Thin, platelet-shaped iron pigments, production thereof and use thereof
Iron effect pigments having a thickness distribution, determined via thickness counting by scanning electron microscopy (SEM), as a cumulative undersize distribution with: a) an h 50 value from 10 to 55 nm; and b) an h 90 value from 20 to 80 nm, and also a method for producing the pigments, and the use of the iron effect pigments. The disclosure further relates to a printing ink comprising the iron effect pigments of the invention.
1. Iron effect pigments wherein the iron effect pigments have a thickness distribution as determined via thickness counting by scanning electron microscopy (SEM) and represented as cumulative undersize distribution, with
a) an h 50 having a range from 10 to 55 nm; and
b) an h 90 having a range from 20 to 80 nm, wherein the iron effect pigments are platelet-shaped iron pigments having a platelet-shaped iron core.
2. The iron effect pigments of claim 1 , wherein the iron effect pigments have an h 50 with a range from 12 to 50 nm.
3. The iron effect pigments of claim 1 , wherein the iron effect pigments have an h 90 with a range from 25 to 70 nm.
4. The iron effect pigments of claim 1 , wherein the iron effect pigments have an h 98 of less than 100 nm.
5. The iron effect pigments of claim 1 , wherein the iron effect pigments have an h 10 with a range from 8 to 40 nm.
6. The iron effect pigments of claim 1 , wherein the iron effect pigments have an average size d 50 in a range from 5 to 40 μm.
7. The iron effect pigments of claim 1 , wherein the iron effect pigments are coated with at least one of a passivating inhibitor layer and a anticorrosion layer.
8. The iron effect pigments of claim 1 , wherein the iron effect pigments are present as powder.
9. A method for producing the iron effect pigments of claim 1 , comprising:
grinding a coarse iron powder having a particle size distribution featuring a d powder,10 ≦2.0 μm, a d powder,50 ≦5.0 μm, and a powder,90 ≦7.0 μm, using a milling mechanism, in the presence of solvent and lubricants and spherical grinding media.
10. The method of claim 9 , wherein the coarse iron powder has a particle size distribution with a d powder,10 ≦1.6 μm, a d powder,50 ≦3.3 μm, and a d powder,90 ≦5.5 μm.
11. The method of claim 9 , wherein the spherical grinding media have an average diameter of 0.5 to 1.5 mm.
12. The method of claim 9 , wherein the total grinding time is over 12 to 100 h.
13. The method of claim 9 , wherein optionally size-classified iron pigments obtained after the grinding of the coarse iron powder are converted to a compact form.
14. A printing ink comprising the iron effect pigments of claim 1 .
15. A coated article comprising the iron effect pigments of claim 1 .
16. The iron effect pigments of claim 8 , wherein the powder is a nondusting powder.
17. The iron effect pigments of claim 8 , wherein the effect pigments are present as a paste or in compacted form.
18. The iron effect pigments of claim 17 , wherein the effect pigments are present in compacted form and the compacted form is selected from the group consisting of granules, pellets, tablets, sausages and briquets.
19. The method of claim 13 , wherein the compact form is selected from the group consisting of paste, granules, tablets, sausages, briquets and pellets.
20. Iron effect pigments wherein the iron effect pigments have a thickness distribution as determined via thickness counting by scanning electron microscopy (SEM) and represented as cumulative undersize distribution, with
a) an h 50 having a range from 10 to 55 nm; and
b) an h 90 having a range from 20 to 80 nm;
wherein the iron effect pigments are present as powder, and wherein the powder is a nondusting powder.