IP Library Granted Patent US 8,409,535
Granted Patent B2
US 8,409,535 · App. 13/006,554 · Granted Apr 2, 2013

System and method for removing a contaminant from a gas stream

Inventors: Brian Benn (Santa Rosa, CA); Allen Sonneville (Keleyville, CA); John Farison (Santa Rosa, CA); John Avery (Cloverdale, CA); Tom Bahning (Santa Rosa, CA); Bruce Carlsen (Healdsburg, CA)
Assignee: Calpine Corporation
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Quick Facts
Patent No.
US 8,409,535
App. No.
13/006,554
Granted
Apr 2, 2013
Kind
B2
Abstract

A system and method for removing contaminants from a gas stream is provided. The method can include the steps of reacting the gas stream with ozone to form solid contaminant particles and separating the solid contaminant particles from the gas stream. The solid contaminant particles can be separated from the gas stream using an adsorption material.

Claims (18)

1. A method for removing mercury and hydrogen sulfide from a non-condensable gas stream, the method comprising:

removing at least a portion of the hydrogen sulfide from the non-condensable gas stream to form a gas stream comprising less than about 0.1% hydrogen sulfide;

reacting the gas stream with ozone to form mercury sulfide; and

separating the mercury sulfide from the gas stream.

2. The method according to claim 1 , further comprising adsorbing the mercury sulfide onto an adsorption material.

3. The method according to claim 2 , wherein the adsorption material is selected from a group consisting of a plastic packaging material, plastic spheres and glass beads.

4. The method according to claim 2 , wherein a temperature of the adsorption material is below a temperature of the gas stream.

5. The method according to claim 4 , wherein the temperature of the adsorption material is in a range of 25° Celsius to 95° Celsius.

6. The method according to claim 1 , wherein the at least a portion of the hydrogen sulfide is removed from the non-condensable gas stream with a hydrogen sulfide abatement system.

7. The method according to claim 1 , wherein the hydrogen sulfide is removed before the step of admixing the ozone with the hydrogen sulfide.

8. The method according to claim 1 , wherein the hydrogen sulfide is removed after the step of admixing the ozone with the hydrogen sulfide.

9. The method according to claim 1 , wherein the hydrogen sulfide is contacted with an aqueous alkaline solution to form a hydrogen sulfide precipitate.

10. The method according to claim 1 , further comprising generating the ozone on-site.

11. The method according to claim 1 , wherein the non-condensable gas stream is geothermal steam.

12. The method according to claim 1 , wherein an effective amount of ozone sufficient to achieve complete reaction of mercury is reacted with the gas stream.

13. The method according to claim 1 , wherein a concentration of ozone reacted with the gas stream is in a range of 1 ppmv to 100 ppmv.

14. The method according to claim 1 , wherein the gas stream is mixed with the ozone at a temperature in a range of 50° Celsius to 180° Celsius.

15. The method according to claim 1 , wherein the gas stream is mixed with the ozone at a pressure in a range of 1 ATM to 10 ATM.

Assignments (2)
SECURITY AGREEMENT Recorded Apr 1, 2016
From: CALPINE CORPORATION
To: MUFG UNION BANK, N.A., AS COLLATERAL AGENT
Reel/Frame 038249/0147 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Jan 14, 2011
From: BENN, BRIAN; SONNEVILLE, ALLEN; FARISON, JOHN; AVERY, JOHN; BAHNING, TOM; CARLSEN, BRUCE
To: CALPINE CORPORATION
Reel/Frame 025639/0189 →
Continuity (2)
Provisional Application 61409861 · Nov 3, 2010
Related Publication 20120183461A1 · Jul 19, 2012