Granted Patent B2

US 8,562,715 · App. 13/124,814 · Granted Oct 22, 2013

Abstract

Claims (9)

1. Process for producing molybdenum metal powder by reduction of molybdenum-containing precursors in a moving bed having a reaction space and a cooling zone, characterized in that the reduction is carried out by means of an inflowing atmosphere containing water vapor and hydrogen and having a dew point of ≧+20° C. on entry into the reaction space,

wherein the hydrogen is introduced simultaneously in two substreams, namely a humid substream having a dew point of at least +20° C. into the reaction space and a dry substream into the cooling zone.

2. Process according to claim 1 , wherein the inflowing atmosphere is introduced in countercurrent to the movement of the molybdenum-containing precursors to be reduced.

3. Process according to claim 1 , wherein the inflowing atmosphere contains up to 50% by volume of nitrogen and/or noble gases.

4. Process according to claim 1 , wherein the reaction space is heated by means of at least two heating zones configured for independent temperature regulation.

5. Process according to claim 1 , wherein the dry substream passes through the cooling zone of the reduced molybdenum metal powder before it is fed into the reaction space, with the dry substream having a dew point which is both below the temperature of the molybdenum metal powder present in the cooling zone and below the lowest dew point occurring in the reaction space.

6. Process according to claim 1 , where molybdenum dioxide (MoO 2 ) is used as molybdenum-containing precursor.

7. Process according to claim 6 , wherein the molybdenum dioxide has a specific BET surface area, measured in accordance with ASTM 3663, of ≦2 m 2 /g.

8. Process according to claim 6 , wherein the MoO 2 has a reduction loss of not more than 27% by weight.

Assignments (17)