IP Library Granted Patent US 8,476,191
Granted Patent B2
US 8,476,191 · App. 13/121,815 · Granted Jul 2, 2013

Heat-sensitive recording body and method for producing same

Inventors: Toshiro Hada (Amagasaki, JP); Yoshihiko Yoneda (Amagasaki, JP)
Assignee: Oji Holdings Corporation
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Quick Facts
Patent No.
US 8,476,191
App. No.
13/121,815
Granted
Jul 2, 2013
Kind
B2
Abstract

The present invention relates to a heat-sensitive recording material comprising one or more heat-sensitive recording layers, an intermediate layer and a protective layer that are formed on one side of a transparent support, and the present inventions provide a heat-sensitive recording material and a process for providing the heat-sensitive recording material, wherein the one or more heat-sensitive recording layers are formed from one or more heat-sensitive recording layer coating compositions that each contain a leuco dye and a developer, the intermediate layer is formed from an intermediate layer coating composition that contains a hydrazine-based compound and an oxazoline group-containing compound, and the protective layer is formed from a protective layer coating composition that contains a modified polyvinyl alcohol.

Claims (21)

1. A heat-sensitive recording material comprising one or more heat-sensitive recording layers, an intermediate layer and a protective layer that are formed on one side of a transparent support,

wherein:

the one or more heat-sensitive recording layers are formed from one or more heat-sensitive recording layer coating compositions that each contain a leuco dye and a developer,

the intermediate layer is formed from an intermediate layer coating composition that contains a hydrazine-based compound and an oxazoline group-containing compound, and

the protective layer is formed from a protective layer coating composition that contains a modified polyvinyl alcohol.

2. The heat-sensitive recording material according to claim 1 , wherein the mass ratio of the hydrazine-based compound to the oxazoline group-containing compound ranges from 70:30 to 95:5.

3. The heat-sensitive recording material according to claim 1 or 2 , wherein the modified polyvinyl alcohol is an acetoacetyl-modified polyvinyl alcohol.

4. The heat-sensitive recording material according to claim 1 or 2 , wherein the intermediate layer coating composition contains a water-dispersible adhesive that is a polymer latex having a heterogeneous particle structure that contains a urethane resin component in at least one phase.

5. The heat-sensitive recording material according to claim 4 , wherein the intermediate layer coating composition further contains a water-soluble adhesive, and the mass ratio of the water-dispersible adhesive to the water-soluble adhesive ranges from 90:10 to 50:50.

6. The heat-sensitive recording material according to claim 1 or 2 , wherein the leuco dye has a form of composite particles containing a leuco dye and a hydrophobic resin.

7. The heat-sensitive recording material according to claim 1 or 2 , wherein the one or more heat-sensitive recording layers, the intermediate layer and the protective layer are formed by simultaneously applying and drying the one or more heat-sensitive recording layer coating compositions, the intermediate layer coating composition, and the protective layer coating composition.

8. The heat-sensitive recording material according to claim 1 or 2 , wherein the one or more heat-sensitive recording layers each contain a leuco dye and a developer,

the intermediate layer contains a hydrazine-based compound and an oxazoline group-containing compound, and

the protective layer contains a modified polyvinyl alcohol.

9. The heat-sensitive recording material according to claim 1 or 2 , wherein the transparent support is a polyethylene terephthalate film.

10. A process for producing a heat-sensitive recording material comprising one or more heat-sensitive recording layers, an intermediate layer and a protective layer that are formed on one side of a transparent support,

the process comprising the steps of:

(1) forming one or more heat-sensitive recording layers using one or more heat-sensitive recording layer coating compositions each containing a leuco dye and a developer;

(2) forming an intermediate layer using an intermediate layer coating composition containing a hydrazine-based compound and an oxazoline group-containing compound; and

(3) forming a protective layer using a protective layer coating composition containing a modified polyvinyl alcohol.

11. The process according to claim 10 , wherein, in the steps (1), (2) and (3), the one or more heat-sensitive recording layers, the intermediate layer and the protective layer are formed by simultaneously applying and drying the one or more heat-sensitive recording layer coating compositions, the intermediate layer coating composition and the protective layer coating composition.

Assignments (2)
CHANGE OF NAME Recorded Mar 11, 2013
From: OJI PAPER CO., LTD.
To: OJI HOLDINGS CORPORATION
Reel/Frame 029967/0240 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Apr 11, 2011
From: HADA, TOSHIRO; YONEDA, YOSHIHIKO
To: OJI PAPER CO., LTD.
Reel/Frame 026105/0062 →
Priority Claims (1)
JP 2008-258354 · Oct 3, 2008 · national
Continuity (1)
Related Publication 20110177942A1 · Jul 21, 2011