Photo-switchable membrane and method
Switchable gas permeation membranes in which a photo-switchable low-molecular-weight liquid crystalline (LC) material acts as the active element, and a method of making such membranes. Different LC eutectic mixtures were doped with mesogenic azo dyes and infused into track-etched porous membranes with regular cylindrical pores. Photo-induced isothermal phase changes in the imbibed mesogenic material afforded large, reversible changes in the permeability of the photo-switchable membrane to nitrogen. For example, membranes imbibed with a photo-switchable cyanobiphenyl LC material demonstrated low permeability in the nematic state, while the photo-generated isotropic state demonstrated a 16×-greater sorption coefficient. Both states obey a high linear sorption behavior in accordance with Henry's Law. In contrast, membranes imbibed with a photo-switchable phenyl benzoate LC material showed the opposite permeability behavior to the biphenyl-imbibed membrane, along with nonlinear sorption behavior.
1. A photo-switchable gas permeation membrane, said membrane comprising:
a eutectic liquid crystalline mixture, said mixture comprising:
a liquid crystal compound; and
a mesogenic azobenzene dye;
wherein the permeability of said membrane to gas is photo-switchable between a first state and a second state.
2. The photo-switchable gas permeation membrane of claim 1 , wherein said membrane is more permeable to gas in said second state than in said first state.
3. The photo-switchable gas permeation membrane of claim 1 , wherein said liquid crystal compound is selected from the group consisting of cyanobiphenyls, cyanobiphenyl acrylates, cyanobiphenyl polyacrylates, phenyl benzoates, phenylcyclohexanes, cyclocycohexanes, pyrimidines, and combinations thereof.
4. The photo-switchable gas permeation membrane of claim 3 , wherein said liquid crystal compound is a cyanobiphenyl selected from the group consisting of 4-cyano-4′-n-pentylbiphenyl, 4-cyano-4′-n-heptyl biphenyl, 4-cyano-4′-n-oxyoctylbiphenyl, 4-cyano-4′-n-pentyl-p-terphenyl, and combinations thereof.
5. The photo-switchable gas permeation membrane of claim 3 , wherein said liquid crystal compound is a phenyl benzoate selected from the group consisting of 4-n-pentylphenyl-4′-methoxybenzoate, 4-n-pentylphenyl-4′-n-pentyloxybenzoate, and combinations thereof.
6. The photo-switchable gas permeation membrane of claim 1 , wherein said mesogenic azobenzene dye comprises 4-butyl-4′-methoxyazobenzene.
7. The photo-switchable gas permeation membrane of claim 1 , wherein said mesogenic azobenzene dye comprises approximately 15% weight/weight (“w/w”) of said eutectic liquid crystalline mixture.
8. The photo-switchable gas permeation membrane of claim 1 , wherein said membrane comprises a material selected from the group consisting of polycarbonate, polyester, polyimide, and combinations thereof.
9. The photo-switchable gas permeation membrane of claim 1 , wherein said eutectic liquid crystalline mixture is imbibed in said membrane.
10. The photo-switchable gas permeation membrane of claim 1 , wherein said liquid crystalline mixture is dispersed into a host polymer solution and cast as a polymer-dispersed liquid crystal membrane.
11. The photo-switchable gas permeation membrane of claim 10 , wherein said liquid crystalline mixture and said host polymer solution are mixed at a ratio of approximately 60:40 weight/weight (“w/w”).
12. The photo-switchable gas permeation membrane of claim 1 , wherein said membrane is treated with n-octyltriethoxylsilane.
13. A method of making a photo-switchable gas permeation membrane, said method comprising the step of adding a mixture of a liquid crystalline compound and a mesogenic azobenzene dye to a gas permeable membrane, wherein after adding said mixture to said membrane, the permeability of said membrane to gas is photo-switchable between a first state and a second state.
14. The method of claim 13 , wherein said mixture is added by dispersing said mixture into a host polymer solution and casting the solution as a polymer-dispersed liquid crystal membrane.
15. The method of claim 13 , wherein said membrane is more permeable to gas in said second state than in said first state.
16. The method of claim 13 , wherein said liquid crystal compound is selected from the group consisting of cyanobiphenyls, phenyl benzoates, phenylcyclohexanes, cyclocycohexanes, pyrimidines, and combinations thereof.
17. The method of claim 13 , wherein said mesogenic azobenzene dye comprises 4-butyl-4′-methoxyazobenzene.
18. The method of claim 13 , wherein said membrane comprises a material selected from the group consisting of polycarbonate, polyester, polyimide, and combinations thereof.
19. The method of claim 13 , further comprising the step of:
treating said membrane with n-octyltriethoxylsilane.