Switching materials comprising mixed nanoscopic particles and carbon nanotubes and method of making and using the same
View Patent ↗An improved switching material for forming a composite article over a substrate is disclosed. A first volume of nanotubes is combined with a second volume of nanoscopic particles in a predefined ration relative to the first volume of nanotubes to form a mixture. This mixture can then be deposited over a substrate as a relatively thick composite article via a spin coating process. The composite article may possess improved switching properties over that of a nanotube-only switching article. A method for forming substantially uniform nanoscopic particles of carbon, which contains one or more allotropes of carbon, is also disclosed.
1. A method for forming a composite nanofabric article over a substrate, said method comprising:
combining a first volume of nanotubes with a second volume of nanoscopic particles at a predefined ratio relative to said first volume of nanotubes to form a mixture; and
depositing said mixture over said substrate to form the composite nanofabric article;
wherein said second volume of nanoscopic particles includes at least one of silicon nitride particles and multi-walled nanotubes.
2. The method of claim 1 , wherein the nanotubes comprising said first volume are substantially all carbon nanotubes.
3. The method of claim 1 wherein said second volume of nanoscopic particles includes nanoscopic particles containing at least one allotrope of carbon.
4. The method of claim 1 , wherein said second volume of nanoscopic particles includes silicon oxide particles.
5. The method of claim 1 , wherein substantially all of said nanoscopic particles within said second volume fall within a predetermined volume tolerance.
6. The method of claim 1 , wherein at least one of the magnitude of said first volume of nanotubes and the magnitude of said second volume of nanoscopic particles is selected to realize a desired volume density of nanotubes within said composite article.
7. The method of claim 1 , wherein the mixture is a homogeneous mixture.
8. The method of claim 1 , wherein the mixture is a heterogeneous mixture.
9. The method of claim 1 , wherein the composite nanofabric article has less than about 10 11 metal atoms/cm.
10. The method of claim 1 , wherein said depositing said mixture over said substrate is performed via a spin coat process.
11. A method of forming substantially uniform nanoscopic particles of carbon particles from a volume of carbon black material, said method comprising:
reacting said volume of carbon black material with an oxidizing agent to form a carbon slurry;
removing metallic contaminants from said carbon slurry by solubilizing said metallic contaminants;
filtering said carbon slurry to remove the solubilized metallic contaminants; increasing a pH level of the carbon slurry to obtain a colloidal system; and
filtering said colloidal system to obtain carbon particles which fall above a predetermined volume threshold; wherein said carbon particles contain one or more carbon allotropes.
12. The method of claim 11 , wherein said colloidal system is a homogeneous and stable colloidal system.
13. The method of claim 11 , wherein said colloidal system is a heterogeneous and stable colloidal system.
14. The method of claim 11 , wherein said oxidizing agent comprises nitric acid.
15. The method of claim 14 , wherein said increasing the pH level of the carbon slurry includes a sonication process.
16. A method for forming a switching device, said method comprising:
depositing a first electrode over a substrate,
depositing a first volume of nanotubes over said first electrode to form a layer of nanotubes,
depositing a second volume of nanoscopic particles, at a predefined ratio relative to said first volume of nanotubes, on said layer of nanotubes to form said composite article, and
depositing a second electrode over said composite article to form the switching device.
17. The method of claim 16 , wherein said second volume of nanoscopic particles is deposited using ion implantation.
18. The method of claim 16 , wherein said second volume of nanoscopic particles is deposited using vapor deposition.
19. The method of claim 16 , wherein said second volume of nanoscopic particles is deposited using sputtering.
20. The method of claim 16 , wherein said depositing a first volume of nanotubes is performed by spin coating.