Tunable phosphor for luminescent
View Patent ↗The present disclosure provides an illuminating system including a light emitting diode (LED); and a tunable luminescent material disposed approximate the light-emitting diode, wherein the tunable luminescent material includes alkaline earth metal (AE) and silicon aluminum nitride doped by a rare earth element (RE), formulated as (AE)Si 6−p Al p N 8 , wherein p is a parameter defining a relative aluminum content in weight and p is greater than zero.
1. An illuminating system comprising:
a light emitting diode (LED); and
a tunable luminescent material disposed approximate the light emitting diode, wherein the tunable luminescent material includes alkaline earth metal (AE) and silicon aluminum nitride doped by a rare earth element (RE), formulated as (AE)Si 6−p Al p N 8 , wherein p is a parameter defining a relative aluminum content in weight and p is greater than zero, wherein the alkaline earth metal includes strontium (Sr), calcium (Ca), barium (Ba), or a combination thereof, and wherein the tunable luminescent material is formulated as (Sr 1−x−y Ca x Ba y ) 1−z Si 6−p Al p N 8 :RE z ; and parameters x, y, and z are relative composition contents in weight.
2. The illuminating system of claim 1 , wherein the parameters x, y, z, and p ranges are 0≦x≦1, 0≦y≦1, 0.001≦z≦0.4, and 0≦p≦3, respectively.
3. The illuminating system of claim 2 , wherein p is less than or equal to 1.2.
4. The illuminating system of claim 1 , wherein the tunable luminescent material is activated by europium (Eu 2+ ) and is formulated as (Sr 1−x−y Ca x Ba y ) 1−z Si 6−p Al p N 8 :Eu 2+ Z .
5. The illuminating system of claim 1 , wherein the tunable luminescent material emits light tunable from red to blue by the parameter p.
6. The illuminating system of claim 1 , wherein the light emitting diode includes an emission spectrum with a peak ranging from 440 nm to 650 nm.
7. The illuminating system of claim 1 , wherein the tunable luminescent material has an excitation spectrum tunable by the parameter p and the excitation spectrum ranges from about 300 nm to about 500 nm.
8. The illuminating system of claim 1 , wherein the tunable luminescent material is embedded in epoxy around the LED.
9. The illuminating system of claim 1 , wherein the LED includes an indium gallium nitride (InGaN) LED.
10. A tunable luminescent material comprising:
a rare earth element doped nitridosilicate phosphor formulated as (AE) z Si 1−p Al p N 8 :RE z , where AE is one of calcium (Ca), strontium (Sr), barium (Ba), and a combination thereof; RE is a rare earth element; z is 0.001≦z≦0.4; and p is 0≦p≦3.
11. The tunable luminescent material of claim 10 , wherein the rare earth element doped nitridosilicate phosphor includes (Sr 1−x−y Ca x Ba y ) 1−z Si 6−p Al p N 8 :Eu z ; x ranges between 0 and 1; and y ranges between 0 and 1.
12. The tunable luminescent material of claim 10 , comprising an excitation spectrum peak ranging from 300 nm to 500 nm.
13. The tunable luminescent material of claim 10 , comprising an emission spectrum peak ranging from 440 nm to 650 nm.
14. The tunable luminescent material of claim 10 , wherein an emission spectrum and the excitation spectrum of the luminescent material are tunable with an aluminum content of the luminescent material.
15. The tunable luminescent material of claim 10 , wherein the luminescent material is embedded in epoxy.
16. A method, comprising:
mixing stoichiometrically powdered strontium nitride (Sr 3 N 2 ), silicon nitride (Si 3 N 4 ), aluminum nitride (AIN), and europium nitride (EuN), thereby forming a mixture free of oxide; and
sintering the mixture under a high pressure and a high temperature, thereby forming a tunable luminescent material having a strontium silicon aluminum nitride.
17. The method of claim 16 , wherein the high pressure ranges from about 0.7 MPa to about 1.2 MPa under a nitrogen atmosphere.
18. The method of claim 16 , wherein the high temperature ranges between about 1700° C. and about 2300° C., and the sintering includes a sintering duration greater than about 0.5 hour.
19. The method of claim 16 , wherein the mixing stoichiometrically powdered Sr 3 N 2 , Si 3 N 4 , AlN, and EuN includes mixing stoichiometrically powdered Sr 3 N 2 , calcium nitride (Ca 3 N 2 ), barium nitride (Ba 3 N 2 ), Si 3 N 4 , AlN, and EuN.
20. The method of claim 16 , wherein the mixing stoichiometrically powdered Sr 3 N 2 , Si 3 N 4 , AlN, and EuN includes mixing powdered Sr 3 N 2 , Si 3 N 4 , and AlN with weights of about 25.45 to about 25.85, about 71.94 to about 60.45, and about 2.19 to about 13.25, respectively.
21. The method of claim 16 , further comprising distributing the tunable luminescent material around a light emitting diode (LED).