Catalyst for preparing synthesis gas from natural gas and carbon dioxide, and preparation method thereof
Disclosed are a catalyst for preparing synthesis gas from natural gas and carbon dioxide, and a method for preparing the same. More particularly, a combined reforming process is performed as an economical way of using carbon dioxide, wherein steam reforming of natural gas is carried out simultaneously with carbon dioxide reforming of methane in such a manner that a predetermined ratio of carbon monoxide/carbon dioxide/hydrogen (H 2 /(2CO+3CO 2 )=0.85-1.15) is maintained. In this manner, the catalyst is used to prepare synthesis gas suitable for methanol synthesis and Fischer-Tropsch synthesis. Disclosed also is a method for preparing synthesis gas on a specific catalyst consisting of Ni/Ce/MgAlOx or Ni/Ce-Zr/MgAlOx. The catalyst is inhibited from deactivation caused by generation of cokes during the reaction as well as deactivation caused by reoxidation of nickel with water added during the reaction. Therefore, the catalyst shows excellent activity as compared to other catalysts for use in combined reforming.
1. A method for preparing synthesis gas, comprising:
carrying out a combined reforming process of steam and carbon dioxide reforming of natural gas, which reforms natural gas with steam and carbon dioxide simultaneously, on a catalyst obtained by reducing a catalyst for natural gas reforming which reforms natural gas with steam and carbon dioxide simultaneously with hydrogen gas at a temperature of 700-1000° C., under the conditions of a reaction temperature of 850-1000° C., reaction pressure of 0.5-20 atm, space velocity of 1,000-500,000 h −1 , and a molar ratio of CH 4 /H 2 O/CO 2 of 1/1.0-2.0/0.3-0.6,
wherein the catalyst comprises Ce/MgAlO x or Ce-Zr/MgAlO x , as a carrier comprising 3-20 wt % based on the carrier of Ce or Ce-Zr, respectively, carried on the MgAlO x having the weight ratio of MgO/Al 2 O 3 within the range of 3/7 to 7/3; and Ni, as an active ingredient, supported on the Ce/MgAlO x or Ce-Zr/MgAlO x carrier in an amount of 5-20 wt % based on the carrier, and has a specific surface area of 80-200 m 2 /g after calcining at a temperature of 600-1000° C.;
wherein the combined reforming process provides a CH 4 conversion and CO 2 conversion maintained at 80% or higher and 45% or higher, respectively, and a molar ratio of H 2 (2CO+3CO 2 ) is maintained at 0.85-1.15.
2. The method for preparing synthesis gas according to claim 1 , wherein the molar ratio of H 2 /(2CO+3CO 2 ) undergoes a change less than 2% under the conditions of the combined reforming process.