Organic photoreceptor, image forming apparatus and process cartridge
In the present invention, disclosed is an organic photoreceptor comprising a conductive support and provided thereon, a photosensitive layer and a protective layer provided on the photosensitive layer, the protective layer formed with alumina particles each comprising a reactive organic group. Also provided is an organic photoreceptor with which electrophotographic images having high durability together with high image quality can be obtained by improving a wear property of the organic photoreceptor up to the same level as that of an amorphous silicon photoreceptor, as well as by improving image flow and image blur which are easy to be generated at high temperature and high humidity.
1. An organic photoreceptor comprising a conductive support and provided thereon, a photosensitive layer and a protective layer provided on the photosensitive layer, the protective layer formed with alumina particles each comprising a reactive organic group,
wherein the reactive organic group comprises a group comprising a C═C double bond.
2. The organic photoreceptor of claim 1 ,
wherein the alumina particles each comprising a reactive organic group are obtained via reaction of alumina particles and a silane compound comprising a reactive organic group.
3. The organic photoreceptor of claim 2 ,
wherein the reactive organic group in the silane compound comprising the reactive organic group comprises a polymerizable functional group.
4. The organic photoreceptor of claim 3 ,
wherein the silane compound comprising the reactive organic group is represented by the following Formula (1):
wherein R 3 represents an alkyl group having 1-10 carbon atoms or an aralkyl group having 1-10 carbon atoms, R 4 represents an organic group having a polymerizable double bond, X represents a halogen atom, an alkoxy group, an acyloxy group, an aminoxy group or a phenoxy group, and n is an integer of 1-3.
5. The organic photoreceptor of claim 4 ,
wherein the alumina particles have a number average primary particle diameter of 1-300 nm.
6. The organic photoreceptor of claim 1 , comprising the protective layer formed via reaction produced by using a curable compound and the alumina particles each comprising the reactive organic group.
7. The organic photoreceptor of claim 6 ,
wherein the curable compound is a compound comprising a C═C double bond.
8. The organic photoreceptor of claim 7 ,
wherein the compound comprising a C═C double bond is a compound comprising an acryloyl group or a methacryloyl group.
9. The organic photoreceptor of claim 8 ,
wherein a ratio Ac/M is within the following range, wherein Ac represents the number of the acryloyl groups or the methacryloyl groups, and M represents molecular weight of the compound comprising the acryloyl group or the methacryloyl group:
0.005 <Ac/M< 0.012.
10. The organic photoreceptor of claim 1 ,
wherein the reactive organic group comprises a polymerizable functional group such that the polymerizable functional group comprises a radical polymerizable functional group.
11. The organic photoreceptor of claim 1 , comprising the protective layer formed via reaction between the alumina particles each comprising the reactive organic group to each other.
12. An image forming apparatus comprising a charging device, a light exposure device and a developing device around the organic photoreceptor of claim 1 to form images repetitively.
13. A process cartridge used for the image forming apparatus of claim 12 comprising the organic photoreceptor and at least one of a charging device, an imagewise light exposure device and a developing device integrally, the process cartridge installed in the image forming apparatus as a detachable unit.