IP Library Granted Patent US 8,815,134
Granted Patent B2
US 8,815,134 · App. 12/999,813 · Granted Aug 26, 2014

Process for manufacturing polyolefin films

Inventor: Martinus Wilhelmus Maria Gemma Peters (Nijmegen, NL)
Assignee: Teijin Aramid B.V.
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Quick Facts
Patent No.
US 8,815,134
App. No.
12/999,813
Granted
Aug 26, 2014
Kind
B2
Abstract

A process for manufacturing a film of ultra-high molecular weight polyolefin comprising: (a) subjecting a starting ultra-high molecular weight polyolefin with a weight average molecular weight of at least 500 000 gram/mole in powder form to a compacting step using an isobaric press; and (b) subjecting the compacted polyolefin to a rolling step and at least one stretching step under such conditions that at no point during the processing of the polymer its temperature is raised to a value above its melting point. The process allows for the manufacture of ultra-high molecular weight polyolefin films of high quality.

Claims (18)

1. A process for manufacturing a homogeneous film of ultra-high molecular weight polyolefin comprising:

applying a starting ultra-high molecular weight polyolefin with a weight average molecular weight of at least 500,000 gram/mole in powder form on a releasable support belt at a distance upstream from an isobaric double belt press comprising a lower belt, an upper belt on top of the lower belt, and pressure cushions to apply pressure to the polyolefin at a compaction zone between the lower and upper belts;

preheating the support belt to increase a temperature of the ultra-high molecular weight polyolefin above a softening point of the ultra-high molecular weight polyolefin before entering the compaction zone;

subsequently feeding the support belt with the ultra-high molecular weight polyolefin into the compaction zone between the upper and lower belts of the isobaric press;

subjecting the support belt with the ultra-high molecular weight polyolefin to a compacting step using the isobaric press, wherein the compacting step is carried out at a temperature of at least 1° C. below an unconstrained melting point of the polyolefin and wherein the temperature is maintained within a temperature window of 2° C. to form a single layer film of compacted polyolefin;

discharging the support belt and the single layer film of compacted polyolefin from the upper and lower belts of the isobaric press;

separating the film of compacted polyolefin from the support belt; and

subjecting the single layer film of compacted polyolefin to a rolling step and at least one stretching step at a temperature of at least 1° C. below the melting point of the polyolefin under process conditions.

2. The process according to claim 1 , wherein the isobaric press is a continuous double belt press.

3. The process according to claim 1 , wherein the isobaric press is equipped with a nip, the nip having an entrance angle smaller than 4.5°.

4. The process according to claim 1 , wherein the isobaric press has at least two pressure zones, and a first pressure zone is operated at a pressure of at most 10 bar and at least one subsequent pressure zone is operated at a pressure above 10 bar.

5. The process according to claim 1 , wherein the pressure in the compacting step is at least 25 bar.

6. The process according to claim 1 , wherein the stretching step is carried out under such conditions that a total stretching ratio is obtained of at least 30.

7. The process according to claim 1 , wherein the staring polyolefin powder has a bulk density below 0.50 g/cm 3 .

8. A process for manufacturing a homogeneous film of ultra-high molecular weight polyolefin comprising:

feeding an ultra-high molecular weight polyolefin with a weight average molecular weight of at least 500,000 gram/mole in powder form to a compaction zone of an isobaric double belt press comprising a lower belt, an upper belt on top of the lower belt, and pressure cushions;

subjecting the ultra-high molecular weight polyolefin powder in the compaction zone to a pressure using the isobaric press at a temperature of at least 1° C. below an unconstrained melting point of the polyolefin and wherein the temperature is maintained within a temperature window of 2° C., a ratio of the pressure to the density of the compacted material being constant at every point of the compaction zone, to form a single layer sheet of compacted polyolefin; and

subjecting the compacted polyolefin to a rolling step and at least one stretching step at a temperature of at least 1° C. below the melting point of the polyolefin under process conditions.

Assignments (4)
CHANGE OF NAME Recorded Jul 29, 2025
From: BARRMAX CORP.
To: BARRDAY LTD.
Reel/Frame 072266/0424 →
SECURITY INTEREST Recorded Aug 6, 2024
From: BARRMAX CORP.
To: THE TORONTO-DOMINION BANK
Reel/Frame 068198/0494 →
NUNC PRO TUNC ASSIGNMENT Recorded Jan 11, 2024
From: TEIJIN ARAMID B.V.
To: BARRMAX CORP.
Reel/Frame 066104/0028 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Dec 17, 2010
From: PETERS, MARTINUS WILHELMUS MARIA GEMMA
To: TEIJIN ARAMID B.V.
Reel/Frame 025591/0988 →
Priority Claims (1)
EP 08158581 · Jun 19, 2008 · regional
Continuity (1)
Related Publication 20110095447A1 · Apr 28, 2011