslinked binder comprising an organic polymer, forming a network in the first pores and the second pores,
wherein a thickness of the single-ply layer is less than 100 μm, and
wherein the crosslinked binder is applied as an aqueous dispersion.
2. The single-ply layer as recited in claim 1 , wherein each of the inorganic particles have a spherical configuration.
3. The single-ply layer as recited in claim 1 , wherein the inorganic particles are distributed homogeneously in a planar manner in the main body.
4. The single-ply layer as recited in claim 1 , wherein at least a portion of the particle-filled regions is in the form of a coating of the main body.
5. The single-ply layer as recited in claim 1 , wherein the binder comprises an organic polymer comprising a beta-unsaturated carboxylic acid, beta-unsaturated carboxylic acid salt, beta-unsaturated carboxylic acid ester, beta-unsaturated carboxylic acid amide, beta-unsaturated nitrile, acrylate, derivative of an acrylate, methacrylate, derivative of a methacrylate, a copolymers of any of these, or a mixture of two or more of any of these.
6. The single-ply layer as recited in claim 1 , wherein the binder has a melting point less than a melting point of the inorganic particles, the main body, or both.
7. The single-ply layer as recited in claim 1 , wherein the inorganic particles include an average diameter in a range of 0.01 and 10 μm.
8. The single-ply layer as recited in claim 1 , further comprising:
an organic particle comprising a polyacetal, polycycloolefin copolymer, polyester, polyimide, polyether ketone, polycarboxylic acid, polycarboxylate, rubber, polyvinyl compound, polyether, polynitrile, polysulfone, halogenated polymer, unsaturated polymer, copolymer of any of these, or a mixture of two or more of any of these.
9. The single-ply layer as recited in claim 1 , further comprising:
organic particles comprising a polypropylene, polyvinylpyrrolidone, polyester, fluorinated polymer, chlorinated polymer, polystyrene, styrene butadiene copolymers, polyacrylate, nitrile butadiene polymer, polymethacrylate, polyether amide, polyether imide, polyether ketone, EPDM-rubber, polyvinylpyridine, polyetherketone, polyacrylonitrile, polysulfone, polyethylene, polyoxymethylene, polybenzimidazole, copolymer of any of these, or a mixture of two or more of any of these.
10. The single-ply layer as recited in claim 1 , further comprising:
further inorganic particles.
11. The single-ply layer as recited in claim 10 , wherein the further inorganic particles comprises a metal oxide, metal hydroxide, nitride, carbonitride, carbooxonitride, borate, sulfate, carbonate, glass, silicate, or a mixture of two or more of these.
12. The single-ply layer as recited in claim 1 , wherein the non-woven fabric includes a fiber,
wherein an average length of the fiber is at least twice an average diameter of the fiber.
13. The single-ply layer as recited in claim 1 , wherein the non-woven fabric includes a fiber,
wherein at least 90% of the fiber has an average diameter of at most 12 μm.
14. The single-ply layer as recited in claim 1 , wherein the non-woven fabric includes a fiber,
wherein at least 40% of the fiber has an average diameter of at most 8 μm.
15. The single-ply layer as recited in claim 1 , wherein the layer has a porosity of at least 15%.
16. The single-ply layer as recited in claim 1 , wherein the plurality of second pores each have a pore size of at most 3 μm.
17. The single-ply layer as recited in claim 1 , wherein the layer has a maximum tensile force of at least 15 N/5 cm in a longitudinal direction.
18. The single-ply layer as recited in claim 1 , wherein the main body is calendered.
19. A method for producing the single-ply layer according to claim 1 , comprising:
preparing a solution or dispersion including crosslinkable polymers and a main body having a plurality of first pores;
crosslinking the polymers so as to coat the main body; and
drying the coated main body.
20. A method for producing the monolayer single-ply layer according to claim 1 , comprising:
producing a solution or dispersion including polymerizable monomers, at least some of the monomers being crosslinkable;
impregnating a main body having a plurality of first pores with the solution or dispersion;
polymerizing the monomers;
crosslinking the polymerized monomers; and
drying the impregnated main body.
21. The method as recited in claim 20 , wherein the monomers include a mixture of monofunctional and bifunctional and/or polyfunctional monomers.
22. The method as recited in claim 20 , wherein the polymerizing is performed ionically or radically.
23. The method as recited in claim 20 , wherein the crosslinking is performed thermally or by radiation.
24. The method as recited in claim 20 , wherein the solution or dispersion contains at least one further component selected from the group consisting of photoinitiators, radical initiators, ionic initiators, thermal initiators, chain transfer agents, chain regulators and protic and aprotic solvents.
25. The method as recited in claim 20 , wherein the solution or dispersion contains particles.
26. A fuel cell, a battery separator, a capacitor separator, a gas-diffusing layer, or a membrane, comprising the single-ply layer as recited in claim 1 .