Heat-sensitive recording material and method for producing same
The present invention provides a heat-sensitive recording material that has high gloss and excellent absorption and scratch off properties against sebum soiling; and a method for producing the heat-sensitive recording material. More specifically, the present invention provides a heat-sensitive recording material containing a heat-sensitive recording layer, an intermediate layer, and a protective layer, which are sequentially formed in this order on a support. The heat-sensitive recording layer contains a leuco dye and a developer; the intermediate layer contains an aqueous adhesive; and the protective layer is cured by irradiation of an ultraviolet- or electron-beam-curable resin composition with ultraviolet light or an electron beam. The heat-sensitive recording material additionally contains, on the protective layer, an uppermost layer which contains an aqueous adhesive and a pigment having a mean particle diameter of not more than 100 nm. The uppermost layer-side surface of the heat-sensitive recording material has a gloss at 75° of not less than 90% and a gloss at 20° of not less than 35% in accordance with JIS P 8142-1993. The present invention further provides a method for producing the heat-sensitive recording material.
1. A heat-sensitive recording material comprising a heat-sensitive recording layer, an intermediate layer, and a protective layer, which are sequentially formed in this order on a support, wherein the heat-sensitive recording layer contains a leuco dye and a developer; the intermediate layer contains an aqueous adhesive; and the protective layer is a cured form obtained by irradiation of an ultraviolet- or electron-beam-curable resin composition with ultraviolet light or an electron beam;
the heat-sensitive recording material further comprising, on the protective layer, an uppermost layer containing an aqueous adhesive and a pigment having a mean particle diameter of not more than 100 nm,
wherein the uppermost layer-side surface of the heat-sensitive recording material has a gloss at 75° of not less than 90% and a gloss at 20° of not less than 35% in accordance with JIS P 8142-1993.
2. The heat-sensitive recording material according to claim 1 , wherein the uppermost layer contains an aqueous adhesive comprising a polyurethane ionomer.
3. The heat-sensitive recording material according to claim 1 or 2 , wherein the pigment comprises one member selected from the group consisting of layered silicate compounds and colloidal silica, and the content of one member selected from the group consisting of layered silicate compounds and colloidal silica is 20 to 70 mass %, based on the total solids content of the uppermost layer.
4. The heat-sensitive recording material according to claim 1 or 2 , wherein the uppermost layer contains a resin obtained from the aqueous adhesive, which is a polymer latex having a heterogeneous particle structure containing a urethane resin component in at least one phase.
5. The heat-sensitive recording material according to claim 1 or 2 , wherein the uppermost layer has an average thickness of 0.02 to 0.4 μm, and the average thickness is not less than a mean particle diameter of the pigment.
6. The heat-sensitive recording material according to claim 1 or 2 , wherein the protective layer contains a filler having a 50% mean volume particle diameter (D50) of less than 2.0 μm as determined from the cumulative volume distribution, and a ratio of the 90% mean volume particle diameter (D90) to the 50% mean volume particle diameter (D50) (D90/D50) of not more than 3.0, and the protective layer has an average thickness of 0.5 to 5 μm, and the average thickness is not less than a mean particle diameter of the filler.
7. The heat-sensitive recording material according to claim 1 or 2 , wherein the protective layer contains at least one filler selected from the group consisting of synthetic zeolite and spherical silica.
8. The heat-sensitive recording material according to claim 1 or 2 , wherein the protective layer surface has a gloss at 75° of not less than 90% in accordance with JIS P 8142-1993 and a wetting tension of not less than 50 mN/m.
9. The heat-sensitive recording material according to claim 1 or 2 , wherein the uppermost layer is formed by using an uppermost layer coating composition containing
an alkyl phosphate;
an alkali metal pyrophosphate; and
at least one thickener selected from the group consisting of acrylic alkali thickeners, polyethylene oxide, xanthan gum, and sodium polyacrylate; and wherein
the alkyl phosphate content is 0.5 to 10 mass %, based on the total solids content of the uppermost layer,
and the alkali metal pyrophosphate content is 3 to 20 mass %, based on the pigment.
10. The heat-sensitive recording material according to claim 9 , wherein the acrylic alkali thickener content is 0.1 to 3 mass %, based on the total solids content of the uppermost layer.
11. The heat-sensitive recording material according to claim 9 , wherein the content of at least one member selected from the group consisting of polyethylene oxide, xanthan gum, and sodium polyacrylate is 0.05 to 0.5 mass %, based on the total solids content of the uppermost layer.
12. A method for producing a heat-sensitive recording material according to claim 1 or 2 , wherein the heat-sensitive recording material comprising a heat-sensitive recording layer, an intermediate layer, and a protective layer, which are sequentially formed in this order on a support, the heat-sensitive recording layer containing a leuco dye and a developer, the intermediate layer containing an aqueous adhesive, and the protective layer being cured by irradiation of an ultraviolet- or electron-beam-curable resin composition with ultraviolet light or an electron beam,
applying to the protective layer an uppermost layer coating composition containing an aqueous adhesive and a pigment with a mean particle diameter of not more than 100 nm and drying the composition to form an uppermost layer,
wherein the uppermost layer-side surface has a gloss at 75° of not less than 90% and a gloss at 20° of not less than 35% in accordance with JIS P 8142-1993.