Bioorganically-augmented high value fertilizer
The invention is directed to processes for treating biosolids that result in high-value, nitrogen-containing, slow-release, organically-augmented inorganic fertilizer that are competitive with less valuable or more costly conventional commercially manufactured fertilizers. The process involves conditioning traditional waste-water biosolids and processing the conditioned biosolids continuously in a high throughput manufacturing facility. The exothermic design and closed loop control of the primary reaction vessel decreases significantly the amount of power necessary to run a manufacturing facility. The process utilizes green technologies to facilitate decreased waste and enhanced air quality standards over traditional processing plants. The fertilizer produced from recovered biosolid waste is safe and meets or exceeds the United States Environment Protection Agency (USEPA) Class A and Exceptional Quality standards and is not subject to restrictions or regulations.
1. A method for a continuous treatment of biosolids comprising:
dewatering the biosolids to form a pump-able fluid;
injecting steam into the dewatered biosolids in a first pug-mill;
mixing concentrated oxidizing agents and one or more first acids into the dewatered biosolids in the first pug-mill;
feeding the mixed biosolids into a pressure vessel;
injecting one or more second acids and ammonia into the pressure vessel to combine with the mixed biosolids and form conditioned biosolids;
feeding the conditioned biosolids into a second pug-mill;
treating the conditioned biosolids with one or more hardening agents in the second pug-mill; and
drying the hardened biosolids to form a fertilizer.
2. The method of claim 1 , wherein the biosolids comprise one or more of municipal biosolids, heat-dried biosolids, pharmaceutical fermentation wastes, microbial digests of organic products, food stuffs, food byproducts, animal manures, digested animal manures, organic biosolids, biosolids containing microorganisms, or combinations thereof.
3. The method of claim 1 , the dewatered biosolids are created by subjecting biosolids to filtration, centrifugation, pressure, or a combination thereof.
4. The method of claim 1 , wherein the one or more first acids comprises at least phosphoric acid at a concentration of 50% or more.
5. The method of claim 1 , wherein the one or more second acids comprise phosphoric acid, sulfuric acid, or both, and the ammonia comprises anhydrous or aqueous ammonia.
6. The method of claim 1 , wherein the one or more second acids and the ammonia together create an exothermic reaction within the mixture.
7. The method of claim 6 , wherein the exothermic reaction takes place without external heating.
8. The method of claim 1 , wherein the pressure vessel is maintained at a temperature of 230° F. or greater.
9. The method of claim 1 , further comprising adding one or more ferrates to the mixture.
10. The method of claim 9 , wherein the one or more ferrates is selected from the group consisting of a calcium ferrate, a sodium ferrate, a potassium ferrate, ferrous sulfate heptahydrate, and combinations thereof.
11. The method of claim 9 , wherein the one or more ferrates is formed from reaction of a solid-state sodium hydroxide with sodium hypochlorite and ferric chloride.
12. The method of claim 1 , wherein the one or more oxidizing agents is selected from the group consisting of hydrogen peroxide, calcium hypochlorite, sodium hypochlorite, potassium hypochlorite, chlorine dioxide, ozone, oxygen, and combinations thereof.
13. The method of claim 1 , wherein the biosolids are retained in the pressure vessel for 15 minutes or less.
14. The method of claim 1 , wherein one or more of acidity, pressure, flow speed, pH, base infusion speed are controlled by closed-loop computer controls to maintain a predetermined reaction temperature.
15. The method of claim 1 , wherein biosolids are continuously processed through the pressure vessel.
16. The method of claim 1 , wherein organic material in the treated and dried biosolids is partially or completely hydrolyzed, denatured, or sterilized.
17. The method of claim 16 , wherein the organic material is selected from the group consisting of one or more members selected from the group consisting of pharmaceutical compounds, antibiotics, hormones, hormone-like molecules, biologically active compounds, macromolecules, carbohydrates, nucleic acids, fats, lipids, proteins, and combinations thereof.
18. The method of claim 1 , wherein phosphate content of the dried biosolids is from 0.5% to 4%.
19. The method of claim 1 , wherein nitrogen content of the dried biosolids is enhanced by aqueous ammonia that is added to the pressure vessel.
20. The method of claim 1 , further comprising adding a granulating agent to the mixture before drying to form a dried and granulated mixture.
21. The method of claim 20 , further comprising crushing the dried and granulated mixture.
22. The method of claim 20 , further comprising passing the dried and granulated mixture through one or more screens to isolate granules of a predetermined size.
23. The method of claim 20 , further comprising coating the dried granules with a coating agent.
24. The method of claim 23 , wherein the coating agent is applied to the granules within a cooling apparatus.
25. The method of claim 20 , further comprising cooling the dried and granulated mixture in a cooling apparatus to a temperature of 140° F. or less.
26. The method of claim 25 , wherein the cooling apparatus is a fluidized bed, an ammonia chiller, or a rotating drum.
27. The method of claim 1 , further comprising passing the conditioned biosolids through a second pressure vessel.
28. The method of claim 1 , further comprising adding one or more plant nutrients to the biosolids in the first pug-mill.
29. The method of claim 28 , wherein the one or more plant nutrients are selected from the group consisting of urea, ammonium nitrate, ammonium sulfate, monoammonium phosphate, diammonium phosphate, urea ammonium nitrate, liquid urea, potash, iron oxide, soluble iron, chelated iron and combinations thereof.
30. The method of claim 1 , wherein the one or more hardening agents are selected from the group consisting of ferric oxides, alum attapulgite clay, industrial molasses, lignon, ligno sulfonate, urea formaldehyde polymerizer and combinations thereof.
31. A method for treatment of biosolids comprising:
combining dewatered biosolids with steam and a first acid to form a mixture;
injecting the mixture, one or more second acids, and ammonia into a pressure vessel to create an exothermic reaction;
subjecting the mixture to a predetermined temperature and pressure for a retention time;
removing the mixture from the pressure vessel after the retention time; and
drying the mixture.