Biodegradable plastic and use thereof
The invention relates to a biodegradable plastic having increased biodegradation speed. Said plastic comprises a) finely distributed particle of a biodegradable, water-soluble, organic component, and b) finely distributed particles of a water-soluble, inorganic component promoting the growth of microorganisms and comprising N, P, and/or S. Said plastic is particularly based on cellulose esters such as cellulose acetate. Preferable components A are water-soluble saccharides and/or water-soluble organic acids. Said particularly advantageous biodegradable plastic is particularly available in the form of fibers, films, injection molded items, granulate beads, and containers. Controlled-release biocides and/or fertilizers can also be included in the molded part, wherein the molded part is degraded faster in the environment as said ingredients are released. The accelerated biodegradation is based on a synergistic interaction of the components indicated.
1. A biodegradable plastic with an increased biodegradation speed, comprising: a polymer, and
(a) approximately 0.1 to 40% by weight of finely distributed particles of a biodegradable, water-soluble, organic component with a mean particle size of less than 10 μm and
(b) finely distributed particles of a water-soluble, inorganic component containing N, P and/or S, promoting the growth of microorganisms and with a mean particle size of less than 10 μm,
wherein the component (a) is a water-soluble saccharide, a water-soluble organic acid and/or a water-soluble nitrogen compound,
wherein the water-soluble saccharide is saccharose, glucose, maltose and/or lactose,
wherein the water-soluble organic acid is oxalic acid, malonic acid, glutaric acid, adipic acid, malic acid, tartaric acid, citric acid, ascorbic acid and/or amino carboxylic acids, and
wherein the water-soluble organic nitrogen compound is urea, guanidine, hexamethylenetetramine, glycine and/or alanine;
wherein the polymer is a cellulose ester, polylactide, polycaprolactone and/or polyhydroxybutyric acid.
2. The biodegradable plastic according to claim 1 , wherein the component (a) has a mean particle size of less than approximately 5 μm.
3. The biodegradable plastic according to claim 1 , wherein the component (a) is contained in the plastic in a quantity of approximately 1 to 20% by weight.
4. The biodegradable plastic according to claim 1 , wherein the component (b) has a mean particle size of less than 5 μm.
5. The biodegradable plastic according to claim 1 ,
wherein the component (b) is present in the form of one or more salts containing Na, NH 4 , K, Mg, Ca and/or Fe.
6. The biodegradable plastic according to claim 5 , wherein the one or more salts is present in the form of Na(NH 4 ) 2 PO 4 , NaNH 4 HPO 4 , NaH 2 PO 4 , Na 2 SO 4 , (NH 4 ) 2 SO 4 , NH 4 NO 3 , NaNO 3 , MgSO 4 , KH 2 PO 4 , FeSO 4 and/or NH 4 Cl, individually or in a mixture.
7. The biodegradable plastic according to claim 1 , wherein the component (b) is present in the biodegradable plastic in a quantity of approximately 0.01 to 20% by weight.
8. The biodegradable plastic according to claim 1 , wherein said biodegradable plastic is a molded part, a fiber, a film, a deep-drawn film, an injection-molded article, a thick-walled molded part, a granulate, a microbead, a bead, a vessel, or a flower pot.
9. The biodegradable plastic according to claim 8 , wherein the molded part contains controlled-release biocides and/or fertilizers.
10. The biodegradable plastic according to claim 1 in the form of threads, obtained by dry spinning of a suspension comprising components (a) and (b), a solvent, and dissolved polymer.
11. The biodegradable plastic according to claim 1 in the form of a filter tow obtained by dry spinning a suspension comprising components (a) and (b), a solvent, and dissolved polymer to threads and subsequently processing the threads to filter tows.
12. A film obtained by processing a solution or melt of a biodegradable plastic according to claim 1 by flat extrusion or by film blowing to form a film.