Single-crystal silicon carbide and single-crystal silicon carbide wafer
View Patent ↗A single-crystal silicon carbide and a single-crystal silicon carbide wafer of good-quality are disclosed that are low in dislocations, micropipes and other crystal defects and enable high yield and high performance when applied to a device, wherein the ratio of doping element concentrations on opposite sides in the direction of crystal growth of the interface between the seed crystal and the grown crystal is 5 or less and the doping element concentration of the grown crystal in the vicinity of the seed crystal is 2×10 19 cm −3 to 6×10 20 cm −3 .
1. A single-crystal silicon carbide manufactured by the modified Lely process, comprising:
a seed crystal, wherein nitrogen concentration of the seed crystal is greater than 1×10 19 cm −3 ; and
a grown crystal grown on the seed crystal, wherein doping element concentration of the grown crystal at least in a region in the vicinity of the seed crystal is 2×10 19 cm −3 to 6×10 20 cm −3 and a ratio of higher to lower doping element concentrations on opposite sides of an interface between the seed crystal and the grown crystal (concentration of high concentration side crystal/concentration of low concentration side crystal) is from 1.05 to 5.
2. A single-crystal silicon carbide according to claim 1 , wherein the region in the vicinity of the seed crystal is a region of 0.5 mm or less thickness on the grown crystal side of the interface between the seed crystal and the grown crystal.
3. A single-crystal silicon carbide according to claim 1 , wherein the ratio of higher to lower doping element concentrations is from 1.05 to 2.
4. A single-crystal silicon carbide according to claim 1 , wherein the ratio of higher to lower doping element concentrations is from 1.05 to 1.5.
5. A single-crystal silicon carbide according to claim 1 , wherein the doping element concentration of the grown crystal in a region in the vicinity of the seed crystal is 5×10 19 cm −3 to 6×10 20 cm −3 .
6. A single-crystal silicon carbide according to claim 1 , wherein the doping element concentration of the grown crystal in a region in the vicinity of the seed crystal is 1×10 20 cm −3 to 6×10 20 cm −3 .
7. A single-crystal silicon carbide according to claim 1 , wherein the doping element is nitrogen.
8. A single-crystal silicon carbide according to claim 1 , wherein the principal polytype is 4H.
9. A single-crystal silicon carbide according to claim 1 , wherein total etch pit density caused by all types of dislocation observed in a wafer of an off-angle of 8° from the {0001} plane made from grown crystal excluding a region in the vicinity of the seed crystal is 1×10 4 cm −2 or less and the micropipe density observed therein is 10 cm −2 or less.
10. A single-crystal silicon carbide according to claim 1 , wherein total etch pit density caused by all types of dislocation observed in a wafer of an off-angle of 8° from the {0001} plane made from grown crystal excluding a region in the vicinity of the seed crystal is 5×10 3 cm −2 or less and the micropipe density observed therein is 5 cm −2 or less.
11. A single-crystal silicon carbide wafer made from grown crystal excluding a region in the vicinity of the seed crystal of the single-crystal silicon carbide according to claim 1 , whose diameter is 75 mm to 300 mm and polytype other than in the edge exclusion region is 4H.