Electrospinning for integrated separator for lithium-ion batteries
Embodiments of the present invention relate generally to lithium-ion batteries, and more specifically, to batteries having integrated separators and methods of fabricating such batteries. In one embodiment, a lithium-ion battery having an electrode structure is provided. The lithium-ion battery comprises an anode stack, a cathode stack, and a porous electrospun polymer separator comprising a nano-fiber backbone structure. The anode stack comprises an anodic current collector and an anode structure formed over a first surface of the anodic current collector. The cathode stack comprises a cathodic current collector and a cathode structure formed over a first surface of the cathodic current collector. The porous electrospun polymer separator is positioned between the anode structure and the cathode structure.
1. A method of forming an electrode structure comprising:
electrospinning a nano-fiber backbone structure having embedded ceramic particles directly onto a surface of a first electrode structure to form a porous electrospun polymer separator, wherein electrospinning the nano-fiber backbone structure comprises:
depositing a polymer containing liquid mixture onto a surface parallel to the surface of the first electrode structure, wherein the polymer containing liquid mixture comprises the ceramic particles; and
applying a voltage to the polymer containing liquid mixture to electrospin the nano-fiber backbone structure embedded with the ceramic particles onto the surface of the first electrode structure; and
electrospraying a second polymer material over the nano-fiber backbone structure having embedded ceramic nanoparticles.
2. The method of claim 1 , wherein the nano-fiber backbone structure comprises a first polymer material selected from poly(acrylic acid) (PAA), polyvinylidene fluoride (PVDF), carboxymethyl cellulose (CMC), and styrene-butadiene rubber (SBR).
3. A method of forming an electrode structure comprising:
electrospinning a nano-fiber backbone structure directly onto a surface of a first electrode structure to form a porous electrospun polymer separator, wherein the nano-fiber backbone structure comprises a first polymer material selected from poly(acrylic acid) (PAA), polyvinylidene fluoride (PVDF), carboxymethyl cellulose (CMC), and styrene-butadiene rubber (SBR); and
electrospraying a second polymer material over the nano-fiber backbone structure wherein the second polymer material is selected from polyvinylidene fluoride (PVDF), carboxymethyl cellulose (CMC), and styrene-butadiene rubber (SBR).
4. The method of claim 2 , wherein the ceramic particles are selected from the group of: Pb(Zr,Ti)O 3 (PZT), Pb 1-x La x Zr 1-y Ti y O 3 (PLZT, x and y are independently between 0 and 1), PB(Mg 3 Nb 2/3 )O 3 —PbTiO 3 (PMN-PT), BaTiO 3 , HfO 2 (hafnia), SrTiO 3 , TiO 2 (titania), SiO 2 (silica), Al 2 O 3 (alumina), ZrO 2 (zirconia), SnO 2 , CeO 2 , MgO, CaO, Y 2 O 3 and combinations thereof.
5. The method of claim 1 , wherein
the first polymer material has a high melting temperature greater than 200° C.; and
wherein the second polymer material has a low melting temperature less than 140° C. and forms a plurality of low melting temperature polymer lines in the porous electrospun polymer separator, such that during a thermal runaway, the low melting temperature polymer lines are melted and fused together, reducing a porosity in the porous electrospun polymer separator and thus slowing a lithium-ion transport and one or more associated electrochemical reactions.
6. The method of claim 1 , wherein the ceramic particles have a diameter between about 10 nm and about 20 nm.
7. The method of claim 1 , wherein the ceramic particles are added to the polymer containing liquid mixture using a sol-gel process.
8. The method of claim 1 , further comprising:
ultrasonically agitating the polymer containing liquid mixture before the voltage is applied to the polymer containing liquid mixture.
9. The method of claim 1 ,
wherein the second polymer material is selected from polyvinylidene fluoride (PVDF), carboxymethyl cellulose (CMC), and styrene-butadiene rubber (SBR).