Curing agents for epoxy resins
View Patent ↗A curing agent for epoxy resin has one or more five- or six-membered aromatic rings, and substituted on the one or more five- or six-membered rings at least two functionalities reactive with the epoxy selected from the group consisting of hydroxyl, amine, imidazole, azine, hydrazide, anhydride, and Lewis acid groups. Choice of functionality can provide a mixed polymer network, one with a more densely cross-linked polymer structure having a high Tg, and the other with a more linear polymer structure to contribute to stress reduction.
1. A curable composition comprising an epoxy resin and a curing agent for the epoxy resin that has the structure
in which
f 1 and f 2 independently are selected from the group consisting of hydroxyl, amine, azine, hydrazide, anhydride, imidazole or Lewis acid, provided that f 1 and f 2 are different;
n and m independently are numerals from 0 to 4, provided that when n is 0, x is at least 1;
x is a numeral from 0 to 100, provided that when x is 0, n is at least 1 and R 1 is f 2 ;
R is a monovalent or polyvalent radical, which includes hydrocarbyl, heteroatom-containing hydrocarbyl, substituted heteroatom-containing hydrocarbyl, hydrocarbylene, substituted hydrocarbylene, heteroatom-containing hydrocarbylene, substituted heteroatom-containing hydrocarbylene, polysiloxanes, polysiloxane-polyurethane block copolymers, and combinations of any of the above linked with one or more linking groups selected from the group consisting of —S—, —O—C(O)—, —O—C(O)—O—, —O—C(O)—NR 3 —, —NR 3 —C(O)—, —NR 3 —C(O) —N═N—, and —S—C(O)—, in which R 3 is independently for each position selected from the group consisting of hydrogen, alkyl, alkylene, alkoxy, acrylate, aryl, and maleimide;
R 1 and R 2 independently are selected from the group consisting of —R, —H, —CH 3 , —OCH 3 , —O(CH 2 ) n CH 3 , —(CH 2 ) n f 3 in which n is a numeral from 1 to 20 and f 3 is a hydrocarbyl group containing at least one carbon to carbon unsaturated bond; and
in which R 3 independently for each position is selected from the group consisting of hydrogen, alkyl, alkylene, alkoxy, acrylate, aryl, and maleimide.