IP Library Granted Patent US 8,920,622
Granted Patent B2
US 8,920,622 · App. 13/234,641 · Granted Dec 30, 2014

Increasing ion sorption and desorption rates of conductive electrodes

Inventors: David William DePaoli (Knoxville, TN); James O. Kiggans, Jr. (Oak Ridge, TN); Costas Tsouris (Oak Ridge, TN); William Bourcier (Livermore, CA); Robert Campbell (Rancho Murieta, CA); Richard T. Mayes (Knoxville, TN)
Assignee: UT Battelle, LLC
C25B15/02C02F1/4691C02F1/4604C02F2201/4613C02F2201/46135C02F2201/4616C02F2209/005C02F2209/05
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Quick Facts
Patent No.
US 8,920,622
App. No.
13/234,641
Granted
Dec 30, 2014
Kind
B2
Abstract

An electrolyte system includes a reactor having a pair of electrodes that may sorb ions from an electrolyte. The electrolyte system also includes at least one power supply in electrical communication with the reactor. The at least one power supply may supply a DC signal and an AC signal to the pair of electrodes during sorption of the ions. In addition, the power supply may supply only the AC signal to the pair of electrodes during desorption of the ions.

Claims (24)

1. An electrolyte system comprising:

a reactor comprising:

a pair of electrodes; and

a channel in between the pair of electrodes, an electrolyte being disposed in the channel,

wherein the pair of electrodes are configured to:

receive a direct current (DC) signal and an alternating current (AC) signal for sorption of ions in the electrolyte by the pair of electrodes;

sorb the ions in the electrolyte in response to receipt of the DC signal and the AC signal;

receive the AC signal without receipt of the DC signal for desorption of the ions in the electrolyte by the pair of electrodes; and

desorb the ions that were sorbed in response to receipt of the AC signal without the DC signal;

at least one power supply in electrical communication with the reactor and configured to:

supply the DC signal and the AC signal to the pair of electrodes for the sorption of the ions in the electrolyte;

switch from being configured to supply the DC signal and the AC signal to being configured to supply the AC signal without the DC signal to the pair of electrodes for the desorption of the ions that were sorbed by the pair of electrodes; and

supply the AC signal without supply of the DC signal to the pair of electrodes for the desorption of the ions in the electrolyte; and

a controller in electrical communication with the at least one power supply and configured to:

cause the at least one power supply to supply the DC signal and the AC signal to the pair of electrodes while determining an amount of ions sorbed by the pair of electrodes;

determine that the amount of ions sorbed by the pair of electrodes has reached a threshold level; and

in response to the determination, cause the at least one power supply to turn off the supply of the DC signal while keeping on the supply of the AC signal to the pair of electrodes for the desorption of the ions.

2. The electrolyte system of claim 1 , wherein a sum of a voltage of the DC signal and a highest voltage of the AC signal is less than or equal to a threshold voltage of an electrochemical reaction associated with the electrolyte.

3. The electrolyte system of claim 2 , wherein the electrochemical reaction is electrolysis, and wherein the threshold voltage is about +1.4 volts.

4. The electrolyte system of claim 1 , wherein a sum of a voltage of the DC signal and a highest voltage of the AC signal is greater than a threshold voltage of an electrochemical reaction associated with the electrolyte.

5. The electrolyte system of claim 1 , wherein a voltage of the DC signal is about +1.2 volts and a highest voltage of the AC signal is about +100 mV.

6. The electrolyte system of claim 1 , further comprising a pump that is connected to the reactor, the pump being configured to pump the electrolyte into and out of the reactor.

7. The electrolyte system of claim 1 , further comprising a charge drainage module connected to the reactor, the charge drainage module being configured to remove charge from the pair of electrodes.

8. The electrolyte system of claim 7 , wherein the charge drainage module is configured to remove charge from the pair of electrodes when the at least one power supply is supplying only the AC signal to the pair of electrodes.

Assignments (3)
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Jan 9, 2012
From: OAK RIDGE ASSOCIATED UNIVERSITIES
To: UT-BATTELLE, LLC
Reel/Frame 027500/0154 →
CONFIRMATORY LICENSE Recorded Nov 8, 2011
From: UT-BATTELLE, LLC
To: U.S. DEPARTMENT OF ENERGY
Reel/Frame 027192/0109 →
CONFIRMATORY LICENSE Recorded Nov 8, 2011
From: UT-BATTELLE, LLC
To: U.S. DEPARTMENT OF ENERGY
Reel/Frame 027192/0251 →
Continuity (1)
Related Publication 20130068630A1 · Mar 21, 2013