Gas-phase polymerization of alpha-olefin
View Patent ↗A method for preparing polyolefin from alpha-olefin with high productivity using an internal circulating fluidized bed polymerization reactor is disclosed. The method for gas-phase polymerization of alpha-olefin comprising the steps of: supplying circulation gas including one or more alpha-olefins and inert gas into a polymerization reactor; polymerizing the alpha-olefin to polyolefin in two separated polymerization areas in the polymerization reactor; and discharging produced polyolefin from the polymerization reactor. The polymerization reactor is divided into the two polymerization areas by a draft tube, and an inside of the draft tube forms a riser where growing polyolefin polymers move up in fast fluidization, and an outside of the draft tube forms an annulus where the polyolefin polymers passing the riser move down by gravity, and the polyolefin polymers passing the annulus are introduced to a lower part of the riser again, so that the polyolefin polymers are polymerized during circulating between the riser and the annulus.
1. An internal circulating fluidized bed polymerization reactor, comprising:
a draft tube installed in the polymerization reactor, in which at least one penetration hole penetrating an inside and an outside of the draft tube is formed;
a partition tube which is located between the draft tube and a side wall of the polymerization reactor and divides an inside area of the reactor into an annulus and an outside area;
a gas distribution plate which is formed with an inclination from an outside of the partition tube to the side wall of the polymerization reactor; and
an annulus distribution plate which is formed with an inclination from an outside of the draft tube to the partition tube.
2. The internal circulating fluidized bed reactor of claim 1 , wherein the penetration hole is formed at a higher position than the contact position of the annulus distribution plate and the outside wall of the draft tube.