Coal processing to upgrade low rank coal having low oil content
A method of treating untreated low calorific coal containing moisture and organic volatiles includes feeding untreated coal to a dryer, and drying the coal. The dried coal is subjected to a pyrolyzing step where oxygen-deficient gases are brought into contact with the coal, thereby lowering the volatile content of the coal and producing a stream of pyrolysis effluent gases. The pyrolysis effluent gases are subjected to a separation process to separate lean fuel gases from liquids and tars, wherein the separation process removes less than about 20 percent of the pyrolysis effluent gases as the liquids and tars, with the remainder being the lean fuel gases. The lean fuel gases are returned to the dryer combustor, the pyrolyzer combustor, or the pyrolyzer.
1. A method of treating untreated low calorific coal containing moisture and organic volatiles, the method comprising:
operating a dryer combustor for producing gases for drying coal;
feeding untreated coal and the gases for drying coal to a dryer, and drying the coal;
operating a pyrolyzer combustor for producing oxygen-deficient gases for pyrolyzing;
subjecting the dried coal to a pyrolyzing step in a pyrolyzer wherein the oxygen-deficient gases for pyrolyzing are brought into contact with the coal, thereby producing char having a lower volatile content than that of the untreated coal and producing a stream of pyrolysis effluent gases;
subjecting the pyrolysis effluent gases to a separation process to separate lean fuel gases from liquids and tars, wherein the separation process removes less than about 20 percent of the pyrolysis effluent gases as the liquids and tars, with the remainder being the lean fuel gases; and
returning the lean fuel gases to one or more of the dryer combustor, the pyrolyzer combustor, or the pyrolyzer, wherein a portion of the lean fuel gases is blended into the oxygen-deficient gases for pyrolyzing.
2. The method of claim 1 in which the separation process removes less than about 10 percent of the pyrolysis effluent gases as the liquids and tars.
3. The method of claim 1 in which the untreated coal has a fuel ratio less than about 0.60.
4. The method of claim 1 in which the atomic hydrogen to carbon (H/C) ratio is less than about 0.65.
5. The method of claim 1 in which the untreated coal has less than about 35 percent volatile content.
6. The method of claim 1 in which the pyrolyzing process produces char having volatile matter in an amount within the range of from about 10 to about 20 percent.
7. The method of claim 1 in which the pyrolyzing process produces char having a volatile content that is at least 20 percent lower than that of the untreated coal.
8. The method of claim 1 in which the treating of untreated low calorific coal is effective to raise the thermal value of low calorific coal having a calorific content of less than or equal to about 8,000 Btu/pound (18.6 MJ/kg) to a resulting stream of processed coal having a thermal value of at least about 11,000 Btu/pound (25.6 MJ/kg).
9. The method of claim 1 in which the resulting processed coal char has its sulfur content reduced by over 35 percent when compared with the untreated coal.
10. The method of claim 1 including operating the pyrolyzer at a temperature within the range of from about 700° F. to about 900° F.
11. The method of claim 1 in which the oxygen-deficient gases used for pyrolyzing have an oxygen content less than about 0.5 percent.
12. A method of treating untreated low calorific coal containing moisture and organic volatiles, the method comprising:
operating a dryer combustor for producing gases for drying coal;
feeding untreated coal and the gases for drying coal to a dryer, and drying the coal;
operating a pyrolyzer combustor for producing gases for pyrolyzing;
subjecting the dried coal to a pyrolyzing step in a pyrolyzer wherein the oxygen-deficient gases for pyrolyzing are brought into contact with the coal, thereby producing char having a lower volatile content than that of the untreated coal, thereby lowering the volatile content of the coal and producing a stream of pyrolysis effluent gases;
subjecting the pyrolysis effluent gases to a separation process to separate lean fuel gases from liquids and tars, wherein the separation process is carried out while maintaining the pyrolysis effluent gases at a temperature above the condensation temperature of the pyrolysis effluent gases; and
returning the lean fuel gases to one or more of the dryer combustor, the pyrolyzer combustor, or the pyrolyzer, wherein a portion of the lean fuel gases is blended into the oxygen-deficient gases for pyrolyzing.
13. The method of claim 12 in which the separation process removes less than about 10 percent of the pyrolysis effluent gases as the liquids and tars.
14. The method of claim 12 in which the untreated coal has a fuel ratio less than about 0.60.
15. The method of claim 12 in which the atomic hydrogen to carbon (H/C) ratio is less than about 0.65.
16. The method of claim 12 in which the untreated coal has less than about 35 percent volatile content.
17. The method of claim 12 including producing char having volatile matter in an amount within the range of from about 10 to about 20 percent.
18. The method of claim 12 in which the treating of untreated low calorific coal is effective to raise the thermal value of low calorific coal having a calorific content of less than or equal to about 8,000 Btu/pound (18.6 MJ/kg) to a resulting stream of processed coal having a thermal value of at least about 11,000 Btu/pound (25.6 MJ/kg).
19. A method of treating untreated low calorific coal containing moisture and organic volatiles, the method comprising:
operating a dryer combustor for producing gases for drying coal;
feeding untreated coal and the gases for drying coal to a dryer, and drying the coal;
operating a pyrolyzer combustor for producing gases for pyrolyzing;
subjecting the dried coal to a pyrolyzing step in a pyrolyzer wherein the oxygen-deficient gases for pyrolyzing are brought into contact with the coal, thereby producing char having a lower volatile content than that of the untreated coal, thereby lowering the volatile content of the coal and producing a stream of pyrolysis effluent gases;
subjecting the pyrolysis effluent gases to a separation process to separate lean fuel gases from liquids and tars, wherein the separation process is carried out without substantial cooling of the pyrolysis effluent gases; and
returning the lean fuel gases to one or more of the dryer combustor, the pyrolyzer combustor, or the pyrolyzer, wherein a portion of the lean fuel gases is blended into the oxygen-deficient gases for pyrolyzing.
20. The method of claim 19 in which the untreated coal has a fuel ratio less than about 0.60, the atomic hydrogen to carbon (H/C) ratio is less than about 0.65, and the untreated coal has less than about 35 percent volatile content.
21. The method of claim 19 in which the pyrolyzing process produces char having volatile matter in an amount within the range of from about 10 to about 20 percent.
22. The method of claim 19 in which the treating of untreated low calorific coal is effective to raise the thermal value of low calorific coal having a calorific content of less than or equal to about 8,000 Btu/pound (18.6 MJ/kg) to a resulting stream of processed coal having a thermal value of at least about 11,000 Btu/pound (25.6 MJ/kg).