Method of controlling surface roughness of a flexographic printing plate
View Patent ↗A method of controlling surface roughness of the relief surface of a flexographic printing element during thermal processing is provided. An imaged and exposed relief image printing element is thermally developed to remove the portions of at least one layer of photopolymer that are not crosslinked and cured by a) heating the at least one layer of photopolymer to soften uncured portions of the at least one layer of photopolymer; b) causing contact between the at least one layer of photopolymer and a blotting material; and c) separating the blotting material from the at least one layer of photopolymer. Thereafter, a smooth material is inserted between the surface of the at least one layer of photopolymer and the blotting material. In the alternative, a polymeric film is laminated onto the relief image printing element using heat and pressure.
1. A method of reducing surface roughness on a surface of a relief image printing element, wherein the relief image printing element comprises at least one layer of photopolymer that has been selectively imagewise exposed to actinic radiation to selectively crosslink and cure portions of the at least one layer of photopolymer, wherein the portions of the at least one layer of photopolymer that are crosslinked and cured form the relief image and the portions of the at least one layer of photopolymer that are not crosslinked and cured are removable in a subsequent development step, the method comprising in order the steps of:
a) thermally developing the relief image printing element to remove the portions of the at least one layer of photopolymer that are not crosslinked and cured by:
i) heating the at least one layer of photopolymer to a sufficient temperature to soften uncured portions of the at least one layer of photopolymer;
ii) causing contact between the at least one layer of photopolymer and a web of blotting material, wherein the web of blotting material is looped under and around at least a portion of a heated roller that contacts the at least one layer of photopolymer, wherein when the web of blotting material contacts the at least one layer of photopolymer, the softened uncured photopolymer portions of the at least one layer of photopolymer are absorbed into the blotting material; and
iii) separating the blotting material from the at least one layer of photopolymer; and thereafter
b) contacting the at least one layer of photopolymer with a smooth material while pressure and heat are applied to the smooth material in forcing it into contact with the at least one layer of photopolymer; and;
c) separating the smooth material from the at least one layer of photopolymer.
2. The method according to claim 1 , wherein the blotting material is an absorbent material selected from the group consisting of paper, woven and non-woven fabrics, screen mesh, open cell foam materials and porous materials.
3. The method according to claim 1 , wherein the smooth material comprises a polymeric material selected from the group consisting of polyesters, polyethylene, polypropylene and combinations of the foregoing.
4. The method according to claim 3 , wherein the smooth material comprises a release coating thereon.
5. The method according to claim 4 , wherein the smooth material comprises a polyethylene terephthalate film with a silicone release coating thereon.
6. The method according to claim 1 , wherein the step of heating the at least one layer of photopolymer to a sufficient temperature to soften uncured portions of the at least one layer of photopolymer comprises heating the layer of photopolymer to a temperature of between about 40 and about 230° C.
7. The method according to claim 1 , wherein step a) is repeated between about 5 and about 15 times.
8. The method according to claim 1 , wherein an average surface roughness of the relief image printing element is controlled to less than about 1000 nm.
9. The method according to claim 8 , wherein the average surface roughness of the relief image printing element is controlled to less than about 500 nm.
10. The method according to claim 1 , wherein steps b) and c) are repeated at least three times and step b) is conducted at a temperature of between about 140 to about 160° C.
11. The method according to claim 10 , wherein steps b) and c) are repeated five times and step b) is conducted at a temperature of about 150° C.
12. A method of reducing surface roughness on a surface of a relief image printing element, wherein the relief image printing element comprises at least one layer of photopolymer that has been selectively imaged and exposed to actinic radiation to create a relief image comprising cured portions of the at least one layer of photopolymer; wherein the imaged and exposed relief image printing element is thereafter thermally processed to removed uncured portions of the at least one layer of photopolymer and reveal the relief image; the method comprising in order the steps of:
a) thermally developing the relief image printing element to remove the portions of the at least one layer of photopolymer that are not crosslinked and cured by:
i) heating the at least one layer of photopolymer to a sufficient temperature to soften uncured portions of the at least one layer of photopolymer;
ii) causing contact between the at least one layer of photopolymer and a web of blotting material, wherein the web of blotting material is looped under and around at least a portion of a heated roller that contacts the at least one layer of photopolymer, wherein when the web of blotting material contacts the at least one layer of photopolymer, the softened uncured photopolymer portions of the at least one layer of photopolymer are absorbed into the blotting material;
iii) separating the blotting material from the at least one layer of photopolymer; and thereafter
b) laminating a polymeric film onto the at least one layer of photopolymer of the relief image printing element using heat and pressure; and
c) separating the polymeric film from the relief image printing element.
13. The method according to claim 12 , wherein the polymeric film is selected from the group consisting of polyesters, polyethylene, polypropylene and combinations of the foregoing.
14. The method according to claim 13 , wherein the polymeric film comprises a release coating thereon.
15. The method according to claim 14 , wherein the polymeric film comprises a polyethylene terephthalate film with a silicone release coating thereon.
16. The method according to claim 12 , wherein the laminating step is performed by passing the relief image printing element with the polymeric film thereon through a laminator at a speed of about one foot per minute and a temperature of about 110-130° C.
17. The method according to claim 12 , wherein an average surface roughness of the relief image printing element is controlled to less than about 1000 nm.
18. The method according to claim 17 , wherein the average surface roughness of the relief image printing element is controlled to less than about 500 nm.