Toner containing crystalline polyester
A toner including a binder resin which contains a crystalline polyester resin and a non-crystalline polyester resin, wherein the crystalline polyester resin has at least two diffraction peaks in a range of 20°<2θ<25° as detected by X-ray diffraction measurement, and has a melting point which is 60° C. or higher but lower than 80° C., and wherein the diffraction peaks each have a half width which is less than 1.0°.
1. A toner comprising:
a binder resin which contains a crystalline polyester resin and a non-crystalline polyester resin, and
an amine elongation composition of polyester modified with an isocyanate,
wherein the crystalline polyester resin is obtained by synthesizing with:
at least one alcohol component selected from the group consisting of ethylene glycol, 1,4-butanediol, 1,6-hexanediol, 1,8-octanediol, 1,10-decanediol, and 1,12-dodecanediol, and
at least one dicarboxylic acid component selected from the group consisting of 1,10-decanediacid and 1,12-dodecanediacid;
wherein the crystalline polyester resin has at least two diffraction peaks in a range of 20°<2θ<25° as detected by X-ray diffraction measurement, and has a melting point which is 60° C. or higher but lower than 80° C.; and
wherein the diffraction peaks each have a half width which is less than 1.0°.
2. The toner according to claim 1 , wherein the diffraction peaks each have a half width which is less than 0.6°.
3. The toner according to claim 1 , wherein the crystalline polyester resin has a melting point which is 65° C. or higher but lower than 75° C.
4. The toner according to claim 1 , wherein the toner has a glass transition temperature Tg1st which is 45° C. or higher but lower than 65° C., where the glass transition temperature Tg1st is measured at the first temperature raising in DSC.
5. The toner according to claim 1 , wherein the toner has a glass transition temperature Tg2nd which is 20° C. or higher but lower than 40° C., where the glass transition temperature Tg2nd is measured at the second temperature raising in DSC.
6. The toner according to claim 1 , wherein soluble matter of the crystalline polyester resin in orthodichlorobenzene has a weight average molecular weight Mw of 3,000 to 30,000, a number average molecular weight Mn of 1,000 to 10,000, and a Mw/Mn of 1 to 10, as measured through GPC.
7. The toner according to claim 6 , wherein the soluble matter of the crystalline polyester resin in the orthodichlorobenzene has the weight average molecular weight Mw of 5,000 to 15,000, the number average molecular weight Mn of 2,000 to 10,000, and the Mw/Mn of 1 to 5, as measured through GPC.
8. The toner according to claim 1 , wherein the toner is obtained by dispersing, in an aqueous medium, an oil phase containing an organic solvent and the binder resin in the organic solvent, so as to prepare a dispersion liquid, and by removing the organic solvent from the dispersion liquid.
9. The toner according to claim 8 , wherein the crystalline polyester resin has a dissolvability to the organic solvent at 20° C. which is less than 3.0 parts by mass.
10. The toner according to claim 8 , wherein the crystalline polyester resin has a dissolvability to the organic solvent at 70° C. which is equal to or more than 10.0 parts by mass.
11. The toner according to claim 8 ,
wherein the binder resin comprises the amine elongation composition, the oil phase comprises a colorant and a releasing agent, and the aqueous medium comprises a dispersing agent, and
wherein the toner is obtained by dissolving, in the oil phase, a compound capable of being elongated with the amine elongation composition; dispersing the oil phase in the aqueous medium to prepare the dispersion liquid; allowing the amine elongation composition to undergo an elongation reaction with the compound in the dispersion liquid; and removing the organic solvent from the dispersion liquid.
12. A developer comprising:
a toner,
wherein the toner comprises a binder resin which contains a crystalline polyester resin and a non-crystalline polyester resin,
wherein the toner further comprises an amine elongation composition of polyester modified with an isocyanate,
wherein the crystalline polyester resin is obtained by synthesizing with:
at least one alcohol component selected from the group consisting of ethylene glycol, 1,4-butanediol, 1,6-hexanediol, 1,8-octanediol, 1,10-decanediol, and 1,12-dodecanediol, and
at least one dicarboxylic acid component selected from the group consisting of 1,10-decanediacid and 1,12-dodecanediacid;
wherein the crystalline polyester resin has at least two diffraction peaks in a range of 20°<2θ<25° as detected by X-ray diffraction measurement, and has a melting point which is 60° C. or higher but lower than 80° C.; and
wherein the diffraction peaks each have a half width which is less than 1.0°.
13. The toner of claim 1 , wherein the amine elongation composition has an average of from 1.5 to 3 isocyanate groups per molecule of polyester prepolymer.
14. The toner of claim 1 , wherein the amine elongation composition has a weight average molecular weight of from 5×10 3 to 5×10 4 .
15. The toner of claim 1 , having a minimum fixing temperature of 125° C. or less.
16. The toner of claim 15 , having a residual toner rate of less than 20% when stored at 50° C. for 8 h then sieved with a 42-mesh sieve for 2 min.
17. The toner of claim 15 , wherein a release range of the toner is 60° C. or greater.