Process for the recovery of pure aromatics from hydrocarbon fractions containing aromatics
A process for the recovery of a pure aromatics-containing product is disclosed. This product is obtained by extractive distillation of a gasoline rich in aromatics, in which olefins, diolefins and polyolefins are separated, and this extractive distillation is followed by a hydrogenation of the recovered aromatics-rich, olefin-lean product stream, in which the alkylated aromatics, especially toluene and xylene, are dealkylated and the paraffinic dealkylation products further converted into methane so that a significant portion of hydrogen can be saved by carrying out the hydrogenation subsequent to the extractive distillation, as the aromatics mixture is then free of olefins and no hydrogen is required for an olefin hydrogenation, with extractive distillation and recovery of the extracting solvent taking place in one column. An apparatus for carrying out the process described is also disclosed. A column is preferably used for the extractive distillation which allows performing the extractive distillation with a solvent recycling system so that it is not required to provide an additional stripping column for removing the extracting solvent.
1. A process for the dealkylation of a hydrocarbon mixture rich in C 7 to C 9 aromatics, comprising:
submitting the aromatics-rich starting hydrocarbon mixture to an extractive distillation in which the aromatics-containing hydrocarbon mixture is distilled by means of a suitable extracting solvent and freed from it, obtaining a product flow significantly depleted from aromatic hydrocarbons and free of solvent as well as an aromatics concentrate significantly enriched in aromatic hydrocarbons and free of solvent;
passing the solvent-free aromatics concentrate to a reactor for hydrodealkylation after the extractive distillation, where it is reacted with hydrogen, giving a dealkylated aromatics stream as main product and a paraffinic hydrocarbon stream and a methane stream as by-products; and
passing the aromatic hydrocarbon stream to a purification unit for treatment; wherein
the extractive distillation and recovery of the extracting solvent take place in one column.
2. The process according to claim 1 , wherein the purification unit is a fractional distillation stage.
3. The process according to claim 1 , wherein the purification unit is a flash distillation stage.
4. The process for the dealkylation of a hydrocarbon mixture rich in aromatics according to claim 1 , wherein the aromatics-containing starting mixture is fully hydrogenated pyrolysis gasoline.
5. The process for the dealkylation of a hydrocarbon mixture rich in aromatics according to claim 1 , wherein the aromatics-containing starting mixture is catalytically reformed gasoline.
6. The process for the dealkylation of a hydrocarbon mixture rich in aromatics according to claim 1 , wherein the aromatics-containing starting mixture is coke-oven light oil refined under pressure.
7. The process for the dealkylation of a hydrocarbon mixture rich in aromatics according to claim 1 , wherein the process produces a dealkylated and purified aromatics stream which is pure benzene.
8. The process for the dealkylation of a hydrocarbon mixture rich in aromatics according to claim 1 , wherein the aromatics-containing starting mixture is submitted to a fractional distillation in a distilling column before being passed to the extractive distillation.
9. The process for the dealkylation of a hydrocarbon mixture rich in aromatics according to claim 1 , wherein the aromatics-containing starting mixture is brought into contact with water, an acid, a suitable solvent or with a mixture of these substances before being passed to the extractive distillation.
10. The process for the dealkylation of a hydrocarbon mixture rich in aromatics according to claim 1 , wherein the aromatics-containing starting mixture is submitted to a hydrogenation before being passed to the extractive distillation.
11. The process for the dealkylation of a hydrocarbon mixture rich in aromatics according to claim 1 , wherein a hydrogenation is carried out between the process steps of extractive distillation and hydrodealkylation.
12. The process for the dealkylation of a hydrocarbon mixture rich in aromatics according to claim 1 , wherein the extracting solvent is an N-substituted solvent with 1 to 8 carbon atoms in the substituent.
13. The process for the dealkylation of a hydrocarbon mixture rich in aromatics according to claim 1 , wherein the extracting solvent is N-formyl morpholine.
14. The process for the dealkylation of a hydrocarbon mixture rich in aromatics according to claim 1 , wherein the extracting solvent for the extractive distillation is N-methylpyrrolidone, sulfolane, methyl sulfonale, an alkylene glycol or an alkylated alkylene glycol or a mixture of these substances.
15. The process for the dealkylation of a hydrocarbon mixture rich in aromatics according to one of claim 12 , wherein an extracting solvent mixture used for the extractive distillation contains water.
16. The process for the dealkylation of a hydrocarbon mixture rich in aromatics according to claim 1 , wherein the hydrogenation step for hydrodealkylation is a thermal process.
17. The process for the dealkylation of a hydrocarbon mixture rich in aromatics according to claim 1 , wherein the hydrogenation step for hydrodealkylation is a catalytic process.
18. A process for the dealkylation of a hydrocarbon mixture rich in C 7 to C 9 aromatics, comprising:
submitting the C 7 to C 9 aromatics-rich starting hydrocarbon mixture to an extractive distillation in which the aromatics-containing hydrocarbon mixture is distilled by means of a suitable extracting solvent and freed from it, obtaining a product flow significantly depleted from aromatic hydrocarbons and free of solvent as well as an aromatics concentrate significantly enriched in aromatic hydrocarbons and free of solvent, which concentrate comprises C 7 to C 9 aromatics;
passing the solvent-free aromatics concentrate to a reactor for hydrodealkylation after the extractive distillation, where it is reacted with hydrogen, giving a dealkylated aromatics stream as main product and a paraffinic hydrocarbon stream and a methane stream as by-products; and
passing the aromatic hydrocarbon stream to a purification unit for treatment; wherein
the extractive distillation and recovery of the extracting solvent take place in one column.