IP Library Granted Patent US 9,879,204
Granted Patent B2
US 9,879,204 · App. 13/050,491 · Granted Jan 30, 2018

Liquid cleaning compositions with lower freezing point

Inventors: Frederick W. Holzhauer (Novato, CA); Kaj Johnson (Livermore, CA)
Assignee: METHOD PRODUCTS, PBC
C11D1/83C11D3/2075C11D3/30
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Quick Facts
Patent No.
US 9,879,204
App. No.
13/050,491
Granted
Jan 30, 2018
Kind
B2
Abstract

A cleaning composition according to one embodiment includes a surfactant system comprising a nonionic surfactant in combination with an anionic surfactant; and an amine neutralized organic acid (ANOA). A concentrated composition according to yet another embodiment includes an amine neutralized organic acid (ANOA) present in an effective amount to lower a freezing point of the concentrated composition, wherein the ANOA is present at no more than about 5 wt % based on a total weight of the concentrated composition. A concentrated cleaning composition in yet another embodiment includes a surfactant system having an invert structure, the surfactant system comprising a nonionic surfactant in combination with an anionic surfactant; an organic acid present in a concentration of greater than 0 to about 5 wt % based on a total weight of the cleaning composition; and an alkaline component. Methods of making are also disclosed.

Claims (36)

1. A cleaning composition, comprising:

a surfactant system comprising a nonionic surfactant in combination with an anionic surfactant, wherein the surfactant system has an invert structure; and

an amine neutralized organic acid (ANOA), wherein the ANOA is selected from a group consisting of monoisopropylamine (MIPA) citrate, MIPA lactate, monoethanolamine (MEA) lactate, and triethanolamine (TEA) lactate, wherein the ANOA is present in a concentration of greater than 0 to less than or equal to-5 wt % based on a total weight of the cleaning composition.

2. A cleaning composition comprising:

a surfactant system comprising a nonionic surfactant in combination with an anionic surfactant, wherein the surfactant system has an invert structure; and

an amine neutralized organic acid (ANOA), wherein the ANOA comprises 2 parts by weight of monoisopropylamine (MIPA) and 3 parts by weight of lactic acid.

3. The cleaning composition of claim 1 , wherein the ANOA is created from an alcohol amine.

4. The cleaning composition of claim 1 , wherein the nonionic surfactant is present in an amount ranging from 15 to 60 wt % based on a total weight of the cleaning composition, and the anionic surfactant is present in an amount ranging from 15 to 55 wt % based on the total weight of the cleaning composition.

5. The cleaning composition of claim 1 , wherein the surfactant system further comprising an antiredeposition agent selected from a group consisting of: polyvinylpyrrolidone; poly-4-vinylpyridine-N-oxide (PVnO); polyvinyl acetate; and combinations thereof.

6. The cleaning composition of claim 1 , further comprising at least one enzyme present in an amount greater than 5 wt % to less than or equal to about 15 wt % based on a total weight of the cleaning composition.

7. The cleaning composition of claim 1 , wherein the cleaning composition is in a form of a single water-in-oil emulsion.

8. The cleaning composition of claim 1 , wherein a weight ratio of the nonionic surfactant to the anionic surfactant is from about 1 to about 4.

9. The cleaning composition of claim 1 , further comprising water present at about 50 wt % or less.

10. The cleaning composition of claim 9 , further comprising a solvent system comprising: a polyalcohol present in an amount from about 3 to about 26 wt %, and a methyl ether of a polyalcohol present in an amount from greater than 0 to less than or equal to about 10 wt %, wherein the solvent system is present in an amount effective to solubilize the surfactant system in the water.

11. The cleaning composition of claim 1 , which does not comprise any ingredient that is not environmental friendly.

12. A method of making a cleaning composition,

the method comprising:

adding a surfactant system comprising a nonionic surfactant in combination with an anionic surfactant, wherein a total amount of the nonionic surfactant is in a range from 15 to 60 wt % based on a total weight of the cleaning composition, wherein a total amount of the anionic surfactant is in a range from 15 to 55 wt % based on the total weight of the cleaning composition, wherein the surfactant system has an invert structure; and

adding an amine neutralized organic acid (ANOA) for lowering a freezing point of the cleaning composition), wherein a total amount of the ANOA is in a range from greater than 0 to less than or equal to 5 wt % based on a total weight of the cleaning composition,

wherein the cleaning composition is a form of a single water-in-oil emulsion.

