Thermally conductive resin composition
The thermally conductive resin composition of the present invention contains (a) a matrix component, (b) a larger-diameter thermally conductive inorganic powder, (c) a smaller-diameter thermally conductive inorganic powder, and (d) a vulcanizing agent and/or curing agent. The surface of the smaller-diameter thermally conductive inorganic powder is selectively treated with a silane compound represented by R(CH 3 ) a Si(OR′) 3-a (wherein R is an unsubstituted or substituted organic group having 6 to 20 carbon atoms, R′ is an alkyl group having 1 to 4 carbon atoms, and a is 0 or 1) or a partially hydrolyzed product thereof, and the amount thereof is smaller than the amount necessary to coat the entire surface area of the smaller-diameter thermally conductive inorganic powder. Accordingly, a thermally conductive resin composition that has a low hardness and a high thermal conductivity and that undergoes little outgassing and has storage stability is provided even when large amounts of thermally conductive inorganic powder is loaded into the resin component.
1. A thermally conductive resin composition comprising:
(a) a matrix component,
(b) a larger-diameter thermally conductive inorganic powder having a specific surface area of 0.06 to 1.0 m 2 /g, and
(c) a smaller-diameter thermally conductive inorganic powder having a pre-treatment specific surface area of greater than 1.0 to 20 m 2 /g,
a surface of the small-diameter thermally conductive inorganic powder of the component (c) being treated with a silane compound represented by R(CH 3 ) a Si(OR′) 3-a , wherein R is an unsubstituted or substituted organic group having 6 to 20 carbon atoms, R′ is an alkyl group having 1 to 4 carbon atoms, and a is 0 or 1, or a partially hydrolyzed product thereof, and an amount thereof being smaller than an amount necessary to coat an entire surface area of the smaller-diameter thermally conductive inorganic powder,
a proportion of a surface area of the larger-diameter thermally conductive inorganic powder of the component (b) being 10% or less of a total surface area of the larger-diameter thermally conductive inorganic powder of the component (b) and the smaller-diameter thermally conductive inorganic powder of the component (c), and
the thermally conductive resin composition having a thermal conductivity of 0.8 W/m·K or greater.
2. The thermally conductive resin composition according to claim 1 , wherein the component (a) is at least one member selected from thermosetting resins, thermoplastic resins, and rubbers.
3. The thermally conductive resin composition according to claim 2 , wherein the component (a) is a thermosetting resin and comprises a curing agent.
4. The thermally conductive resin composition according to claim 1 , wherein the component (a) is a silicone rubber.
5. The thermally conductive resin composition according to claim 4 , wherein the silicone rubber of the component (a) is cured with a platinum catalyst.
6. The thermally conductive resin composition according to claim 1 , wherein the thermally conductive inorganic powders of the components (b) and (c) are each at least one member selected from alumina, zinc oxide, magnesium oxide, and silica.
7. The thermally conductive resin composition according to claim 6 , wherein the alumina is α-alumina having a purity of 99.5 mass % or greater.
8. The thermally conductive resin composition according to claim 1 , wherein an amount of volatilized gas derived from the component (c) is 5 μg/cm 2 or less.
9. The thermally conductive resin composition according to claim 1 , wherein the specific surface area of each of the components (b) and (c) is a BET specific surface area and is measured according to JIS R1626.
10. The thermally conductive resin composition according to claim 1 , wherein the amount of the silane compound is from 0.5 times to less than 1.0 times the amount of silane compound calculated according to a formula:
Amount of silane compound(g)=Amount of thermally conductive inorganic powder(g)×Specific surface area of thermally conductive inorganic powder(m 2 /g)/Minimum silane coating area(m 2 /g),
wherein the minimum silane coating area (m 2 /g) is calculated according to [(6.02×10 23 )×(13×10 −20 )/molecular weight of silane].
11. The thermally conductive resin composition according to claim 1 , wherein the smaller-diameter thermally conductive inorganic powder of the component (c) treated by coating with the silane compound or a partially hydrolyzed product thereof is mixed with the matrix component (a) in conjunction with the larger-diameter thermally conductive inorganic powder of the component (b).
12. The thermally conductive resin composition according to claim 1 , wherein the silane compound or a partially hydrolyzed product thereof is coated on the smaller-diameter thermally conductive inorganic powder of the component (c) according to a dry method or a wet method.
13. The thermally conductive resin composition according to claim 12 , wherein after coating the smaller-diameter thermally conductive inorganic powder of the component (c) with the silane compound or a partially hydrolyzed product thereof according to a dry method or a wet method, an unreacted material is removed.
14. The thermally conductive resin composition according to claim 1 , wherein, regarding particles of the thermally conductive inorganic powders to be spherical, particles of the larger-diameter thermally conductive powder having a specific surface area of 0.06 to 1.0 m 2 /g have an average particle diameter of 20 μm or greater, and particles of the smaller-diameter thermally conductive powder having a specific surface area of greater than 1 to 20 m 2 /g have an average particle diameter of less than 20 μm.