Diffraction unlimited photolithography
Methods, devices, systems, and materials are disclosed for diffraction unlimited photofabrication. A method is provided where a photoresponsive material is illuminated with a first optical pattern at a first wavelength of light. The first wavelength of light alters a solubility of the photoresponsive organic material. The photoresponsive material is also illuminated with a second optical pattern at a second wavelength of light. The second wavelength of light hinders the ability of the first wavelength of light to alter the solubility of the photoresponsive organic material where the second optical pattern overlaps the first optical pattern. The photoresponsive organic material is then developed.
1. A method of photo fabrication, comprising:
illuminating a photoresponsive material with a first optical pattern at a first wavelength of light, wherein the first wavelength of light alters a solubility of the photoresponsive material through the interaction of the first wavelength of light with a photoinitiator of the photoresponsive material, and wherein the photoinitiator comprises a disulfide selected from the group consisting of tetraethylthiuram disulfide and bis(dialkylamino) disulfide;
illuminating the photoresponsive material with a second optical pattern at a second wavelength of light, wherein:
the second optical pattern overlaps the first optical pattern; and
the second wavelength of light hinders the ability of the first wavelength of light to alter the solubility of the photoresponsive material through the interaction of the second wavelength of light with a photoinhibitor of the photoresponsive material; and
developing the photoresponsive material.
2. The method of photo fabrication as in claim 1 , wherein the photoinitiator produces free radicals when illuminated with the first wavelength of light.
3. The method of photo fabrication of claim 2 , wherein the photoinhibitor traps free radicals when illuminated with the second wavelength of light.
4. The method of photo fabrication of claim 3 , wherein the photoinitiator comprises at least camphorquinone or ethyl 4-(dimethylamino)benzoate.
5. The method of photo fabrication as in claim 1 , wherein the second optical pattern comprises a Gauss-Laguerre pattern.
6. The method of photo fabrication as in claim 1 , wherein the second optical pattern comprises a Hermite-Gauss pattern.
7. The method of photo fabrication as in claim 1 , wherein illuminating the photoresponsive material utilizes a direct-write illumination system.
8. The method of photo fabrication as in claim 1 , wherein illuminating the photoresponsive material utilizes a mask-based illumination system.
9. A method of photo fabrication, comprising:
illuminating a photoresponsive material with a first optical pattern at a first wavelength of light, wherein the first wavelength of light alters a solubility of the photoresponsive material through the interaction of the first wavelength of light with a photoinitiator of the photoresponsive material;
illuminating the photoresponsive material with a second optical pattern at a second wavelength of light, wherein:
the second optical pattern comprises a Gaussian pattern;
the second optical pattern overlaps the first optical pattern; and
the second wavelength of light hinders the ability of the first wavelength of light to alter the solubility of the photoresponsive material through the interaction of the second wavelength of light with a photoinhibitor of the photoresponsive material; and
developing the photoresponsive material.
10. The method of photo fabrication as in claim 9 , wherein the photoinitiator produces free radicals when illuminated with the first wavelength of light.
11. The method of photo fabrication of claim 10 , wherein the photoinhibitor traps free radicals when illuminated with the second wavelength of light.
12. The method of photo fabrication as in claim 9 , wherein the second optical pattern comprises a Gauss-Laguerre pattern.
13. The method of photo fabrication as in claim 9 , wherein the second optical pattern comprises a Hermite-Gauss pattern.
14. The method of photo fabrication as in claim 9 , wherein illuminating the photoresponsive material utilizes a direct-write illumination system.
15. The method of photo fabrication as in claim 9 , wherein illuminating the photoresponsive material utilizes a mask-based illumination system.
16. A method of photo fabrication, comprising:
illuminating a photoresponsive material with a first optical pattern at a first wavelength of light, wherein the first wavelength of light alters a solubility of the photoresponsive material through the interaction of the first wavelength of light with a photoinitiator of the photoresponsive material;
illuminating the photoresponsive material with a second optical pattern at a second wavelength of light, wherein:
the second optical pattern comprises a pattern selected from the group consisting of a Gauss-Laguerre pattern and a Hermite-Gauss pattern;
the second optical pattern overlaps the first optical pattern; and
the second wavelength of light hinders the ability of the first wavelength of light to alter the solubility of the photoresponsive material through the interaction of the second wavelength of light with a photoinhibitor of the photoresponsive material; and
developing the photoresponsive material.
17. The method of photo fabrication as in claim 16 , wherein the photoinitiator produces free radicals when illuminated with the first wavelength of light.
18. The method of photo fabrication of claim 17 , wherein the photoinhibitor traps free radicals when illuminated with the second wavelength of light.
19. The method of photo fabrication of claim 18 , wherein the photoinitiator comprises at least camphorquinone or ethyl 4-(dimethylamino)benzoate.
20. The method of photo fabrication of 19 , wherein the photoinhibitor comprises tetraethylthiuram disulfide.
21. The method of photo fabrication of claim 19 , wherein the photoinhibitor comprises bis(dialkylamino) disulfide.
22. The method of photo fabrication as in claim 16 , wherein illuminating the photoresponsive material utilizes a direct-write illumination system.
23. The method of photo fabrication as in claim 16 , wherein illuminating the photoresponsive material utilizes a mask-based illumination system.