Method for producing light-modulating film and light-modulating film
View Patent ↗A method for producing a light-modulating film in which a light-modulating layer is sandwiched between two transparent resin substrates, the light-modulating layer being formed by use of a light-modulating material containing: a polymeric medium for forming a resin matrix; and a light-modulating suspension, includes the following steps: step (a) of applying the light-modulating material to one (a first transparent resin substrate: of the transparent resin substrates; step (b) of bonding the other transparent resin substrate (a second transparent resin substrate) onto the light-modulating material applied to the first transparent resin substrate; and step (c) of irradiating the light-modulating material sandwiched between the first transparent resin substrate and the second transparent resin substrate with an energy ray to cure the polymeric medium for forming the resin matrix contained in the light-modulating material, thereby forming the light-modulating layer to yield the light-modulating film.
1. A method for producing a light-modulating film in which a light-modulating layer is sandwiched between two transparent resin substrates, the light-modulating layer being formed by use of a light-modulating material containing: a polymeric medium for forming a resin matrix; and a light-modulating suspension, the method comprising the steps of:
the step (a) of applying the light-modulating material to one (a first transparent resin substrate) of the transparent resin substrates;
the step (b) of bonding the other transparent resin substrate (a second transparent resin substrate) onto the light-modulating material applied to the first transparent resin substrate to obtain a lamination; and
the step (c) of irradiating the light-modulating material sandwiched between the first transparent resin substrate and the second transparent resin substrate with an energy ray to cure the polymeric medium for forming the resin matrix contained in the light-modulating material, thereby forming the light-modulating layer to yield the light-modulating film,
wherein the step b) is performed before the step c), and
wherein the lamination is pressed from either the first transparent resin substrate side thereof or from the second transparent resin substrate side thereof, or
the lamination is pressed from both of the first transparent resin substrate side thereof and the second transparent resin substrate side thereof in the step (b).
2. The method for producing a light-modulating film according to claim 1 , further comprising a step of applying the light-modulating material to the second transparent resin substrate before the step (b).
3. The method for producing a light-modulating film according to claim 1 , wherein the lamination is pressed from both of the first transparent resin substrate side thereof and the second transparent resin substrate side thereof in the step (b).
4. The method for producing a light-modulating film according to claim 1 , wherein the lamination is irradiated with the energy ray from both of the first transparent resin substrate side thereof and the second transparent resin substrate side thereof in the step (c).
5. The method for producing a light-modulating film according to claim 1 , wherein the first transparent resin substrate is wound out from a roll in the step (a), and the second transparent resin substrate is wound out from a roll in the step (b),
the method further comprising the step of winding up the light-modulating film yielded in the step (c) around a roll.
6. A light-modulating film produced by the light-modulating film producing method according to claim 1 .
7. The method for producing a light-modulating film according to claim 1 ,
wherein the light-modulating suspension contains light-modulating particles and a dispersing medium, the light-modulating particles being at least one selected from the group consisting of polyperiodides, inorganic fibers, carbon nanotubes, metal-free phthalocyanines and metal phthalocyanines.
8. The method for producing a light-modulating film according to claim 1 ,
wherein at least one of the transparent resin substrates includes a transparent electroconductive film made of at least one selected from the group of consisting of indium tin oxide (ITO), SnO 2 and In 2 O 3 .
9. A method for producing a light-modulating film in which a light-modulating layer including a light-modulating material is sandwiched between two transparent resin substrates, the method comprising steps of:
applying a light-modulating material to a first transparent resin substrate, the light-modulating material including a light-modulating suspension dispersed in a polymeric medium;
forming a lamination by bonding a second transparent resin substrate onto the light-modulating material applied to the first transparent resin substrate; and
irradiating the light-modulating material sandwiched between the first transparent resin substrate and the second transparent resin substrate to cure the polymeric medium and form a resin matrix containing the light-modulating suspension, thereby forming a light-modulating layer to yield a light-modulating film,
wherein the step of forming the lamination is performed before the step of irradiating the light-modulating material, and
wherein the step of forming the lamination includes pressing the first transparent resin substrate toward the second transparent resin substrate,
pressing the second transparent resin substrate toward the first transparent resin substrate, or
pressing the first transparent resin substrate toward the second transparent resin substrate and pressing the second transparent resin substrate toward the first transparent resin substrate.
10. The method for producing a light-modulating film according to claim 9 , further comprising applying light-modulating material to the second transparent resin substrate before the step of forming the lamination.
11. The method for producing a light-modulating film according to claim 9 , wherein the step of forming the lamination includes pressing the first transparent resin substrate toward the second transparent resin substrate and pressing the second transparent resin substrate toward the first transparent resin substrate.
12. The method for producing a light-modulating film according to claim 9 , wherein the step of irradiating the light-modulating material includes applying radiation through both of the first transparent resin substrate and the second transparent resin substrate.
13. The method for producing a light-modulating film according to claim 9 , wherein the step of applying light-modulating material to the first transparent resin substrate includes winding out the first transparent resin substrate from a first roll, and the step of forming the lamination includes winding out the second transparent resin substrate from a second roll.
14. The method for producing a light-modulating film according to claim 13 , further comprising winding up the light-modulating film around a third roll.
15. The method for producing a light-modulating film according to claim 9 , further comprising winding up the light-modulating film around a roll.
16. The light-modulating film produced by the method for producing a light-modulating film according to claim 9 .
17. The method for producing a light-modulating film according to claim 9 , wherein the resin matrix contains droplets of the light-modulating suspension.
18. The method for producing a light-modulating film according to claim 9 ,
wherein the light-modulating suspension contains light-modulating particles and a dispersing medium, the light-modulating particles being at least one selected from the group consisting of polyperiodides, inorganic fibers, carbon nanotubes, metal-free phthalocyanines and metal phthalocyanines.
19. The method for producing a light-modulating film according to claim 9 ,
wherein at least one of the transparent resin substrates includes a transparent electroconductive film made of at least one selected from the group of consisting of indium tin oxide (ITO), SnO 2 and In 2 O 3 .