Non-aqueous inkjet ink and ink set
Disclosed is a non-aqueous inkjet ink that includes a polyvinyl chloride resin synthesized by a suspension polymerization method or an emulsion polymerization method; an organic solvent that is a mixed solvent comprising diethylene glycol ethyl methyl ether, diethylene glycol diethyl ether, and diethylene glycol monoethyl ether in which the polyvinyl chloride resin is dissolved; a pigment; and a radical polymerization inhibitor. In another embodiment, the mixed solvent includes N-methyl-2-pyrrolidone, diethylene glycol diethyl ether, and diethylene glycol monoethyl ether. The radical polymerization inhibitor prevents the polyvinyl chloride resin from gelling in a short period and causing a discharge fault, clogging, etc. Also disclosed is an ink set of inkjet inks includes a combination of the non-aqueous inkjet inks above having respective colors and including at least a cyan ink; a magenta ink; a yellow ink; and a black ink.
1. A non-aqueous inkjet ink, comprising:
a polyvinyl chloride resin synthesized by a suspension polymerization method or an emulsion polymerization method;
an organic solvent that is a mixed solvent comprising N-methyl-2-pyrrolidone, diethylene glycol diethyl ether, and diethylene glycol monoethyl ether in which the polyvinyl chloride resin is dissolved;
a pigment; and
a radical polymerization inhibitor.
2. The non-aqueous inkjet ink according to claim 1 , wherein the radical polymerization inhibitor is selected from the group consisting of hydroquinones, catechols, hindered amines, phenols, phenothiazines, condensed aromatic ring quinones, and combinations thereof.
3. The non-aqueous inkjet ink according to claim 1 , wherein the polyvinyl chloride resin is a vinyl chloride-vinyl acetate copolymer, and wherein the vinyl chloride-vinyl acetate copolymer has a vinyl content that is no less than 1 mass % and no more than 36 mass %.
4. The non-aqueous inkjet ink according to claim 1 , wherein the non-aqueous inkjet ink further comprises a benzotriazole.
5. The non-aqueous inkjet ink according to claim 1 , wherein the pigment is a phthalocyanine pigment, and wherein the radical polymerization inhibitor is a hindered amine present in an amount based on total amount of the non-aqueous inkjet ink that is no less than 0.2 mass % and no more than 2 mass %.
6. The non-aqueous inkjet ink according to claim 1 , wherein the pigment is a quinacridone pigment, and wherein the radical polymerization inhibitor is a hindered phenol present in an amount based on total amount of the non-aqueous inkjet ink that is no less than 0.05 mass % and no more than 2 mass %.
7. The non-aqueous inkjet ink according to claim 1 , wherein the pigment is a chelate azo pigment, and wherein the radical polymerization inhibitor is a hindered amine present in an amount based on total amount of the non-aqueous inkjet ink that is no less than 0.05 mass % and no more than 2 mass %.
8. The non-aqueous inkjet ink according to claim 1 , wherein the pigment is carbon black, and wherein the radical polymerization inhibitor is a hindered amine present in an amount based on total amount of the non-aqueous inkjet ink that is no less than 0.05 mass % and no more than 2 mass %.
9. An ink set of inkjet inks, comprising:
a combination of non-aqueous inkjet inks according to claim 1 having respective colors and including at least:
a cyan ink having a cyan color;
a magenta ink having a magenta color;
a yellow ink having a yellow color; and
a black ink having a black color.