Method for preparing succinic acid
A method for preparing succinic acid, including producing a modified palladium-containing catalyst by using an acid and liquid-phase hydrogenation of unsaturated acid compounds on the modified catalyst at an increased temperature and pressure; separating the catalyst from the succinic acid; wherein the modification of the catalyst is performed on a substrate having the palladium-containing catalyst delivered thereon, the delivery being performed in an oxygen-free atmosphere; the delivery being performed in an aqueous medium of succinic, maleic or fumaric acids and/or their mixtures at a Pd 2+ /acid ratio of 1:1-1:100; hydrogenating the liquid-phase unsaturated acid compounds selected from maleic, fumaric acids or their anhydrides or their mixtures; and crystallizing the succinic acid from an aqueous solution containing 0.001-0.01 wt. % succinic acid seed.
1. A method for preparing succinic acid, comprising:
producing a modified palladium-containing catalyst by using an acid and liquid-phase hydrogenation of unsaturated acid compounds on the modified catalyst at a temperature of between 40 and 120 degrees C. and a pressure of 10-25 atm;
separating the catalyst from the succinic acid;
wherein the modification of the catalyst is performed on a substrate having the palladium-containing catalyst delivered thereon, the delivery being performed in an oxygen-free atmosphere;
the delivery being performed in an aqueous medium of succinic, maleic or fumaric acids and/or their mixtures at a Pd 2+ /acid ratio of 1:1-1:100;
hydrogenating the liquid-phase unsaturated acid compounds selected from maleic, fumaric acids or their anhydrides or their mixtures; and
crystallizing the succinic acid from an aqueous solution containing 0.001-0.01 wt. % succinic acid seed.
2. The method of claim 1 , wherein the oxygen-free atmosphere includes any of nitrogen, hydrogen, argon, helium and/or their mixture, and the process of modification occurs in a temperature range of 5 to 70 degrees Centigrade, and with a concentration of the catalyst aqueous solution in a range of 0.1 to 1.5 wt. %.
3. The method of claim 2 , wherein the process of modification is carried out at a temperature chosen from the range of 15 to 40 degrees Centigrade at the catalyst aqueous solution concentration within the range of 0.1 to 1.0 wt. % and a concentration of the modifying acid compound solution within the range of 0.01 to 0.7%.
4. The method of claim 1 , wherein the crystallization seed is a succinic acid of natural origin.
5. The method of claim 1 , wherein the crystallization seed is a synthetic succinic acid.
6. The method of claim 1 , wherein the crystallization seed is both a succinic acid of natural origin and a synthetic succinic acid.