IP Library Granted Patent US 9,560,848
Granted Patent B2
US 9,560,848 · App. 12/933,476 · Granted Feb 7, 2017

Method and compositions for biofouling deterrence

Inventors: Andrew S. Mount (Mountain Rest, SC); Neeraj V. Gohad (Clemson, SC); Andrew Metters (Clemson, SC); Nihar M. Shah (Woodland, CA)
Assignee: Clemson University
A01N33/10
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Quick Facts
Patent No.
US 9,560,848
App. No.
12/933,476
Granted
Feb 7, 2017
Kind
B2
Abstract

A method of deterring biofouling of a surface comprising attaching an adduct having formula (I) or noradrenalin to the surface. Formula (I) being defined as compounds that have the formula A-L-R wherein A is i) a C6 or C10 substituted aryl ring, or ii) a C1-C9 substituted or unsubstituted heteroaryl ring: L is a linking group, and R is a primary amino moiety comprising unit.

Claims (20)

1. An anti-fouling surface comprising noradrenaline conjugated to a polymer, the polymer including a vinyl resin, a vinyl ester, a vinyl chloride, a polymer of methacrylic acid, or a polymer of 2-hydroxyethyl methacrylate; wherein,

the polymer is grafted to the surface and the polymer attaches the noradrenaline to the surface, the surface being a marine or aquatic surface that contacts fresh water, brackish water, or salt water during use, the anti-fouling surface being resistant to settling and cementation of marine life on the surface.

2. The anti-fouling surface of claim 1 , wherein the anti-fouling surface is resistant to settling and cementation of mollusks, crustaceans, Bryozoa, and/or polychaet.

3. The anti-fouling surface of claim 2 , wherein the anti-fouling surface is resistant to settling and cementation of oysters.

4. The anti-fouling surface of claim 2 , wherein the anti-fouling surface is resistant to settling and cementation of barnacles.

5. The anti-fouling surface of claim 1 , wherein the polymer is a component of a marine paint or varnish.

6. The anti-fouling surface of claim 1 , wherein the surface is at least a portion of the hull of a ship, a propeller, a seismic streamer, a dock, an oil rig, a gas rig, a pipeline, a power plant water intake system, a heat exchanger, a grid, a fish net, or a cage.

7. The anti-fouling surface of claim 1 , wherein the surface comprises metal, wood, concrete or plastic.

8. The anti-fouling surface of claim 1 , wherein the surface is a metal surface.

9. An anti-fouling surface comprising noradrenaline conjugated to a polymer, the polymer comprising —COOH or —OH side groups, the noradrenaline being conjugated to the polymer via reaction between the noradrenaline and the —COOH or —OH side groups; wherein,

the polymer is grafted to the surface and the polymer attaches the noradrenaline to the surface, the surface being a marine or aquatic surface that contacts fresh water, brackish water, or salt water during use, the anti-fouling surface being resistant to settling and cementation of marine life on the surface.

10. The anti-fouling surface of claim 9 , wherein the anti-fouling surface is resistant to settling and cementation of mollusks, crustaceans, Bryozoa, and/or polychaet.

11. The anti-fouling surface of claim 10 , wherein the anti-fouling surface is resistant to settling and cementation of oysters.

12. The anti-fouling surface of claim 10 , wherein the anti-fouling surface is resistant to settling and cementation of barnacles.

13. The anti-fouling surface of claim 9 , wherein the polymer is a component of a marine paint or varnish.

14. The anti-fouling surface of claim 9 , wherein the surface is at least a portion of the hull of a ship, a propeller, a seismic streamer, a dock, an oil rig, a gas rig, a pipeline, a power plant water intake system, a heat exchanger, a grid, a fish net, or a cage.

15. The anti-fouling surface of claim 9 , wherein the surface comprises metal, wood, concrete or plastic.

16. The anti-fouling surface of claim 9 , wherein the surface is a metal surface.

17. The anti-fouling surface of claim 9 , wherein the surface further comprises a phenolic resin, a silicone polymer, a chlorinated rubber, a coal tar, an epoxy resin, a polyamide resin, a vinyl resin, an elastomer, an acrylate polymer, a fluoropolymer, a polyester, a polyurethane, or a latex.

18. The anti-fouling surface of claim 9 , wherein the polymer is a polymer of methacrylic acid, or a polymer of 2-hydroxyethyl methacrylate.

Assignments (2)
CONFIRMATORY LICENSE Recorded May 16, 2016
From: CLEMSON UNIVERSITY
To: NAVY, SECRETARY OF THE UNITED STATES OF AMERICA
Reel/Frame 038728/0761 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Feb 9, 2011
From: MOUNT, ANDREW S.; GOHAD, NEERAJ V.; METTERS, ANDREW; SHAH, NIHAR M.
To: CLEMSON UNIVERSITY
Reel/Frame 025776/0162 →
Continuity (2)
Provisional Application 61039032 · Mar 24, 2008
Related Publication 20110123477A1 · May 26, 2011