IP Library Granted Patent US 8,722,590
Granted Patent B2
US 8,722,590 · App. 12/986,479 · Granted May 13, 2014

Ceramic proppants

Inventors: Frank O'Brien (St. Louis, MO); Chris Haller (St. Louis, MO)
Assignee: Shamrock Group
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Quick Facts
Patent No.
US 8,722,590
App. No.
12/986,479
Granted
May 13, 2014
Kind
B2
Abstract

A sintered, generally spherical ceramic body, having an alumina content of from about 52 to about 58 weight percent distributed substantially homogeneously throughout the body, a silica content from about 32 to about 39 weight percent distributed substantially homogeneously throughout the body, an apparent specific gravity of about 2.63 to about 2.67, and a bulk density of about 1.48 to about 1.56 grams per cubic centimeter.

Claims (27)

1. A sintered, generally spherical ceramic body, comprising:

an alumina content between about 32 and about 39 weight percent distributed substantially homogeneously throughout the body;

a silica content between about 52 and about 58 weight percent distributed substantially homogeneously throughout the body;

an iron oxide content of about 3 weight percent;

a titania content of about 2 weight percent titania;

with the remainder being alkali and alkali earth metal oxides;

having an apparent specific gravity of about 2.65; and

having a bulk density of about 1.50 grams per cubic centimeter.

2. The sintered body of claim 1 wherein the body is characterized by a crush of less than about 10 percent at 7500 psi.

3. The sintered body of claim 1 wherein the body is characterized by a crush of less than about 5 percent at 7500 psi.

4. The sintered body of claim 1 wherein the body is characterized by a crush of less than about 10 percent at 8000 psi.

5. The sintered body of claim 1 wherein the alumina content is between about 35 and about 38 weight percent and the silica content is between about 54 and about 57 weight percent.

6. The sintered body of claim 1 wherein the sintered body has a Krumbein roundness value of at least 0.9.

7. A high strength ceramic body, comprising:

an alumina content between about 32 and about 39 weight percent distributed substantially homogeneously throughout the body; and

a silica content between about 52 and about 58 weight percent distributed substantially homogeneously throughout the body;

wherein the body has an apparent specific gravity of about 2.65;

wherein the body has a bulk density of about 1.50 grams per cubic centimeter;

wherein the body has an iron oxide content of about 3 weight percent;

wherienthe body has a titania content of about 2 weight percent;

wherein the remainder of the body is alkali and alkali earth metal oxides;

wherein the body has a specific gravity between 2.61 and 2.65 grams per cubic centimeter; and

wherein the body has an ambient temperature permeability of at least about 100,000 millidarcies at 8,000 psi.

8. The high strength ceramic body of claim 7 wherein the body has a silica content of between 54 and 57 weight percent.

9. The high strength ceramic body of claim 8 wherein the body contains about 36 weight percent alumina and about 56 weight percent silica.

10. The high strength ceramic body of claim 7 wherein the body has a Krumbein sphericity of at least 0.9.

11. The high strength ceramic body of claim 7 wherein the body further includes a crush strength enhancer selected from the group of rutile, bentonite, ball clay, fireclay, nepheline syenite, fused bauxite dust, wollastonite, feldspar and talc.

Assignments (5)
RELEASE OF SECURITY INTEREST Recorded Mar 15, 2018
From: MONROE CAPITAL MANAGEMENT ADVISORS, LLC
To: SHAMROCK GROUP, LLC
Reel/Frame 045237/0851 →
RELEASE OF SECURITY INTEREST Recorded Dec 29, 2017
From: MONROE CAPITAL MANAGEMENT ADVISORS, LLC
To: O'BRIEN INDUSTRIAL HOLDINGS, LLC; THE CHRISTY REFRACTORIES COMPANY, L.L.C.; CHRISTY INDUSTRIAL SERVICES CO., LLC; CHRISTY CATALYTICS, LLC; CHRISTY MINERALS, LLC; O'BRIEN ASSET MANAGEMENT, LLC; SHAMROCK PROPPANTS, LLC; SHAMROCK GROUP, LLC; SHAMROCK ASSETS LLC
Reel/Frame 044504/0885 →
SECURITY INTEREST Recorded Jul 10, 2017
From: SHAMROCK GROUP, LLC
To: FIRST BANK
Reel/Frame 042954/0803 →
SECURITY INTEREST Recorded May 15, 2014
From: O'BRIEN INDUSTRIAL HOLDINGS, LLC; THE CHRISTY REFRACTORIES COMPANY, L.L.C.; CHRISTY INDUSTRIAL SERVICES CO., LLC; CHRISTY CATALYTICS, LLC; CHRISTY MINERALS, LLC; O'BRIEN ASSET MANAGEMENT, LLC; SHAMROCK PROPPANTS, LLC; SHAMROCK GROUP, LLC; SHAMROCK ASSETS LLC
To: MONROE CAPITAL MANAGEMENT ADVISORS, LLC, AS ADMINISTRATIVE AGENT
Reel/Frame 032902/0243 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Apr 12, 2011
From: O'BRIEN, FRANK; HELLER, CHRIS
To: SHAMROCK GROUP
Reel/Frame 026117/0767 →
Continuity (1)
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