Controlled geometry composite micro pellets for use in compression molding
Controlled geometry pellets, which have at least one generally flat face having a cross-sectional shape with a rectangular envelope having an aspect ratio of at least 1.5, are provided. The controlled geometry pellets may include a plurality of reinforcing particulates dispersed throughout the thermoplastic resin. The reinforcing particulates typically have a largest dimension which is no more than about 90% of the largest pellet dimension. Compression molding methods of manufacturing a shaped article using the pellets are also provided. The methods include compression molding thermoplastic resin-based material to provide a molded article, where thermoplastic resin-based material comprises a plurality of the controlled geometry pellets.
1. Composite pellets produced by a method comprising:
extruding a blended mixture comprising molten thermoplastic resin and reinforcing fibers through a die orifice with a cross-sectional shape having a rectangular envelope with an aspect ratio of about 1.5:1 to 5:1, wherein the reinforcing fibers have a largest dimension which is no more than about 90% of a width of the die orifice; and cutting the extruded mixture to form pellets having an axial length to cross-sectional width ratio of about 0.25:1 to 5:1;
wherein the reinforcing particulates comprise carbon fibers having a diameter of about 5 to 20 microns and an aspect ratio of about 10 to 200; and
the thermoplastic polymeric resin comprises polyetheretherketone, polyetherketoneetherketoneketone, polyetherimide, polyethersulfone, polyphthalamide or a combination thereof.
2. The composite pellets of claim 1 , wherein the thermoplastic polymeric resin comprises polyetheretherketone, polyetherketoneetherketoneketone, or a combination thereof.
3. Composite pellets produced by a method comprising:
extruding a blended mixture comprising molten thermoplastic resin and reinforcing fibers through a die orifice with a cross-sectional shape having a rectangular envelope with an aspect ratio of about 1.5:1 to 5:1, wherein the reinforcing fibers have a largest dimension which is no more than about 90% of a width of the die orifice; and cutting the extruded mixture to form pellets having an axial length to cross-sectional width ratio of about 0.25:1 to 5:1;
wherein the pellet has at least three substantially planar faces; and
the thermoplastic polymeric resin comprises polyetheretherketone, polyetherketoneetherketoneketone, polyetherimide, polyethersulfone, polyphthalamide or a combination thereof.
4. The composite pellets of claim 3 , wherein the thermoplastic polymeric resin comprises polyetheretherketone, polyetherketoneetherketoneketone, or a combination thereof.
5. The composite pellets of claim 3 , wherein the thermoplastic resin comprises polyetheretherketone; and the reinforcing fibers comprise milled and/or chopped carbon fibers.
6. Composite pellets produced by a method comprising:
extruding a blended mixture comprising molten thermoplastic polymeric resin and reinforcing fibers through a die orifice with a cross-sectional shape having a rectangular envelope with an aspect ratio of about 1.5:1 to 5:1, wherein the reinforcing fibers have a largest dimension which is no more than about 90% of a width of the die orifice; and
cutting the extruded mixture to form pellets having an axial length to cross-sectional width ratio of about 0.25:1 to 5:1;
wherein the thermoplastic polymeric resin comprises oxyphenoxyphenoxybenzoyl polyetheretherketone; and the reinforcing particulates comprise milled and/or chopped carbon fibers.
7. The composite pellets of claim 6 , wherein the pellets have a thickness of about 0.5 to 3 mm and an axial dimension of no more than about 5 mm; and pellets have an average weight of about 1 to 20 mg.
8. The composite pellets of claim 6 , comprising:
about 30 to 90 wt. % of the thermoplastic polymeric resin; and
about 10 to 70 wt. % of the reinforcing fibers dispersed in the thermoplastic polymeric resin;
wherein the composite pellets have a thickness of about 0.5 to 3 mm.
