IP Library Granted Patent US 8,388,861
Granted Patent B2
US 8,388,861 · App. 13/049,905 · Granted Mar 5, 2013

Liquid crystal compound and liquid crystal mixture

Inventors: Chun-Chih Wang (Taichung, TW); Wen-Chung Chu (Kaohsiung, TW); Ren-Jie Chiou (Kaohsiung, TW); Shi-Zhi You (Beijing, CN); Hong-Wei Zhang (Hebei Province, CN); Yu-Dong Tan (Hebei Province, CN)
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Quick Facts
Patent No.
US 8,388,861
App. No.
13/049,905
Granted
Mar 5, 2013
Kind
B2
Abstract

A LC compound and a LC mixture are provided. The LC mixture includes a compound represented by (I) and at least one compound selected from a group consisting of compounds represented by (II) to (IV): in which X 1 is F, —Cl, —CF3, or —OCF 3 ; R, R11, and R12 are independently H, a C1-C15 alkyl group, or a C2-C15 alkenyl group; A1 is 1,4-phenylene; A 11 , A 12 , A 13 , and A 14 are independently selected from a group consisting of 1,4-phenylene, 1,4-cyclohexylene, and 2,5-tetrahydropyranylene; at least one of A2, A3, and A4 is 2,5-indanylene, and the others are independently selected from a group consisting of 1,4-phenylene, 1,4-cyclohexylene, and 2,5-tetrahydropyranylene; L 1 is —F 2 CO—; Z 11 , Z 12 , and Z 13 are independently a single bond, —O—, —F 2 CO—, or —COO—; m is 1; n, o and p are independently 0, 1, 2 or 3, and n+o+p≧3.

Claims (37)

1. A liquid crystal mixture, comprising:

a compound represented by Formula (I):

and

at least one compound selected from a group consisting of compounds represented by Formulas (II) to (IV):

wherein X 1 is F, Cl, —CF3 or —OCF 3 ; R, R11 and R12 are independently H, a C1-C15 alkyl group, or a C2-C15 alkenyl group; A1 is 1,4-phenylene; A 11 , A 12 , A 13 and A 14 are independently selected from a group consisting of 1,4-phenylene, 1,4-cyclohexylene, and 2,5-tetrahydropyranylene; at least one of A2, A3 and A4 is 2,5-indanylene, and the others are independently selected from a group consisting of 1,4-phenylene, 1,4-cyclohexylene, and 2,5-tetrahydropyranylene; L 1 is —F 2 CO—; Z 11 , Z 12 , and Z 13 are independently a single bond, —O—, —F 2 CO—, or —COO—; m is 1; and n, o, and p are independently an integer of 0 to 3, and n+o+p≧3.

2. The liquid crystal mixture according to claim 1 , wherein X 1 is F or —OCF 3 .

3. The liquid crystal mixture according to claim 1 , wherein the C1-C15 alkyl group comprises an unsubstituted C1-C15 alkyl group or a C1-C15 alkyl group substituted with —O—, —CO—, or —COO—.

4. The liquid crystal mixture according to claim 1 , wherein the C2-C15 alkenyl group comprises an unsubstituted C2-C15 alkenyl group or a C2-C15 alkenyl group substituted with —O—, —CO—, or —COO—.

5. The liquid crystal mixture according to claim 1 , wherein 1,4-phenylene comprises unsubstituted 1,4-phenylene or 1,4-phenylene substituted with at least one F or Cl.

6. The liquid crystal mixture according to claim 1 , wherein 1,4-cyclohexylene comprises unsubstituted 1,4-cyclohexylene or 1,4-cyclohexylene substituted with at least one F or Cl.

7. The liquid crystal mixture according to claim 1 , wherein 2,5-tetrahydropyranylene comprises unsubstituted 2,5-tetrahydropyranylene or 2,5-tetrahydropyranylene substituted with at least one F or Cl.

8. The liquid crystal mixture according to claim 1 , wherein 2,5-indanylene comprises unsubstituted 2,5-indanylene or 2,5-indanylene substituted with at least one F or Cl.

9. The liquid crystal mixture according to claim 1 , wherein based on the total weight of the liquid crystal mixture, a content of the compound represented by Formula (I) is between 10 wt % and 40 wt %.

10. The liquid crystal mixture according to claim 1 , wherein based on the total weight of the liquid crystal mixture, a content of the at least one compound selected from the group consisting of the compounds represented by Formulas (II) to (IV) is between 10 wt % and 50 wt %.

11. A liquid crystal mixture, comprising:

a compound represented by Formula (I):

and

at least one compound selected from a group consisting of compounds represented by Formulas (V) to (VII):

wherein X 1 , X 21 , X 22 , and X 23 are independently F, Cl, —CF 3 , or —OCF 3 ; R and R21 are independently H, a C1-C15 alkyl group, or a C2-C15 alkenyl group; A1 is 1,4-phenylene; A 21 , A 22 , and A 23 are independently selected from a group consisting of 1,4-phenylene, 1,4-cyclohexylene, and 2,5-tetrahydropyranylene; at least one of A2, A3 and A4 is 2,5-indanylene, and the others are independently selected from a group consisting of 1,4-phenylene, 1,4-cyclohexylene, and 2,5-tetrahydropyranylene; L 1 is —F 2 CO—; Z 21 and Z 22 are independently a single bond, —O—, —F 2 CO—, or —COO—; m is 1; and n, o, and p are independently an integer of 0 to 3, and n+o+p≧3.

