Ceramic structure for water treatment, water treatment apparatus and method
A ceramic structure for water treatment, a water treatment apparatus and method are provided. Immersion efficiency of a photo catalyst and a specific surface area of the immersed photo catalyst can be improved using a ceramic medium including a ceramic paper prepared of a ceramic fiber. Accordingly, it is possible to provide the water treatment apparatus and method capable of increasing decomposition efficiency of contaminated materials due to irradiation of ultraviolet light, and so on, enabling continuous purification treatment, and remarkably reducing preparation, management and water treatment expenses.
1. A ceramic structure for water treatment comprising:
a porous ceramic medium having a honeycomb structure and including a flat ceramic paper and a waved ceramic paper adhered to the flat ceramic paper; and
a photo catalyst layer coated on the porous ceramic medium,
wherein the porous ceramic medium comprises a primary coating layer, which is formed on the flat and waved ceramic papers and which includes one or more selected from the group consisting of silica, silane, siloxane, alumina, zirconia and aluminum silicate and comprises a secondary coating layer, which is formed on the primary coating layer and which includes aluminum phosphate, and
wherein the primary and/or secondary coating layer comprise one or more of magnesium, calcium and boron containing compounds.
2. The ceramic structure for water treatment according to claim 1 , wherein the ceramic medium has a parallelepiped shape.
3. The ceramic structure for water treatment according to claim 2 , wherein the parallelepiped ceramic medium has a ratio (width/length) of a width to a length of a bottom surface of 1 to 1.5.
4. The ceramic structure for water treatment according to claim 2 , wherein the parallelepiped ceramic medium has a ratio (height/width) of a height to a width of a bottom surface of 2 to 6.
5. The ceramic structure for water treatment according to claim 1 , wherein the flat ceramic paper and the waved ceramic paper include a ceramic fiber.
6. The ceramic structure for water treatment according to claim 5 , wherein the ceramic fiber has a diameter between 1 μm and 20 μm, an average length between 0.1 mm and 10 mm.
7. The ceramic structure for water treatment according to claim 1 , wherein the photo catalyst layer comprises SrTiO 3 , CdSe, KNbO 3 or TiO 2 .
8. The ceramic structure for water treatment according to claim 1 , wherein the photo catalyst layer comprises anatase type TiO 2 and rutile type TiO 2 .
9. The ceramic structure for water treatment according to claim 8 , wherein a weight ratio (anatase type:rutile type) of the anatase type TiO 2 to the rutile type TiO 2 is 5 to 8:2 to 5.
10. A water treatment apparatus comprising:
a storage tank in which contaminated water is stored;
a ceramic structure for water treatment, according to claim 1 , installed such that a portion thereof contacts the contaminated water when the contaminated water is stored in the storage tank; and
an ultraviolet irradiation apparatus installed to irradiate ultraviolet light to a photo catalyst included in the ceramic structure for water treatment.
11. The water treatment apparatus according to claim 10 , wherein the ceramic structure for water treatment is installed such that the flat ceramic paper thereof is perpendicular to the surface of the contaminated water when the contaminated water is stored in the storage tank.
12. A water treatment method comprising:
a first step of storing contaminated water in a storage tank of a water treatment apparatus according to claim 10 ; and
a second step of irradiating ultraviolet light to a photo catalyst immersed in a ceramic medium of the water treatment apparatus.
13. The water treatment method according to claim 12 , wherein the ultraviolet light irradiated to the photo catalyst has a wavelength of 400 nm or less.