Positive electrode mixture slurry for lithium secondary batteries, and positive electrode and lithium secondary battery that use said slurry
The invention provides a stable positive-electrode mixture slurry that is not subject to gelation, a positive electrode with abundant flexibility, and a lithium secondary battery with excellent battery characteristics. The slurry comprises a positive-electrode active material, a binder, and an organic solvent, the positive-electrode active material is a lithium-containing complex metal oxide represented by Formula: Li x M 1 y M 2 1-y O 2 (wherein 0.4≦x≦1; 0.3≦y≦1; M 1 is at least one selected from Ni or Mn; and M 2 is at least one selected from Co, Al, or Fe); and the binder comprises a fluorine-containing polymer represented by Composition Formula: (VDF) m (TFE) n (HFP) l (wherein VDF is a structural unit from vinylidene fluoride; TFE is a structural unit from tetrafluoroethylene; HFP is a structural unit from hexafluoropropylene; and 0.45≦m≦1; 0≦n≦0.5; and 0≦l≦0.1, and m+n+l=1).
1. A positive electrode mixture slurry for a lithium secondary battery, the slurry comprising a positive electrode active material (A), a binder (B), and an organic solvent (C), wherein
the positive electrode active material (A) is a lithium-containing complex metal oxide represented by:
LiNi x Co y Mn z O 2 Formula (A2)
wherein ⅓≦x≦0.4; 0.2≦y≦⅓; ⅓≦z≦0.4 and 0.9≦x+y+z≦1.1; and
the binder (B) comprises a fluorine-containing polymer represented by Composition Formula (B): (VDF) m (TFE) n (HFP) L
wherein VDF is a structural unit from vinylidene fluoride; TFE is a structural unit from tetrafluoroethylene; HFP is a structural unit from hexafluoropropylene; and 0.50≦m≦0.90; 0.10≦n≦0.50; and 0≦L≦0.08, and m+n+L=1.
2. The positive electrode mixture slurry according to claim 1 , wherein the binder (B) comprises a fluorine-containing copolymer of Formula (B) wherein 0.50≦m≦0.90; 0.10≦n≦0.45; and 0.01≦L≦0.05, and m+n+L=1.
3. A positive electrode for a lithium secondary battery obtainable by applying the positive electrode mixture slurry according to claim 1 to a positive electrode current collector and drying the applied slurry.
4. A lithium secondary battery comprising the positive electrode according to claim 3 , a negative electrode, and a nonaqueous electrolyte.
5. A method for producing a positive electrode mixture slurry for a lithium secondary battery, comprising dispersing:
a positive electrode active material (A) that is a lithium-containing complex metal oxide represented by:
LiNi x Co y Mn z O 2 Formula (A2)
wherein ⅓≦x≦0.4; 0.2≦y≦⅓; ⅓≦z≦0.4; and 0.9≦x+y+z≦1.1; and
a binder (B) comprising a fluorine-containing polymer represented by Composition Formula (B): (VDF) m (TFE) n (HFP) L ,
wherein VDF is a structural unit from vinylidene fluoride; TFE is a structural unit from tetrafluoroethylene; HFP is a structural unit from hexafluoropropylene; and 0.50≦m≦0.90; 0.10≦n≦0.50; and 0≦L≦0.08, and m+n+L=1,
in an organic solvent (C).
6. The production method according to claim 5 , wherein the organic solvent (C) is N-methylpyrrolidone.
7. A positive electrode mixture slurry for a lithium secondary battery obtainable by the production method according to claim 5 .