9. Composite pellets produced by a method comprising:
extruding a blended mixture comprising molten thermoplastic resin and reinforcing fibers through a die orifice with a cross-sectional shape having a rectangular envelope with an aspect ratio of about 1.5:1 to 5:1, wherein the reinforcing fibers have a largest dimension which is no more than about 90% of a width of the die orifice; and
cutting the extruded mixture to form pellets having an axial length to cross-sectional width ratio of about 0.25:1 to 5:1;
wherein the reinforcing fibers comprise milled and/or chopped glass fibers, milled and/or chopped carbon fibers, or a combination thereof;
the thermoplastic polymeric resin comprises polyarylether/arylketone.
10. The composite pellets of claim 9 , wherein the pellets have a rectangular, elliptical, triangular or hexagonal die-face cross-sectional shape.
11. The composite pellets of claim 9 , wherein each of the pellets weighs no more than about 10 mg.
12. The composite pellets of claim 9 , wherein the pellets have an axial length of no more than about 5 mm, a thickness of about 0.25 mm to 3 mm, and die-face cross-sectional area of no more than about 5 mm 2 ; and the reinforcing fibers have an average length of about 0.05 to 3 mm.
13. Composite pellets produced by a method comprising:
(a) extruding a blended mixture comprising molten thermoplastic polymeric resin and reinforcing fibers through a die orifice with a cross-sectional shape having a rectangular envelope with an aspect ratio of about 1.5:1 to 5:1, wherein the reinforcing fibers have a largest dimension which is no more than about 90% of a width of the die orifice; and (b) cutting the extruded mixture to form pellets having an axial length to cross-sectional width ratio of about 0.25:1 to 5:1;
wherein the composite pellets comprise about 30 to 90 wt. % of the thermoplastic polymeric resin; and about 10 to 70 wt. % of the reinforcing fibers dispersed in the thermoplastic polymeric resin; and
the thermoplastic polymeric resin comprises polyarylether/arylketone.
14. The composite pellets of claim 9 , comprising:
about 30 to 90 wt. % of the thermoplastic polymeric resin; and
about 10 to 70 wt. % of the reinforcing fibers dispersed in the thermoplastic polymeric resin;
wherein the composite pellets have a compression factor of no more than about 2.2; and a thickness of about 0.5 to 3 mm.
15. The composite pellets of claim 9 , further comprising a flame retardant, a lubricant, a wear resistance additive, a micro-tag, a colorant, a fragrance, a conductive filler or a combination thereof.
16. The composite pellets of claim 13 , wherein the pellets have an axial length to cross-sectional width ratio of about 0.5:1 to 3:1; and the reinforcing particulates comprise carbon fibers having a diameter of about 5 to 20 microns and an aspect ratio of about 10 to 200.
17. The composite pellets of claim 13 , wherein the polyarylether/arylketone comprises polyether ketone (PEK), polyetheretherketone (PEEK), polyetherketoneketone (PEKK), polyetherketoneetherketoneketone (PEKEKK), or a combination thereof.
18. The composite pellets of claim 13 , wherein the thermoplastic polymeric resin comprises polyetheretherketone (PEEK); and the reinforcing fibers comprise milled and/or chopped carbon fibers.
19. The composite pellets of claim 13 , wherein the pellets have an axial dimension of no more than about 5 mm and a die-face cross-sectional area of no more than about 5 mm 2 .
20. The composite pellets of claim 13 , wherein the pellets have a compression factor of no more than about 2.5.
21. A method of producing composite pellets comprising:
blending a mixture comprising reinforcing fibers and molten thermoplastic polymeric resin;
extruding the blended mixture through a die orifice with a cross sectional shape having a rectangular envelope with an aspect ratio of about 1.5:1 to 5:1, wherein the reinforcing fibers have a largest dimension which is no more than about 90% of a largest dimension of the die orifice; and
cutting the extruded mixture to form pellets, each pellet having an axial length to cross sectional width ratio of about 0.25:1 to 5:1;
wherein the reinforcing fibers comprise milled and/or chopped glass fibers, milled and/or chopped carbon fibers, or a combination thereof; and
the thermoplastic polymeric resin comprises polyarylether/arylketone.