Preparation of siloxanes
View Patent ↗The invention relates to a process for producing siloxanes comprising reacting at least two siloxanes in the presence of an ion exchange resin catalyst comprising from 6 to 19 weight %, based upon the dry weight of the ion exchange resin catalyst, water, at a temperature from ambient to 110° C. The invention also relates to a process for reusing the ion exchange resin catalyst after the reacting of the at least two siloxanes in the presence of the ion exchange resin catalysts comprising adding water to the ion exchange resin catalyst to readjust the water content to from 6 to 19 weight % water, based on the dry weight of the catalyst, and then reacting at least two siloxanes in the presence of the readjusted water content ion exchange resin catalyst.
1. A process for preparing siloxanes, comprising:
reacting at least two siloxanes in the presence of an ion exchange resin catalyst comprising from 6 to 19 weight % water;
recovering the ion exchange resin catalyst after the reacting;
adding water to the ion exchange resin catalyst to bring the ion exchange resin to from 6 to 19 weight % water, based upon the dry weight of the ion exchange resin catalyst; and
reacting at least two siloxanes in the presence of the ion exchange resin catalyst,
wherein the at least two siloxanes comprise a first siloxane and a second siloxane,
the first siloxane having units of the general formula R a SiO (4-a)/2 , wherein each R is independently a hydrogen or a C 1 -C 20 hydrocarbyl group and “a” has a value from 0 to 3; and
the second siloxane having a formula MD x M wherein M is R 3 SiO— and D is —SiR 2 O—.
2. The process of claim 1 , wherein the ion exchange resin catalyst comprises from 6 to 13 weight % water, based upon the dry weight of the ion exchange resin catalyst.
3. The process of claim 1 , wherein the ion exchange resin catalyst comprises from 6 to 9 weight % water, based upon the weight of the ion exchange resin catalyst.
4. The process of claim 1 , wherein at least one of the siloxanes is poly(methyl)hydrogensiloxane or a cyclic siloxane.
5. The process of claim 1 , wherein the siloxanes have between 2 and 200 silicon atoms.
6. The process of claim 1 , wherein the reacting is at a temperature from 20 to 110° C.
7. The process of claim 6 , wherein the temperature is from 20 to 80° C.
8. The method of claim 1 , wherein the water is added to the ion exchange resin catalyst to bring the ion exchange resin to from 6 to 13 weight % water, based upon the dry weight of the ion exchange resin catalyst.
9. The method of claim 1 , wherein the ion exchange resin catalyst is styrenedivinylbenzene sulfonic acid copolymer.
10. The method of claim 1 , wherein
the first siloxane has a formula (R 2 SiO) n , wherein n is an integer from 3 to 12; and
wherein in the formula for the second siloxane x has a value from 0 to 20.
11. The method of claim 1 , wherein at least one of the siloxanes comprises at least one silicon bonded hydrogen atom and the ion exchange resin catalyst is an acid ion exchange resin.