Battery electrolyte solutions containing aromatic phosphorus compounds
A battery electrolyte solution contains from 0.01 to 80% by weight of an aromatic phosphorus compound. The aromatic phosphorus compound provides increased thermal stability for the electrolyte, helping to reduce thermal degradation, thermal runaway reactions and the possibility of burning. The aromatic phosphorus compound has little adverse impact on the electrical properties of the battery, and in some cases actually improves battery performance.
1. A battery electrolyte solution comprising at least one lithium salt and a non-aqueous solvent in which the lithium salt is soluble, wherein from 0.01 to 80% by weight of the battery electrolyte solution is at least one aromatic phosphorus compound represented by the structure:
wherein R 3 is independently hydrogen, C 1-3 alkyl, hydroxyl, halogen, alkoxyl containing from 1 to 3 carbon atoms or C 2-3 alkylene and each R 3 is independently alkyl having from 1 to 8 carbon atoms.
2. The battery electrolyte solution of claim 1 wherein each R 4 is independently methyl, ethyl or isopropyl and each R 3 is independently hydrogen or C 1-3 alkyl.
3. The battery electrolyte solution of claim 1 wherein the aromatic phosphorus compound has the structure:
4. The battery electrolyte solution of claim 1 wherein the solvent includes at least one material selected from linear alkyl carbonates, cyclic carbonates, cyclic esters, linear esters, alkyl ethers, nitriles, sulfones, sulfolanes, siloxanes and sultones.
5. The battery electrolyte solution of claim 4 wherein the solvent includes at least one linear alkyl carbonate, at least one cyclic carbonate, or a mixture thereof.
6. The battery electrolyte solution of claim 1 wherein the lithium salt is at least one of LiPF 6 , LiClO 4 , LiBF 4 , LiAsF 6 , LiCF 3 SO 3 and LiN(SO 2 CF 3 ) 2 .
7. The battery electrolyte solution of claim 1 which further comprises at least one other additive selected from a solid electrolyte interface formation promoter, a cathode protection agent, a lithium salt stabilizer, a lithium deposition improving agent, an ionic solvation enhancer, a corrosion inhibitor, a wetting agent and a viscosity reducing agent.
8. The battery electrolyte solution of claim 1 which further comprises at least one phosphorus-sulfur compound represented by the structure:
wherein X is oxygen or sulfur, T is a covalent bond, oxygen or sulfur, provided that at least one of X and T is sulfur, each X′ is independently oxygen or sulfur, each m is independently zero or 1 when X′ is oxygen and zero, 1 or 2 when X′ is sulfur, n is at least 1 and preferably at least 2, each R 5 is independently an unsubstituted or inertly substituted hydrocarbyl group or the R 5 groups together form an unsubstituted or inertly substituted divalent organic group and A is an organic linking group.
9. The battery electrolyte solution of claim 1 which further comprises at least one carbonate compound having aliphatic carbon-carbon unsaturation.
10. The battery electrolyte solution of claim 1 which further comprises at least one sultone compound.
11. An electrical battery comprising an anode, a cathode, a separator disposed between the anode and cathode, and an electrolyte solution in contact with the anode and cathode, wherein the electrolyte solution is a battery electrolyte solution of claim 1 .