Polymers modified by silanes
View Patent ↗The invention relates to a process for grafting hydrolysable silane groups to a polyolefin, comprising reacting the polyolefin with an unsaturated silane, containing an olefinic —C═C— bond or acetylenic —C≡C— bond and having at least one hydrolysable group bonded to Si, or a hydrolysate thereof, in the presence of means capable of generating free radical sites in the polymer. The silane contains an aromatic ring or a further olefinic double bond or acetylenic unsaturation, the aromatic ring or the further olefinic double bond or acetylenic unsaturation being conjugated with the olefinic —C═C— or acetylenic —C≡C— unsaturation of the silane. The unsaturated silane may also contains electron-withdrawing moiety with respect to the olefinic —C═C— or acetylenic —C≡C— bond. The invention permits to provide a silane-modified polyolefin having a high grafting efficiency while limiting/preventing polymer degradation by chain scission. The silane-modified polyolefin can be further reacted with a polar surface, a filler or a polar polymer or reacted on itself to crosslink the polyolefin and obtain enhanced physical properties of the composites made thereof.
1. A process for grafting hydrolysable silane groups to a polyolefin, the process comprising reacting the polyolefin with a sorbyloxyalkylsilane having at least one hydrolysable group bonded to Si, in the presence of means capable of generating free radical sites in the polyolefin.
2. A process according to claim 1 characterised in that the polyolefin comprises at least 50% by weight units of an alpha-olefin having 3 to 8 carbon atoms.
3. A process according to claim 2 characterised in that the polyolefin is polypropylene.
4. A process according to claim 1 characterised in that the hydrolysable group of the silane has the formula —SiR a R′ (3-a) wherein R represents a hydrolysable group; R′ represents a hydrocarbyl group having 1 to 6 carbon atoms; and a has a value in the range 1 to 3 inclusive.
5. A process according to claim 1 characterised in that the sorbyloxyalkylsilane is partially hydrolyzed and condensed into oligomers.
6. A process according to claim 1 wherein the sorbyloxyalkylsilane is γ-sorbyloxypropyltrimethoxysilane.
7. A process according to claim 1 characterised in that the sorbyloxyalkylsilane is present at 0.5 to 20.0% by weight based on the total composition.
8. A process according to claim 1 characterised in that an organic peroxide compound capable of generating free radical sites in the polymer is present in the composition in an amount of 0.01 to 2% by weight based on the total composition.
9. A process for grafting hydrolysable silane groups to a polyolefin, the process comprising treating the polyolefin with an electron beam in the presence of sorbyloxyalkylsilane having at least one hydrolysable group bonded to Si.
10. A process according to claim 1 characterised in that the sorbyloxyalkylsilane is deposited on a filler before being reacted with the polymer.
11. A process according to claim 1 characterised in that the polymer, sorbyloxyalkylsilane and filler are reacted in situ.
12. A process for carrying out the crosslinking of a polymer, characterized in that the grafted polyolefin prepared by the process according to claim 1 is exposed to moisture optionally in the presence or absence of a silanol condensation catalyst.
13. A process according to claim 12 characterized in that the grafted polyolefin is shaped into an article and subsequently crosslinked by exposure to moisture.
14. A process for forming a foamed polymer, characterized by adding a blowing agent, moisture and condensation catalyst together to the grafted polyolefin prepared by the process according to claim 1 .