Polymer composites and fabrications thereof
The present invention provides polymer composites reinforced with high aspect ratio reinforcing fillers selected from calcium phosphate nanofibers, nanoplates, submicron fibers, submicron plates, and combinations thereof. The mechanical and biological properties of the inventive composites are enhanced significantly over current polymer composites and may be employed in various biomedical applications, such as dental restorations.
1. A polymer composite, comprising: a polymer matrix and a reinforcing filler wherein the reinforcing filler comprises calcium phosphate nanofibers, submicron fibers, or combinations thereof, wherein the reinforcing filler has a gelatin coated surface comprising amine moieties, carboxylic acid moieties, or combinations thereof, and wherein the reinforcing filler has a diameter or thickness ranging between about 10 nm and about 1 μm and an aspect ratio ranging between about 50 and about 5,000 and is present in an amount ranging from about 0.6 wt. % to about 15 wt. %.
2. The polymer composite of claim 1 , wherein the amine moieties, carboxylic acid moieties, or combinations thereof on the gelatin coated surface are modified with a reagent selected from the group consisting of alkyls, amines, carboxylic acids, peroxides, and silanes.
3. The polymer composite of claim 1 , wherein the reinforcing filler is present in an amount ranging from about 0.6 wt. % to about 6 wt. %.
4. The polymer composite of claim 1 , wherein the reinforcing filler is bundled.
5. The polymer composite of claim 1 , wherein the diameter or thickness of the reinforcing filler is between about 50 nm and about 500 nm.
6. The polymer composite of claim 1 , wherein the aspect ratio is between about 100 and about 500.
7. The polymer composite of claim 1 , wherein the polymer matrix comprises a mixture of bisphenol A glycidyl methacrylate and triethylene glycol dimethacrylate.
8. The polymer composite of claim 1 , wherein the polymer matrix comprises poly(L-lactide).
9. The polymer composite of claim 4 , wherein the bundles have a diameter less than about 5 μm.
10. The polymer composite of claim 4 , wherein the bundles have a diameter less than about 2 μm.
11. The polymer composite of claim 1 , wherein the polymer composite further comprises an additional filler selected from the group consisting of calcium phosphates, strontium glass, barium glass, quartz, borosilicate glass, ceramics, silica, silicon nitride, silicon carbide, zirconia, medical grade ceramics, poly(L-lactide), poly(e-caprolactone), poly(lactide-co-glycolide), chitosan, cellulose, collagen, gelatin, and mixtures thereof.