13. The method of claim 12 , further comprising forming the ANOA by combining 2 parts by weight of monoisopropylamine (MIPA) and 3 parts by weight of lactic acid.

14. The method of claim 12 , wherein the surfactant system further comprises at least one of an amphoteric surfactant and an anionic polymer with dispersing property.

15. A concentrated composition, comprising:

an amine neutralized organic acid (ANOA) present in an effective amount to lower a freezing point of the concentrated composition, wherein the ANOA is selected from a group consisting of monoisopropylamine (MIPA) citrate, MIPA lactate, and monoethanolamine (MEA) lactate, wherein the ANOA is present at no more than about 5 wt % based on a total weight of the concentrated composition,

wherein a surfactant system in the concentrated composition has an invert structure.

16. The concentrated composition of claim 15 , wherein the concentrated composition is considered readily biodegradable according to the OECD 301F biodegradability standard.

17. The concentrated composition of claim 15 , further comprising water present at about 50 wt % or less.

18. The concentrated composition of claim 15 , further comprising a non-phosphate builder in an amount from greater than 0 to less than or equal to about 15 wt %, wherein the non-phosphate builder is selected from a group consisting of: ethylenediaminetetraacetic acid (EDTA), nitriloacetic acid, sodium polyaspartate, a borate, and combinations thereof.

19. The concentrated composition of claim 15 , wherein the concentrated composition is selected from a group consisting of a concentrated cleaner, a concentrated hand or body wash, a concentrated lotion, a concentrated stain treatment, and a concentrated carpet treatment.

20. A concentrated cleaning composition, comprising:

a surfactant system having an invert structure, the surfactant system comprising a nonionic surfactant in combination with an anionic surfactant;

an organic acid present in a concentration of greater than 0 to about 5 wt % based on a total weight of the cleaning composition, wherein the organic acid is selected from a group consisting of monoisopropylamine (MIPA) citrate, MIPA lactate, and monoethanolamine (MEA) lactate; and

an alkaline component.

21. The concentrated composition of claim 20 , wherein the concentration of the organic acid is below a level that would provide chlorine control for 3 parts per million chlorine in 69 liters of external water when a normal dose of the concentrated composition is added to 69 liters of external water.

22. The concentrated composition of claim 20 , wherein the alkaline component includes at least one of neutralized polyacrylic acid and sodium tripolyphosphate.

23. The method of claim 12 , wherein the ANOA is selected from a group consisting of monoisopropylamine (MIPA) citrate, MIPA lactate, monoethanolamine (MEA) lactate, and triethanolamine (TEA) lactate.

Assignments (5)
RELEASE OF SECURITY INTEREST Recorded Aug 31, 2018
From: U.S. BANK NATIONAL ASSOCIATION
To: METHOD PRODUCTS PBC
Reel/Frame 046765/0593 →
CHANGE OF NAME Recorded Apr 9, 2015
From: METHOD PRODUCTS, INC.
To: METHOD PRODUCTS, PBC
Reel/Frame 035402/0118 →
SECURITY AGREEMENT Recorded Aug 9, 2013
From: METHOD PRODUCTS, PBC
To: U.S. BANK NATIONAL ASSOCIATION, AS ADMINISTRATIVE AGENT
Reel/Frame 030994/0201 →
SECURITY AGREEMENT Recorded Jun 21, 2013
From: METHOD PRODUCTS, INC.
To: U.S. BANK NATIONAL ASSOCIATION, AS ADMINISTRATIVE AGENT
Reel/Frame 030666/0601 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Jun 27, 2011
From: JOHNSON, KAJ; HOLZHAUER, FREDERICK W.
To: METHOD PRODUCTS, INC.
Reel/Frame 026508/0664 →
Continuity (2)
Provisional Application 61314965 · Mar 17, 2010
Related Publication 20110230380A1 · Sep 22, 2011