Methods of forming polycrystalline compacts
Methods of forming a polycrystalline compact using at least one metal salt as a sintering aid. Such methods may include forming a mixture of the at least one metal salt and a plurality of grains of hard material and sintering the mixture to form a hard polycrystalline material. During sintering, the metal salt may melt or react with another compound to form a liquid that acts as a lubricant to promote rearrangement and packing of the grains of hard material. The metal salt may, thus, enable formation of hard polycrystalline material having increased density, abrasion resistance, or strength. The metal salt may also act as a getter to remove impurities (e.g., catalyst material) during sintering. The methods may also be employed to faun cutting elements and earth-boring tools.
1. A method of forming a polycrystalline compact, the method comprising: combining a plurality of diamond particles with lithium fluoride to form a powder mixture comprising the diamond particles and the lithium fluoride substantially homogeneously dispersed on the diamond particles; and sintering the powder mixture comprising the diamond particles and the lithium fluoride, wherein combining a plurality of diamond particles with fluoride comprises combining the plurality of diamond particles with the lithium fluoride dispersed in an organic solvent.
2. The method of claim 1 , wherein combining a plurality of diamond particles with lithium fluoride comprises dispersing the plurality of diamond particles with particles of the lithium fluoride in an organic solvent.
3. The method of claim 1 , wherein combining a plurality of diamond particles with lithium fluoride comprises combining a plurality of diamond particles with a solution comprising the lithium fluoride dissolved in a polar solvent.
4. The method of claim 1 , wherein combining a plurality of diamond particles with lithium fluoride to form a powder mixture comprises:
combining the plurality of diamond particles with the lithium fluoride in at least one solvent to form a slurry; and
subjecting the slurry to a spray-drying process to form the powder mixture.
5. The method of claim 1 , wherein combining a plurality of diamond particles with lithium fluoride to form a powder mixture comprises subjecting the plurality of diamond particles and a plurality of particles of the lithium fluoride to a milling process.
6. The method of claim 1 , wherein sintering the powder mixture comprising the diamond particles and the lithium fluoride comprises fully sintering the powder mixture comprising the diamond particles and the lithium fluoride to form a hard polycrystalline material comprising interbonded hard particles of the plurality.
7. The method of claim 6 , further comprising leaving at least a portion of the lithium fluoride within interstitial spaces between the interbonded hard particles of the plurality.
8. The method of claim 1 , wherein sintering the powder mixture comprising the diamond particles and the lithium fluoride comprises removing at least a portion of the lithium fluoride from interstitial spaces between the diamond particles.
9. The method of claim 8 , wherein removing at least a portion of the lithium fluoride from interstitial spaces between the diamond particles comprises reacting fluorine of the lithium fluoride with at least one catalyst material in contact with the powder mixture.
10. The method of claim 1 , wherein sintering the powder mixture comprising the diamond particles and the lithium fluoride comprises heating the powder mixture to form liquid lithium fluoride between diamond particles of the plurality.
11. The method of claim 1 , further comprising molding the powder mixture comprising the diamond particles and the lithium fluoride to form an unsintered preform.
12. The method of claim 1 , wherein sintering the powder mixture comprising the diamond particles and the lithium fluoride comprises reacting a silicon material with fluorine of the lithium fluoride.
13. A method of forming a polycrystalline compact, comprising:
forming an unsintered compact preform, comprising:
mixing a solution comprising lithium fluoride with a plurality of diamond grains to form a powder mixture comprising a plurality of coated diamond grains comprising a coating of the lithium fluoride; and
disposing the powder mixture within a container;
disposing a cutting element substrate in contact with the powder mixture; and
sintering the unsintered compact perform.
14. The method of claim 13 , further comprising evaporating a solvent from the solution comprising the lithium fluoride.
15. The method of claim 13 , further comprising exposing the polycrystalline compact to a temperature sufficient to volatilize the lithium fluoride under vacuum pressure to remove a residual portion of the lithium fluoride from the polycrystalline compact.
16. The method of claim 13 , wherein disposing the powder mixture within a container comprises disposing the powder mixture in contact with a silicon material proximate an inner surface of the container.
17. The method of claim 13 , wherein sintering the unsintered compact perform comprises heating the unsintered compact preform to melt the lithium fluoride to form a liquid that occupies interstitial spaces between the diamond grains.
18. The method of claim 17 , wherein heating the unsintered compact preform to melt the lithium fluoride to form a liquid that occupies interstitial spaces between the diamond grains comprises lubricating the interstitial spaces between the diamond grains to promote rearrangement of the diamond grains.