IP Library Granted Patent US 8,268,234
Granted Patent B2
US 8,268,234 · App. 13/016,459 · Granted Sep 18, 2012

Cermets from molten metal infiltration processing

Assignee: Lawrence Livermore National Security, LLC
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Quick Facts
Patent No.
US 8,268,234
App. No.
13/016,459
Granted
Sep 18, 2012
Kind
B2
Abstract

New cermets with improved properties and applications are provided. These new cermets have lower density and/or higher hardness than B4C cermet. By incorporating other new ceramics into B4C powders or as a substitute for B4C, lower densities and/or higher hardness cermets result. The ceramic powders have much finer particle size than those previously used which significantly reduces grain size of the cermet microstructure and improves the cermet properties.

Claims (16)

1. A method for fabricating a cermet, comprising:

providing a ceramic powder comprising nano-powder size particles;

sintering said ceramic powder at a sintering temperature to produce a porous ceramic preform matrix; and

infiltrating said matrix with a metal alloy to produce a cermet, wherein said ceramic powder comprises a blend of boron carbide, aluminum horde and magnesium boride, the method further comprising cold pressing said blend to greater than 55% density, wherein the step of sintering is carried out in a protective environment.

2. The method of claim 1 , wherein said nano-powder size particles comprise a particle size within a range from about 40 nm to about 900 nm.

3. The method of claim 2 , wherein said size of each particle of said particles is about the same as that of all other said particles.

4. The method of claim 1 , wherein said matrix comprises a porosity within a range from about 20% to about 50%.

5. The method of claim 1 , wherein the step of infiltrating said matrix comprises heating said metal alloy to at least its melting temperature.

6. The method of claim 5 , wherein said melting temperature is less than said sintering temperature.

7. The method of claim 1 , wherein said alloy is selected from the group consisting of Al, Mg, Be, Li, Ti and V.

8. The method of claim 1 , wherein said alloy comprises a density of less than 2.8 gm cc.

9. The method of claim 8 , wherein said alloy is able to wet said matrix at a temperature of less than 1150° C.

10. The method of claim 8 , wherein said alloy is able to wet said matrix at a temperature of less than 1150° C. within an infiltration period of less than 3 hours.

11. The method of claim 1 , wherein said metal alloy and said particle sizes are selected in combination so that said particles remain of about the same size following the step of sintering.

12. The method of claim 1 , wherein the step of infiltrating infiltrates said matrix greater than 98%.

13. The method of claim 1 , further comprising heat treating said cermet to adjust the properties of said cermet for a specific application.

Assignments (2)
CONFIRMATORY LICENSE Recorded Apr 11, 2011
From: LAWRENCE LIVERMORE NATIONAL SECURITY, LLC
To: U.S. DEPARTMENT OF ENERGY
Reel/Frame 026101/0940 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Mar 14, 2011
From: LANDINGHAM, RICHARD LEE
To: LAWRENCE LIVERMORE NATIONAL SECURITY, LLC
Reel/Frame 025951/0525 →
Continuity (3)
Continuation In Part 10260121 · Sep 27, 2002
Continuation In Part 08829034 · Mar 31, 1997
Related Publication 20120153548A1 · Jun 21, 2012