12. The liquid crystal mixture according to claim 11 , wherein X 1 , X 21 , X 22 , and X 23 are independently F or —OCF 3 .

13. The liquid crystal mixture according to claim 11 , wherein the C1-C15 alkyl group comprises an unsubstituted C1-C15 alkyl group or a C1-C15 alkyl group substituted with —O—, —CO—, or —COO—.

14. The liquid crystal mixture according to claim 11 , wherein the C2-C15 alkenyl group comprises an unsubstituted C2-C15 alkenyl group or a C2-C15 alkenyl group substituted with —O—, —CO—, or —COO—.

15. The liquid crystal mixture according to claim 11 , wherein 1,4-phenylene comprises unsubstituted 1,4-phenylene or 1,4-phenylene substituted with at least one F or Cl.

16. The liquid crystal mixture according to claim 11 , wherein 1,4-cyclohexylene comprises unsubstituted 1,4-cyclohexylene or 1,4-cyclohexylene substituted with at least one F or Cl.

17. The liquid crystal mixture according to claim 11 , wherein 2,5-tetrahydropyranylene comprises unsubstituted 2,5-tetrahydropyranylene or 2,5-tetrahydropyranylene substituted with at least one F or Cl.

18. The liquid crystal mixture according to claim 11 , wherein 2,5-indanylene comprises unsubstituted 2,5-indanylene or 2,5-indanylene substituted with at least one F or Cl.

19. The liquid crystal mixture according to claim 11 , wherein based on the total weight of the liquid crystal mixture, a content of the compound represented by Formula (I) is between 10 wt % and 40 wt %.

20. The liquid crystal mixture according to claim 11 , wherein based on the total weight of the liquid crystal mixture, the content of the at least one compound selected from the group consisting of the compounds represented by Formula (V) to Formula (VII) is between 10 wt % and 50 wt %.

21. A liquid crystal compound, represented by Formula (I):

wherein X 1 is F, Cl, —CF 3 or —OCF 3 ; L 1 is —F 2 CO—; R is H, a C1-C15 alkyl group, or a C2-C15 alkenyl group; A1 is 1,4-phenylene; at least one of A2, A3 and A4 is 2,5-indanylene, and the others are independently selected from a group consisting of 1,4-phenylene, 1,4-cyclohexylene, and 2,5-tetrahydropyranylene; m is 1; and n, o, and p are independently an integer of 0 to 3, and n+o+p≧3.

22. The liquid crystal compound according to claim 21 , wherein X 1 is F or —OCF 3 .

23. The liquid crystal compound according to claim 21 , wherein the C1-C15 alkyl group comprises an unsubstituted C1-C15 alkyl group or a C1-C15 alkyl group substituted with —O—, —CO—, or —COO—.

24. The liquid crystal compound according to claim 21 , wherein the C2-C15 alkenyl group comprises an unsubstituted C2-C15 alkenyl group or a C2-C15 alkenyl group substituted with —O—, —CO—, or —COO—.

25. The liquid crystal compound according to claim 21 , wherein 1,4-phenylene comprises unsubstituted 1,4-phenylene or 1,4-phenylene substituted with at least one F or Cl.

26. The liquid crystal compound according to claim 21 , wherein 1,4-cyclohexylene comprises unsubstituted 1,4-cyclohexylene or 1,4-cyclohexylene substituted with at least one F or Cl.

27. The liquid crystal compound according to claim 21 , wherein 2,5-tetrahydropyranylene comprises unsubstituted 2,5-tetrahydropyranylene or 2,5-tetrahydropyranylene substituted with at least one F or Cl.

28. The liquid crystal compound according to claim 21 , wherein 2,5-indanylene comprises unsubstituted 2,5-indanylene or 2,5-indanylene substituted with at least one F or Cl.

Assignments (3)
CHANGE OF ADDRESS OF 2ND ASSIGNEE Recorded Apr 14, 2023
From: JIANGSU HECHENG DISPLAY TECHNOLOGY CO., LTD.
To: JIANGSU HECHENG DISPLAY TECHNOLOGY CO., LTD.
Reel/Frame 063333/0020 →
CHANGE OF NAME Recorded Jun 29, 2012
From: JIANGSU HECHENG CHEMICAL MATERIALS CO., LTD.
To: DAXIN MATERIALS CORPORATION; JIANGSU HECHENG DISPLAY TECHNOLOGY CO.,LTD.
Reel/Frame 028466/0283 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Mar 22, 2011
From: WANG, CHUN-CHIH; CHU, WEN-CHUNG; CHIOU, REN-JIE; YOU, SHI-ZHI; ZHANG, HONG-WEI; TAN, YU-DONG
To: DAXIN MATERIALS CORPORATION; JIANGSU HECHENG CHEMICAL MATERIALS CO., LTD.
Reel/Frame 025994/0004 →
Priority Claims (1)
CN 2010 1 0558887 · Nov 25, 2010 · national
Continuity (1)
Related Publication 20120132854A1 · May 31, 2012