Oil-in-water emulsion composition
View Patent ↗An oil-in-water type (O/W) emulsion lubricant composition includes safe and renewable components that do not have environmental load, exhibits excellent lubrication properties, has excellent handling capability, is economical, and may be applied to tribological fields. The lubricant composition includes water or oil dispersant-treated ultrafine diamond particles in the aqueous phase (W phase) and/or the oil phase (O phase) of an oil-in-water (O/W) emulsion, or includes at least one multiple emulsion state that includes an oiliness improver and/or a composite state that includes a solid lubricant other than the ultrafine diamond particles in the same configuration.
1. An oil-in-water (O/W) emulsion composition comprising ultrafine diamond particles having an average particle size of 100 nm or less, which is treated with a water dispersion dispersant and/or an oil dispersion dispersant, and wherein the ultrafine diamond particles are dispersed in a water phase (W phase) and/or an oil phase (O phase), wherein the ultrafine diamond particles are added and dispersed
(1) in the water phase (W phase) as a dispersant-treated ultrafine diamond particle water dispersion prepared by treating the ultrafine diamond particles with a water dispersion dispersant and/or
(2) in an oil phase (O phase) as a dispersant-treated ultrafine diamond particle water dispersion prepared by treating the ultrafine diamond particles with an oil dispersion dispersant, wherein the ultrafine diamond particles in the dispersant-treated ultrafine diamond particle oil dispersion (2) are ultrafine diamond particles which have a water dispersion dispersant and an oil dispersion dispersant.
2. The O/W emulsion composition according to claim 1 , wherein the ultrafine diamond particles in the dispersant-treated ultrafine diamond particle water dispersion (1) are obtained by adding the water dispersion dispersant to water after or when dispersing ultrafine diamond particles in the water, and then removing the water.
3. The O/W emulsion composition according to claim 1 , wherein the water dispersion dispersant comprises one or a plurality of an anionic dispersant, an amphoteric dispersant, and a nonionic dispersant.
4. The O/W emulsion composition according to claim 1 , wherein the oil dispersion dispersant comprises any one or both of a polar dispersant and a nonpolar dispersant.
5. The O/W emulsion composition according to claim 1 , further comprising an emulsifier which comprises one or a plurality of an anionic emulsifier, a cationic emulsifier, an amphoteric emulsifier, and a nonionic emulsifier.
6. The O/W emulsion composition according to claim 1 , wherein the water phase (W phase) comprises partially a hydrophilic solvent.
7. An oil-in-water (O/W) emulsion composition comprising ultrafine diamond particles having an average particle size of 100 nm or less, which is treated with a water dispersion dispersant and/or an oil dispersion dispersant, and wherein the ultrafine diamond particles are dispersed in a water phase (W phase) and/or an oil phase (O phase), wherein said O/W emulsion composition comprises a multiple emulsion state that includes both the following 1) and 2), 1) and 3), or 1) to 3) at the same time:
1) an O/W emulsion composition that includes the ultrafine diamond particles in a water phase (W phase) and/or an oil phase (O phase),
2) another O/W emulsion composition newly produced by adding at least one oiliness improver to the water phase (W phase) of the O/W emulsion composition, and
3) an emulsion composition that is separately produced from 2) above and is at least one member selected from the group consisting of an oil-in-water (O/W) emulsion composition, a water-in-oil (W/O) emulsion composition, a water-in-oil-in-water (W/O/W) emulsion composition, and an oil-in-water-in-oil (O/W/O) emulsion composition.
8. The O/W emulsion composition according to claim 1 , wherein the water phase (W phase) and/or the oil phase (O phase) of the O/W emulsion composition including the ultrafine diamond particles includes a solid lubricant other than the ultrafine diamond particles in composite state.
9. A lubricant comprising the O/W emulsion composition according to claim 1 .
10. A coating agent comprising the O/W emulsion composition according to claim 1 .
11. A coating member having a modified surface thereof, the coating member being obtained by
coating the member with an oil-in-water (O/W) emulsion composition comprising ultrafine diamond particles having an average particle size of 100 nm or less, which is treated with a water dispersion dispersant and/or an oil dispersion dispersant, and wherein the ultrafine diamond particles are dispersed in a water phase (W phase) and/or an oil phase (O phase), and
drying the coated member.
12. An anhydrous mixture that produces the O/W emulsion composition according to claim 1 upon addition of an aqueous component, comprising two or more of components selected from a base oil component (base oil or emulsifier), a dispersant, a dispersant-treated ultrafine diamond particle oil dispersion, water dispersion solid particles, oil dispersion solid particles, an oiliness improver, a solid other than ultrafine diamond particles, and a hydrophilic solvent.
13. The O/W emulsion composition according to claim 1 , wherein the ultrafine diamond particles added and dispersed in both the oil phase (O phase) and the water phase (W phase) are contained in a concentration of not more than 10 wt %.
14. An oil-in-water (O/W) emulsion composition comprising ultrafine diamond particles having an average particle size of 100 nm or less, which is treated with a water dispersion dispersant and/or an oil dispersion dispersant, and wherein the ultrafine diamond particles are dispersed in a water phase (W phase) and/or an oil phase (O phase), wherein said O/W emulsion composition comprises a multiple emulsion state that includes following 1) and 2), 1) and 3), or 1) to 3) at the same time;
1) an O/W emulsion composition that includes the ultrafine diamond particles in a water phase (W phase) and/or an oil phase (O phase),
2) an O/W emulsion composition that is produced by adding an oiliness improver to the oil phase (O phase) of the O/W emulsion composition of the above 1), and
3) an emulsion composition that is separately produced from the above 1), and is at least one member selected from the group consisting of an oil-in-water (O/W) emulsion composition, a water-in-oil (W/O) emulsion composition, a water-in-oil-in-water (W/O/W) emulsion composition, and an oil-in-water-in-oil (O/W/O) emulsion composition.
15. A method of producing the coating member according to claim 11 , comprising coating the member with the oil-in-water (O/W) emulsion composition comprising ultrafine diamond particles having an average particle size of 100 nm or less, which is treated with a water dispersion dispersant and/or an oil dispersion dispersant, and wherein the ultrafine diamond particles are dispersed in a water phase (W phase) and/or an oil phase (O phase) by and during a pre-conditioning interim operation.