Method for methanol synthesis using synthesis gas generated by combined reforming of natural gas with carbon dioxide
Disclosed is a method for methanol synthesis using synthesis gas obtained from reforming of natural gas with carbon dioxide. First, synthesis gas is obtained from steam carbon dioxide reforming of methane, in which steam reforming of natural gas is carried out simultaneously with carbon dioxide reforming of methane, by using a catalyst (Ni/Ce/MgAlO x , or Ni/Ce—Zr/MgAlO x ) and processing condition capable of maintaining a predetermined ratio of carbon monoxide, carbon dioxide, and hydrogen [H 2 /(2CO+3CO 2 )=0.85-1.15]. Next, methanol synthesis is carried out by using the obtained synthesis gas and a catalyst system suitable for methanol synthesis with minimum byproduct formation (a catalyst system including a Cu—Zn—Al oxide containing CuO, ZnO, and Al 2 O 3 at a predetermined ratio in combination with a cerium-zirconium oxide obtained by a sol-gel process). In addition, unreacted synthesis gas remaining after the operation of methanol synthesis is recycled efficiently to improve the carbon availability (methane and CO 2 availability) and energy efficiency in the overall process.
1. A method for preparing methanol from carbon dioxide, comprising:
preparing synthesis gas having H 2 /(2CO+3CO 2 ) mole ratio of 0.85˜1.15 via combined reforming, in which steam reforming of natural gas is carried out simultaneously with carbon dioxide reforming of methane, in the presence of a catalyst of Ni/Ce/MgAlO x or Ni/Ce—Zr/MgAlO x , wherein said preparing synthesis gas is performed by carrying out combined reforming at a reaction temperature of 800 to 1,000° C. under a reaction pressure of 05˜20 atm with a space velocity of 1,000 to 500,000 h −1 in such a condition that molar ratio of CH 4 /CO 2 /H 2 O is within a range of 1/0.3-0.6/1.0-2.0;
synthesizing methanol from the obtained synthesis gas in the presence of a catalyst of Cu—ZnO—Al 2 O 3 /CeZrOx; and
separating the methanol product from unreacted synthesis gas and recycling 10 the unreacted synthesis gas.
2. The method for preparing methanol from carbon dioxide according to claim 1 , wherein the unreacted synthesis gas separated from the methanol product is recycled to said preparing synthesis gas or said synthesizing methanol.
3. The method for preparing methanol from carbon dioxide according to claim 1 , wherein said synthesizing methanol is carried out at a reaction temperature of 200 to 400° C. under a reaction pressure of 30 to 60 kg/cm 2 with a space velocity of 1,000 to 10,000 −1 .
4. The method for preparing methanol from carbon dioxide according to claim 2 , wherein the unreacted synthesis gas separated from the methanol product is recycled in such a manner that the ratio of synthesis gas recycled to combined reforming is maintained at 0.0 to 0.2 and that of synthesis gas recycled to methanol synthesis is maintained at 0.8 to 1.0, based on the total unreacted reactants.
5. The method for preparing methanol from carbon dioxide according to claim 1 , wherein said preparing synthesis gas provides a methane conversion of 90% or higher and a carbon dioxide conversion of 40% or higher.
6. The method for preparing methanol from carbon dioxide according to claim 1 , wherein said synthesizing methanol provides a CO conversion of 35% or higher.