Ultrabright fluorescent OLEDS using triplet sinks
A first device is provided. The first device further comprises an organic light emitting device. The organic light emitting device further comprises an anode, a cathode, and an emissive layer disposed between the anode and the cathode. The emissive layer further comprises an organic host compound, an organic emitting compound capable of fluorescent emission at room temperature, and an organic dopant compound. The triplet energy of the dopant compound is lower than the triplet energy of the host compound. The dopant compound does not strongly absorb the fluorescent emission of the emitting compound.
1. A first device, further comprising:
an organic light emitting device, further comprising:
an anode;
a cathode; and
an emissive layer disposed between the anode and the cathode, the emissive layer further comprising:
an organic host compound;
an organic emitting compound capable of fluorescent emission; and
an organic dopant compound;
wherein:
the triplet energy of the organic dopant compound is lower than or equal to the triplet energy of the organic host compound;
the triplet energy of the organic dopant compound is lower or equal to than the triplet energy of the organic emitting compound;
the singlet energy of the organic emitting compound is lower than the singlet energy of the organic host compound;
the singlet energy of the organic emitting compound is lower than the singlet energy of the organic dopant compound; and
the organic dopant compound does not strongly absorb the fluorescent emission of the organic emitting compound; and
wherein, the triplet energy of the dopant compound is greater than 1.6 eV.
2. The first device of claim 1 , wherein the organic light emitting device further comprises:
a hole transport layer disposed between the emissive layer and the anode; and
an electron transport layer disposed between the emissive layer and the cathode;
wherein the organic dopant compound is present only in the emissive layer.
3. The first device of claim 1 , wherein the transport gap of the dopant compound is no less than the transport gap of the host compound.
4. The first device of claim 1 , wherein the mobility of the dopant compound is higher than the mobility of the host compound.
5. The first device of claim 1 , wherein the triplet decay time of the dopant compound is shorter than the triplet decay time of the emitting compound.
6. The first device of claim 1 , wherein the first device further comprises an outcoupling enhancement structure adapted to increase the amount of light outcoupled from the first device by at least 25% relative to a device having no outcoupling enhancement structure.
7. The first device of claim 1 , wherein:
the concentration of the dopant compound is 10 wt %-90 wt %;
the concentration of the emitting compound is 0.5 wt %-5 wt %.
8. The first device of claim 1 , wherein the organic light emitting device does not have a turn-on peak.
9. The first device of claim 1 , wherein the organic light emitting device has a turn-on peak that is at least 50% reduced relative to an otherwise equivalent device that omits the dopant compound.
10. The first device of claim 1 , wherein the organic emitting compound is capable of fluorescent emission at room temperature.
11. The first device of claim 1 , wherein the dopant compound has a triplet energy less than 1.7 eV, and has a singlet energy that is at least twice the triplet energy.
12. The first device of claim 1 , wherein the dopant compound is selected from the group consisting of: anthracene, tetracene, and their derivatives.
13. The first device of claim 1 , wherein the dopant compound is a phosphor.
14. The first device of claim 1 , wherein the first device is a consumer product.
15. A method, comprising:
providing a first device, further comprising an organic light emitting device, the organic light emitting device further comprising:
an anode;
a cathode;
an emissive layer disposed between the anode and the cathode, the emissive layer further comprising:
an organic host compound;
an organic emitting compound capable of fluorescent emission;
an organic dopant compound;
wherein:
the triplet energy of the organic dopant compound is lower than or equal to the triplet energy of the organic host compound;
the triplet energy of the organic dopant compound is lower or equal to than the triplet energy of the organic emitting compound;
the singlet energy of the organic emitting compound is lower than the singlet energy of the organic host compound;
the singlet energy of the organic emitting compound is lower than the singlet energy of the organic dopant compound;
the organic dopant compound does not strongly absorb the fluorescent emission of the organic emitting compound; and
the triplet energy of the dopant compound is greater than 1.6 eV;
applying an operating voltage across the anode and the cathode;
wherein the concentration of the dopant compound is sufficient to reduce the turn-on peak of the organic light emitting device by at least 50% relative to an otherwise equivalent device that omits the dopant compound.
16. The method of claim 15 , wherein the organic light emitting device does not have a turn-on peak.
17. The first device of claim 1 , wherein the dopant compound comprises ADN having a concentration of between 60 wt %-80 wt %.
18. The method of claim 15 , wherein the dopant compound has a triplet energy less than 1.7 eV, and has a singlet energy that is at least twice the triplet energy.