Method for producing sintered cubic boron nitride compact
A method for producing a highly uniform and highly dense sintered cubic boron nitride compact having high hardness by sintering at a milder condition without a binder, is provided. The method includes deflocculating secondary particles in cubic boron nitride starting powders by dispersing the starting powders in a solution of a deflocculant; molding the green compact after removing the solution of the deflocculant from the starting powders; and then sintering the green compact in the presence of a supercritical fluid source in a supercritical state by pressing and heating the green compact together with the supercritical fluid source. The supercritical fluid source can be one or more selected from a group consisted of polyvinylidene chloride, polyvinyl chloride, polyethylene, polypropylene, polystyrene, a polyester and an ABS resin. In the sintering, the pressure is 5 GPa or higher, and the temperature is 1400° C. or higher. According to the method, a highly uniform and highly dense sintered cubic boron nitride sintered compact having high hardness, can be obtained.
1. A method for producing a sintered cubic boron nitride compact, the method comprising:
a step of deflocculating, in which secondary particles in boron nitride starting powders are deflocculated by dispersing the boron nitride starting powders in a solution of a deflocculant to be a dispersion liquid;
a step of removing, in which the solution of deflocculant is removed from the dispersion liquid after the step of deflocculating;
a step of molding, in which the boron nitride starting powders, which have been deflocculated, are molded to form a green compact after the step of removing; and
a step of sintering, in which the green compact is pressurized at 5 GPa or higher and heated at 1400° C. or higher in the presence of a supercritical fluid source, the supercritical fluid source is put into a supercritical state, and the green compact is sintered, after the step of molding,
wherein a content ratio of the deflocculant in the dispersion liquid ranges from 0.1 to 5 wt % of a sum of the deflocculant and the cubic boron nitride starting powders as a weight.
2. A method for producing a sintered cubic boron nitride compact according to claim 1 ,
wherein the deflocculant is one or more selected from a group consisting of an alkali metal phosphate salt, an alkali metal carbonate salt, an alkali metal silicate salt, an alkali metal aluminate salt, and an alkali metal hydroxide.
3. A method for producing a sintered cubic boron nitride compact according to claim 2 ,
wherein, the deflocculant is one or more selected from a group consisting of sodium phosphate, sodium polyphosphate, sodium metaphosphate, sodium carbonate, sodium silicate, sodium aluminate and sodium hydroxide.
4. A method for producing a sintered cubic boron nitride compact according to claim 3 ,
wherein the deflocculant is sodium metaphosphate.
5. A method for producing a sintered cubic boron nitride compact according to claim 1 ,
wherein the supercritical fluid source is one or more selected from a group consisting of polyvinylidene chloride, polyvinyl chloride, polyethylene, polypropylene, polystyrene, a polyester and an ABS resin.
6. A method for producing a sintered cubic boron nitride compact according to claim 2 ,
wherein the supercritical fluid source is one or more selected from a group consisting of polyvinylidene chloride, polyvinyl chloride, polyethylene, polypropylene, polystyrene, a polyester and an ABS resin.
7. A method for producing a sintered cubic boron nitride compact according to claim 3 ,
wherein the supercritical fluid source is one or more selected from a group consisting of polyvinylidene chloride, polyvinyl chloride, polyethylene, polypropylene, polystyrene, a polyester and an ABS resin.
8. A method for producing a sintered cubic boron nitride compact according to claim 4 ,
wherein the supercritical fluid source is one or more selected from a group consisted of polyvinylidene chloride, polyvinyl chloride, polyethylene, polypropylene, polystyrene, a polyester and an ABS resin.
9. A method for producing a sintered cubic boron nitride compact according to claim 1 , further comprising:
a step of eliminating by vacuuming and heating, in which the deflocculant remaining in the green compact is eliminated by heating the green compact under a vacuum, after the step of molding and before the step of sintering.
10. A method for producing a sintered cubic boron nitride compact according to claim 1 ,
wherein the green compact, a metal foil, and the supercritical fluid source are stacked in a capsule after the step of molding and before the step of sintering, and
the metal foil is made of one or more selected from a group consisting of Zr, Nb, Mo, and Ta.
11. A method for producing a sintered cubic boron nitride compact according to claim 1 ,
wherein a mass ratio of the supercritical fluid source to the cubic boron nitride starting powder ranges from 0.02 to 0.2 wt %.