IP Library › Granted Patent US 8,435,601
Granted Patent B2
US 8,435,601 · App. 13/122,057 · Granted May 7, 2013

Method for forming carbon nanotube

Inventors: Suguru Noda (Tokyo, JP); Koji Furuichi (Kyoto, JP)
Assignees: University of Tokyo; Dainippon Screen Mfg. Co., Ltd.
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Quick Facts
Patent No.
US 8,435,601
App. No.
13/122,057
Granted
May 7, 2013
Kind
B2
Abstract

Disclosed is a method of forming carbon nanotubes on a conductor that covers a portion of a substrate, the method includes depositing a mesh-like conductive member made of Mo or the like on a substrate made of glass or the like, forming a catalyst support, such as Al 2 O 3 , and a catalyst such as Fe or Co on the conductive member, placing the substrate in a carbon-source gas atmosphere, and generating heat with the conductive member for a short period of time to grow nanotubes while avoiding damage to the substrate.

Claims (49)

1. A method for forming carbon nanotubes comprising the processes of:

depositing a conductive member covering a portion of a surface of a substrate;

disposing a catalyst on the conductive member;

placing the substrate on which the catalyst has been disposed in a carbon-source gas atmosphere; and

generating heat with the conductive member deposited on the substrate placed in the carbon-source gas atmosphere for a short enough heating time that allows for growing carbon nanotubes on the catalyst but avoids causing thermal damage to the substrate and avoids damage to the conductive member.

2. The method for forming carbon nanotubes according to claim 1 ,

wherein the process of depositing the conductive member includes covering a portion of the surface of the substrate by depositing the conductive member in a linear pattern, a comb pattern or a mesh pattern,

wherein the catalyst covers the conductive member and portions of the surface of the substrate not covered by the conductive member, and

wherein nanotubes are grown from those portions of the catalyst that extend over the conductive member.

3. The method for forming carbon nanotubes according to claim 2 ,

wherein the process of depositing the conductive member includes disposing conductive thin lines, each having a width of 1 μm to 50 μm, with an interval of 10 μm to 500 μm to make the linear pattern, the comb pattern or the mesh pattern.

4. The method for forming carbon nanotubes according to claim 3 ,

wherein the process of depositing the conductive member includes depositing Mo as the conductive member, and

the process of disposing the catalyst includes disposing Al 2 O 3 as a catalyst support in such a way that the Al 2 O 3 contacts the conductive member and disposing Fe or Co as the catalyst so that the Fe or Co contacts the catalyst support.

5. The method for forming carbon nanotubes according to claim 1 ,

wherein the substrate is made of glass or transparent material, and

in the process of heating, a length of the heating time is equal to or less than ten seconds.

6. The method for forming carbon nanotubes according to claim 1 ,

wherein the generating heat step comprises passing a short pulse of electric current from a first end of the conductive member to a second end of the conductive member, and

electrons move between at least one of the first and second ends of the conductive member and the carbon nanotubes when the carbon nanotubes function as an electronic device.

7. The method for forming carbon nanotubes according to claim 1 ,

wherein the generating heat step comprises applying a short pulse of voltage between a first end of the conductive member and a second end of the conductive member, and

a same voltage is applied to the first and second ends of the conductive member when the carbon nanotubes function as an electronic device.

8. The method for forming nanotubes according to claim 1 , wherein the nanotubes remain in electrical communication with the conductive member.

9. The method for forming carbon nanotubes according to claim 1 ,

wherein the generating heat step comprises passing a short pulse of electric current from a first end of the conductive member to a second end of the conductive member.

10. The method for forming carbon nanotubes according to claim 1 ,

wherein the generating heat step comprises applying a short pulse of voltage between a first end of the conductive member and a second end of the conductive member.

11. The method for forming nanotubes according to claim 10 , wherein the substrate is comprised of either glass or plastic.

12. The method for forming nanotubes according to claim 10 , wherein the substrate is comprised of soda-lime glass.

13. The method for forming nanotubes according to claim 1 , wherein said substrate is transparent, translucent or opaque.

14. A method for forming carbon nanotubes comprising the processes of:

depositing a conductive member covering a portion of a surface of a substrate;

disposing a catalyst on the conductive member;

placing the substrate on which the catalyst has been disposed in a carbon-source gas atmosphere; and

generating heat with the conductive member deposited on the substrate placed in the carbon-source gas atmosphere by irradiating such a short pulse of electromagnetic wave onto the conductive member that a temperature of the substrate is kept below a heatproof temperature of the substrate during the process of heating, to make carbon nanotubes grow from the catalyst.

15. A method for forming carbon nanotubes comprising the processes of:

depositing a conductive member covering a portion of a surface of substrate;

disposing a catalyst support on the conductive member and a catalyst on the catalyst support;

placing the substrate on which the catalyst has been disposed in a carbon-source gas atmosphere; and

generating heat with the conductive member deposited on the substrate placed in the carbon-source gas atmosphere for a short time to make carbon nanotubes grow from the catalyst.

16. The method for forming carbon nanotubes according to claim 15 ,

wherein during the generating heat step, a temperature of the substrate is kept below a heatproof temperature of the substrate.

17. A method for forming carbon nanotubes comprising the processes of:

depositing a conductive member covering a portion of a surface of a substrate;

disposing a catalyst on the conductive member;

placing the substrate on which the catalyst has been disposed in a carbon-source gas atmosphere; and

generating heat with the conductive member deposited on the substrate placed in the carbon-source gas atmosphere to make carbon nanotubes grow from portions of the catalyst that is adjacent to the conductive member,

wherein during the generating heat step, a temperature of the substrate is kept below a heatproof temperature of the substrate.

Assignments (2)
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Aug 26, 2016
From: DAINIPPON SCREEN MFG. CO., LTD.
To: SCREEN HOLDINGS CO., LTD.
Reel/Frame 039555/0042 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Apr 1, 2011
From: NODA, SUGURU; FURUICHI, KOJI
To: UNIVERSITY OF TOKYO; DAINIPPON SCREEN MFG. CO., LTD.
Reel/Frame 026059/0951 →
Priority Claims (1)
JP 2008-278869 · Oct 29, 2008 · national
Continuity (1)
Related Publication 20110189394A1 · Aug 4, 2011