Synthesis of pyrochlore nanostructures and uses thereof
View Patent ↗A template-free reverse micelle (RM) based method is used to synthesize pyrochlore nanostructures having photocatalytic activity. In one embodiment, the method includes separately mixing together a first acid stabilized aqueous solution including pyrochlore precursor A and a second acid stabilized aqueous solution including pyrochlore precursor B with an organic solution including a surfactant to form an oil-in-water emulsion. Next, equimolar solutions of the first and second acid stabilized oil-in-water emulsions are mixed together. Then, the mixture of the first and second acid stabilized oil-in-water emulsion is treated with a base to produce a precipitate including pyrochlore precursors A and B. After which, the precipitate is dried to remove volatiles. The precipitate is then calcined in the presence of oxygen to form a pyrochlore nanostructure, such as a bismuth titanate (Bi 2 Ti 2 O 7 ) pyrochlore nanorod. The method of synthesizing the pyrochlore nanorod is template-free.
1. A method of synthesizing a pyrochlore nanostructure having the general formula A 2 B 2 O 7 , where A and B are rare-earth or transition metal species and O is oxygen, the method comprising:
separately mixing together a first acid stabilized aqueous solution including a pyrochlore precursor A and a second acid stabilized aqueous solution including a pyrochlore precursor B with an organic solvent mixture comprising a surfactant and an organic solvent to form a first acid stabilized oil-in-water emulsion of precursor A and a second acid stabilized oil-in-water emulsion of precursor B;
mixing together equimolar portions of the first and second acid stabilized oil-in-water emulsions to form a mixed acid stabilized oil-in-water emulsion comprising the pyrochlore precursor A and the pyrochlore precursor B;
treating the mixed acid stabilized oil-in-water emulsion with a base to increase the pH from acidic to alkaline to produce a precipitate including the pyrochlore precursors A and B;
isolating the precipitate; and
calcining the precipitate in the presence of oxygen to form the pyrochlore nanostructure, wherein the method of synthesizing the pyrochlore nanostructure is template-free.
2. The method of claim 1 , wherein B of the pyrochlore precursor B is titanium (Ti), vanadium (V), chromium (Cr), manganese (Mn), iron (Fe), nickel (Ni), zirconium (Zr), tin (Sn), hafnium (Hf), tantalum (Ta), tungsten (W), or combinations thereof.
3. The method of claim 1 , wherein A of the pyrochlore precursor A is bismuth (Bi), calcium (Ca), strontium (Sr), yttrium (Y), barium (Ba), lanthanum (La), or combinations thereof.
4. The method of claim 1 , wherein the first and second acid stabilized solutions each include an acid independently selected from hydrochloric acid (HCl), nitric acid (HNO 3 ), acetic acid (CH 3 CO 2 H), sulfurous acid (H 2 SO 3 ), formic acid (HCO 2 H), perchloric acid (HClO 4 ), or combinations thereof.
5. The method of claim 1 , wherein the surfactant is selected from an anionic surfactant comprising a sulfate, a sulfonate, a phosphinate, or a carboxylate moiety; a cationic surfactant comprising an ammonium moiety; or a nonionic surfactant.
6. The method of claim 1 , wherein the organic solvent is selected from an alkane, an alkanol, an alkanone, or combinations thereof.
7. The method of claim 1 , wherein calcining is performed at a temperature greater than 350° C. and less than 900° C.
8. The method of claim 7 , wherein calcining is performed at a temperature greater than 500° C.
9. The method of claim 1 wherein the pyrochlore nanostructure is a pyrochlore nanorod.
10. The method of claim 9 wherein the pyrochlore nanorod is a bismuth titanate (Bi 2 Ti 2 O 7 ) pyrochlore nanorod.
11. The method of claim 1 wherein the pyrochlore nanostructure has photocatalytic activity.
12. The method of claim 1 wherein a ratio of water to organic solvent mixture of the first and second acid stabilized aqueous solutions is from 4 to 40 v/v.