Metal complexes; use thereof for the preparation of compositions for agricultural use
Novel metal complexes useful in the area of agriculture, notably as agents for treating metal deficiency. The novel metal complexes comprise at least one metal selected from the metal trace elements essential for the development of plants, at least one first ligand selected from the lignosulfonates, and derivatives thereof, and at least one second ligand selected from the multidentate organic ligands.
1. A metal complex, represented by a following formula:
[ligand 1] n -(metal) x -[ligand 2] m ,
wherein the metal is selected from the group consisting of iron, manganese, boron, zinc, molybdenum, nickel, cobalt, and copper,
the ligand 1 is a lignosulfonate, and
the ligand 2 is selected from the group consisting of citric acid, oxalic acid, malonic acid, succinic acid, malic acid, glutaric acid, phthalic acid, terephthalic acid, adipic acid, and salicylic acid, and
n, x, and m are positive integers that satisfy requirements imposed by a number of bonds or of coordinations formed between the metal and the ligand 1 and between the metal and the ligand 2.
2. The complex as claimed in claim 1 , wherein said metal is iron, and said ligand 2 is citric acid.
3. A composition for agricultural use, wherein the composition comprises at least one metal complex according to claim 1 together with an agriculturally acceptable support or vehicle.
4. The composition as claimed in claim 3 , wherein the composition comprises the at least one metal complex in an amount from 1 to 20 wt. %.
5. The composition as claimed in claim 3 , wherein the composition further comprises at least one additional compound selected from the group consisting of mineral nutrients and plant biostimulants.
6. The composition as claimed in claim 3 , wherein the composition is in a solid form or in a liquid form.
7. The complex as claimed in claim 2 , wherein the iron is in a form of Fe(III).
8. The composition as claimed in claim 4 , which comprises the at least one metal complex in an amount from 3 to 15 wt. %.
9. The composition as claimed in claim 6 , wherein the composition is in the solid form, which is a powder, a granule, or a tablet.
10. A metal complex represented by a following formula:
[ligand 1] n -(metal) x -[ligand 2] m
wherein the metal is selected from the group consisting of iron, manganese, boron, zinc, molybdenum, nickel, cobalt and copper;
the ligand 1 is a lignosulfonate; and
the ligand 2 is selected from the group consisting of citric acid, oxalic acid, malonic acid, succinic acid, malic acid, glutaric acid, phthalic acid, terephthalic acid, adipic acid, and salicylic acid, and
wherein n is 1 or 2, x is 1, 2, 3 or 4, and m is 1, 2, 3 or 4.
11. The complex as claimed in claim 10 , wherein n, x, and m are each 1.
12. A method of treating metal deficiency of a plant or growing a plant, said metal being selected from the group consisting of iron, manganese, boron, zinc, molybdenum, nickel, cobalt, and copper,
wherein the method comprises a step of applying a metal in a form of the metal complex as claimed in claim 1 to the plant.
13. The method as claimed in claim 12 , wherein said metal complex is applied in an amount from 50 to 80 grams per seedling to fruit trees for the treatment or in an amount from 30 to 40 kilograms per hectare to a vegetable for the growing.